Results 31 to 40 of about 45,965 (323)

Synthesis of Chromium(II) Complexes with Chelating Bis(alkoxide) Ligand and Their Reactions with Organoazides and Diazoalkanes

Molecules, 2020
Synthesis of new chromium(II) complexes with chelating bis(alkoxide) ligand [OO]Ph (H2[OO]Ph = [1,1′:4′,1′’-terphenyl]-2,2′’-diylbis(diphenylmethanol)) and their subsequent reactivity in the context of catalytic ...
Sudheer S. Kurup, Richard J. Staples, Richard L. Lord, Stanislav Groysman   +3 more
doaj   +1 more source

One pot ‘click’ reactions: tandem enantioselective biocatalytic epoxide ring opening and [3+2] azide alkyne cycloaddition [PDF]

, 2010
Halohydrin dehalogenase (HheC) can perform enantioselective azidolysis of aromatic epoxides to 1,2-azido alcohols which are subsequently ligated to alkynes producing chiral hydroxy triazoles in a one-pot procedure with excellent enantiomeric excess.
Campbell-Verduyn, Lachlan S.,, Dierckx, Rudi A.,, Elsinga, Philip H.,, Feringa, Ben L.,, Janssen, Dick B.,, Postema, Christiaan P.,, Szymański, Wiktor,   +6 more
core   +2 more sources

Discovery of Escherichia coli methionyl-tRNA synthetase mutants for efficient labeling of proteins with azidonorleucine in vivo [PDF]

, 2009
Incorporation of noncanonical amino acids into cellular proteins often requires engineering new aminoacyl-tRNA synthetase activity into the cell. A screening strategy that relies on cell-surface display of reactive amino acid side-chains was used to ...
Goddard, William A., III, Mechulam, Yves, Schmitt, Emmanuelle, Tanrikulu, I. Caglar, Tirrell, David A.   +4 more
core   +5 more sources

Mn(iii)-Catalyzed Radical Reactions of 1,3-Dicarbonyl Compounds and Cyclopropanols with Vinyl Azides for Divergent Synthesis of Azaheterocycles

CHIMIA, 2012
Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols.
Shunsuke Chiba
doaj   +1 more source

Crystal structure and spectroscopic properties of (E)-1,3-dimethyl-2-[3-(4-nitrophenyl)triaz-2-enylidene]-2,3-dihydro-1H-imidazole

Acta Crystallographica Section E: Crystallographic Communications, 2021
The title compound (E)-1,3-dimethyl-2-[3-(4-nitrophenyl)triaz-2-enylidene]-2,3-dihydro-1H-imidazole, C11H12N6O2, has monoclinic (C2/c) symmetry at 100 K.
Hector Mario Heras Martinez, David Chavez Flores, Patrick C. Hillesheim, Siddappa Patil, Alejandro Bugarin   +4 more
doaj   +1 more source

Folding of a donor–acceptor polyrotaxane by using noncovalent bonding interactions [PDF]

, 2008
Mechanically interlocked compounds, such as bistable catenanes and bistable rotaxanes, have been used to bring about actuation in nanoelectromechanical systems (NEMS) and molecular electronic devices (MEDs).
A. Z. Stieg, Appella, Beebe, Berna, Binnig, Chatterjee, Collier, Collier, D. Benitez, Estroff, Fletcher, Frechet, Harth, Hawker, J. F. Stoddart, J. K. Gimzewski, J. R. Heath, Kim, Liu, Liu, Miljanic, Sheiko, Srinivasachari, Torn  e, W. R. Dichtel, W. Zhang, Wenz   +26 more
core   +3 more sources

Multistep flow synthesis of vinyl azides and their use in the copper-catalyzed Huisgen-type cycloaddition under inductive-heating conditions

Beilstein Journal of Organic Chemistry, 2011
The multistep flow synthesis of vinyl azides and their application in the synthesis of vinyltriazoles is reported. The synthesis relies on a stable polymer-bound equivalent of iodine azide that serves to carry out 1,2-functionalization of alkenes in a ...
Lukas Kupracz, Jan Hartwig, Jens Wegner, Sascha Ceylan, Andreas Kirschning   +4 more
doaj   +1 more source

Design and synthesis of a bis-macrocyclic host and guests as building blocks for small molecular knots

Beilstein Journal of Organic Chemistry, 2020
The thread–link–cut (TLC) approach has previously shown promise as a novel method to synthesize molecular knots. The modular second-generation approach to small trefoil knots described herein involves electrostatic interactions between an electron-rich ...
Elizabeth A. Margolis, Rebecca J. Keyes, Stephen D. Lockey IV, Edward E. Fenlon   +3 more
doaj   +1 more source

Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". [PDF]

, 2015
The copper-catalyzed 1,3-dipolar cycloaddition of an azide to a terminal alkyne (CuAAC) is one of the most popular chemical transformations, with applications ranging from material to life sciences.
Bertrand, Guy, Jin, Liqun, Melaimi, Mohand, Tolentino, Daniel R   +3 more
core   +2 more sources

Copper(I)-Phosphinite Complexes in Click Cycloadditions: Three-Component Reactions and Preparation of 5-Iodotriazoles [PDF]

, 2016
© 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.The remarkable activity displayed by copper(I)–phosphinite complexes of general formula [CuBr(L)] in two challenging cycloadditions is reported: a) the one-pot azidonation/cycloaddition of
Crosbie, P, Diez-Gonzalez, S, Lal, S, Perez, J   +3 more
core   +2 more sources