Results 11 to 20 of about 119,317 (256)

Crystal structure of 6-azido-6-deoxy-1,2-O-isopropylidene-α-d-glucofuranose

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
Short syntheses to high Fsp3 index natural-product analogues such as iminosugars are of paramount importance in the investigation of their biological activities and reducing the use of protecting groups is an advantageous synthetic strategy.
Adam Wood   +3 more
doaj   +1 more source

Oligonucleotide Tagging for Copper-Free Click Conjugation

open access: yesMolecules, 2013
Copper-free click chemistry between cyclooctynes and azide is a mild, fast and selective technology for conjugation of oligonucleotides. However, technology for site-specific introduction of the requisite probes by automated protocols is scarce, while ...
Alan Rowan   +7 more
doaj   +1 more source

Chemical Architecture and Applications of Nucleic Acid Derivatives Containing 1,2,3-Triazole Functionalities Synthesized via Click Chemistry

open access: yesMolecules, 2012
There is considerable attention directed at chemically modifying nucleic acids with robust functional groups in order to alter their properties. Since the breakthrough of copper-assisted azide-alkyne cycloadditions (CuAAC), there have been several ...
Wei Gong   +2 more
doaj   +1 more source

Stereochemical Geometries and Photoluminescence in Pseudo-Halido-Zinc(II) Complexes. Structural Comparison between the Corresponding Cadmium(II) Analogs

open access: yesInorganics, 2021
Six pseudohalide zinc(II) containing a variety of N-donor auxiliary amines were structurally characterized. These include two mononuclear trigonal bipyramidal [Zn(NTB)(N3)]ClO4·½H2O (3) and [Zn(TPA)(NCS)]ClO4 (4), two distorted octahedral [Zn(1,8-damnph ...
Franz A. Mautner   +8 more
doaj   +1 more source

Review of novel energetic polymers and binders – high energy propellant ingredients for the new space race

open access: yesDesigned Monomers and Polymers, 2019
Current solid rocket propellant formulations still employ traditional ingredients utilized since the 1960s, such as hydroxyl terminated polybutadiene (HTPB).
Tianze Cheng
doaj   +1 more source

2-(2-Azabicyclo[3.2.1]octa-3,6-dien-2-yl)-1,3-dimethoxyimidazolium hexafluoridophosphate

open access: yesIUCrData, 2016
The title salt, C12H16N3O2+·PF6−, was obtained by the dipolar cycloaddition of norbornadiene to 2-azido-1,3-dimethoxyimidazolium hexafluoridophosphate.
Simone Haslinger   +3 more
doaj   +1 more source

Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
The structures of two azide containing imidazole derivatives are reported. Allylic azides are fairly reactive making them attractive starting compounds to convert into amides.
Lorenzo M. Cruz   +5 more
doaj   +1 more source

Crystal structure of (N^C) cyclometalated AuIII diazide at 100 K

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
The title compound, an (N^C)-cyclometalated gold(III) diazide, namely, diazido[5-ethoxycarbonyl-2-(5-ethoxycarbonylpyridin-2-yl)phenyl-κ2C1,N]gold(III), [Au(C17H16NO4)(N3)2] or Au(ppyEt)(N3)2, was synthesized by reacting Au(ppyEt)Cl2 with NaN3 in water ...
Volodymyr Levchenko   +3 more
doaj   +1 more source

Synthesis of Calix[4]arene Appended Lactosylated G1 and Galacto­sylated G2 Generation Glycodendrimers using a ‘CuAAC’ Click Approach

open access: yesSynOpen, 2023
A modular and highly reliable click approach is applied for the expeditious synthesis of lactose- and galactose-coated calixarene-cored G1 and G2 generation glycodendrimers, respectively.
Sunil Kumar   +4 more
doaj   +1 more source

Promising Oxygen- and Nitrogen-Rich Azidonitramino Ether Plasticizers for Energetic Materials

open access: yesMolecules, 2022
A simple, mild and general method has been developed for the preparation of alkyl nitramines bearing a halogenoalkoxylic moiety. From these reactive halogen intermediates, a few azidoalkoxyl alkyl nitramines have been produced as energetic plasticizers ...
Dmitry B. Vinogradov   +10 more
doaj   +1 more source

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