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Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
The structures of two azide containing imidazole derivatives are reported. Allylic azides are fairly reactive making them attractive starting compounds to convert into amides.
Lorenzo M. Cruz   +5 more
doaj   +1 more source

Nitrene Transfer Catalyzed by a Non-Heme Iron Enzyme and Enhanced by Non-Native Small-Molecule Cofactors [PDF]

open access: yes, 2019
Transition-metal catalysis is a powerful tool for the construction of chemical bonds. Here we show that a non-heme iron enzyme can catalyze olefin aziridination and nitrene C–H insertion, and that these activities can be improved by directed evolution ...
Arnold, Frances H.   +3 more
core   +1 more source

Crystal structure of (N^C) cyclometalated AuIII diazide at 100 K

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
The title compound, an (N^C)-cyclometalated gold(III) diazide, namely, diazido[5-ethoxycarbonyl-2-(5-ethoxycarbonylpyridin-2-yl)phenyl-κ2C1,N]gold(III), [Au(C17H16NO4)(N3)2] or Au(ppyEt)(N3)2, was synthesized by reacting Au(ppyEt)Cl2 with NaN3 in water ...
Volodymyr Levchenko   +3 more
doaj   +1 more source

Synthesis of Calix[4]arene Appended Lactosylated G1 and Galacto­sylated G2 Generation Glycodendrimers using a ‘CuAAC’ Click Approach

open access: yesSynOpen, 2023
A modular and highly reliable click approach is applied for the expeditious synthesis of lactose- and galactose-coated calixarene-cored G1 and G2 generation glycodendrimers, respectively.
Sunil Kumar   +4 more
doaj   +1 more source

Promising Oxygen- and Nitrogen-Rich Azidonitramino Ether Plasticizers for Energetic Materials

open access: yesMolecules, 2022
A simple, mild and general method has been developed for the preparation of alkyl nitramines bearing a halogenoalkoxylic moiety. From these reactive halogen intermediates, a few azidoalkoxyl alkyl nitramines have been produced as energetic plasticizers ...
Dmitry B. Vinogradov   +10 more
doaj   +1 more source

SnAr Reactions of 2,4-Diazidopyrido[3,2-d]pyrimidine and Azide-Tetrazole Equilibrium Studies of the Obtained 5-Substituted Tetrazolo[1,5-a]pyrido[2,3-e]pyrimidines

open access: yesMolecules, 2022
A straightforward method for the synthesis of 5-substituted tetrazolo[1,5-a]pyrido[2,3-e]pyrimidines from 2,4-diazidopyrido[3,2-d]pyrimidine in SnAr reactions with N-, O-, and S- nucleophiles has been developed.
Kristaps Leškovskis   +3 more
doaj   +1 more source

Dual function additives: A small molecule crosslinker for enhanced efficiency and stability in organic solar cells [PDF]

open access: yes, 2015
A bis‐azide‐based small molecule cross­linker is synthesized and evaluated as both a stabilizing and efficiency‐boosting additive in bulk heterojunction organic photovoltaic cells.
Ashraf, RS   +8 more
core   +2 more sources

Synthesis, crystal structure and Hirshfeld surface analysis of 2-azido-N-(2,6-dimethylphenyl)acetamide

open access: yesActa Crystallographica Section E: Crystallographic Communications
The asymmetric unit of the title compound, C10H12N4O, consists of two independent molecules differing in the rotational orientation of the 2-azidoacetamido group.
Abderrazzak El Moutaouakil Ala Allah   +7 more
doaj   +1 more source

2D frameworks self-assembled from a hydrazone ligand and azide salts: synthesis, structures, and luminescent property

open access: yesActa Chimica Slovenica, 2017
Three metal-organic coordination polymers {[Cu(L)(N3)]·(H2O)0.25}n (1), {[Zn(L)(N3)]·(H2O)0.5}n(2)and [Cd2(L)2(N3)2(H2O)]n(3)have been synthesized from hydrazone ligand N′-(1-(pyrazin-2-yl)ethylidene)isonicotinohydrazide (HL), NaN3 and corresponding ...
Peng Wang   +4 more
doaj   +1 more source

N-(1-azido-2-(azidomethyl)butan-2-yl)-4-methylbenzenesulfonamide

open access: yesMolbank, 2022
A new bi-triazole precursor, N-(1-azido-2-(azidomethyl)butan-2-yl)-4-methylbenzenesulfonamide, was synthesized in two steps from 2-amino-2-ethyl-1,3-propanediol, with an overall yield of 80%.
Sara Hajib   +3 more
doaj   +1 more source

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