Results 41 to 50 of about 152,508 (309)

Synthesis of alpha-tetrasubstituted triazoles by copper-catalyzed silyl deprotection/azide cycloaddition

open access: yesBeilstein Journal of Organic Chemistry, 2015
Propargylamines are popular substrates for triazole formation, but tetrasubstituted variants have required multistep syntheses involving stoichiometric amounts of metal.
Zachary L. Palchak   +2 more
doaj   +1 more source

2D-IR spectroscopy of azide-labeled carbohydrates in H2O [PDF]

open access: yes
Carbohydrates constitute one of the key classes of biomacromolecules, yet vibrational spectroscopic studies involving carbohydrates remain scarce as spectra are highly congested and lack significant marker vibrations.
Henrike M., Müller-Werkmeister   +2 more
core   +1 more source

Clinical and analytical problems of sodium azide poisonings as exemplified by a case of fatal suicidal poisoning [PDF]

open access: yes, 2015
Aim of the study: To present clinical and analytical aspects associated with sodium azide poisoning. The problems were verified on the basis of a case of sodium azide poisoning which was unique due to its circumstances and the development of an ...
Sebastian Rojek   +9 more
core   +1 more source

Translation of a phosphine- and azide-based reaction to chemical modification of biomolecules in ionic liquid [PDF]

open access: yes, 2022
The difference of reaction design principles between traditional, small molecule synthetic chemistry and biomolecular chemical reactions prevented the simple translation of small molecule chemistry into biomolecular reactions.
Chiamaka, Uzoewulu, Jun, Ohata
core   +1 more source

Salivary Hydrogen Sulfide Measured with a New Highly Sensitive Self-Immolative Coumarin-Based Fluorescent Probe

open access: yesMolecules, 2018
Ample evidence suggests that H2S is an important biological mediator, produced by endogenous enzymes and microbiota. So far, several techniques including colorimetric methods, electrochemical analysis and sulfide precipitation have been developed for H2S
Ewelina Zaorska   +4 more
doaj   +1 more source

2-Azido-N-(4-methylphenyl)acetamide

open access: yesIUCrData, 2022
The asymmetric unit of the title compound, C9H10N4O, comprises three independent molecules, two pairs of which differ significantly in the rotational orientation of the azido group and one pair having very similar conformations; the N—N—C—C torsion ...
Mohcine Missioui   +4 more
doaj   +1 more source

Azide-Substituted Polylactide: A Biodegradable Substrate for Antimicrobial Materials via Click Chemistry Attachment of Quaternary Ammonium Groups

open access: yes, 2019
Polylactide (PL) co-polymers substituted with pendant azide groups (azido-PL) were synthesized by the nucleophilic conjugate addition of 3-azido-1-propanethiol to a co-polymer of PL containing α,β-unsaturated ester units, poly­(lactide-co-methylene ...
Pranav P. Kalelkar   +7 more
core   +1 more source

ABL kinase‐dependent phosphorylation of SH proteins promotes their direct interaction with CRK family SH2 domains

open access: yesFEBS Letters, EarlyView.
CT10 regulator of kinase (CRK) and CRK‐Like (CRKL) are signaling adaptors driving cell adhesion, motility, differentiation, and proliferation. SH2‐domain containing (SH) proteins are enriched in YXXP motifs which when phosphorylated create preferred binding sites for CRK family SH2 domains.
Phoebe M. Cousens   +8 more
wiley   +1 more source

Bis{bis(azido-κN)bis[bis(pyridin-2-yl-κN)amine]cobalt(III)} sulfate dihydrate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2016
The search for new molecular materials with interesting magnetic properties, using the pseudohalide azide ion and di-2-pyridylamine (dpa, C10H9N3) as a chelating ligand, led to the synthesis and structure determination of the title compound, [Co(N3)2(dpa)
Fatima Setifi   +3 more
doaj   +1 more source

Five-Coordinated Geometries from Molecular Structures to Solutions in Copper(II) Complexes Generated from Polydentate-N-Donor Ligands and Pseudohalides

open access: yesMolecules, 2020
A novel series of mononuclear five-coordinated pseudohalido-Cu(II) complexes displaying distorted square bipyramidal: [Cu(L1)(NCS)2] (1), [Cu(L2)(NCS)2] (2) and [Cu(L3)(NCS)]ClO4 (5) as well as distorted trigonal bipyramidal: [Cu(isp3tren)(N3)]ClO4 (3), [
Franz A. Mautner   +6 more
doaj   +1 more source

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