Results 31 to 40 of about 73,246 (246)

Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors

open access: yesMolecules, 2002
The thermal decomposition of imidoyl azides (ArO-C=N-Z)-N3, (Ar = p-NO2-C6H4-, p-Br-C6H4-, p-Cl-C6H4-, p-C6H5-, p-CH3-C6H4-, 2,4-dimethyl-C6H3-, 2,4,6-trimethyl-C6H2-, p-CH3O-C6H4- and Z = p-CH3-C6H4-SO2-, 2,4,6-trimethyl-C6H2-SO2-,CN) in the solid phase
Reza Karimzadeh, Hossein A. Dabbagh
doaj   +1 more source

azides [PDF]

open access: yes, 2008
Citation: 'azides' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.A00555 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

A construction of 4,4-spirocyclic γ-lactams by tandem radical cyclization with carbon monoxide

open access: yesBeilstein Journal of Organic Chemistry, 2013
A straightforward synthesis of 4,4-spirocyclic indol γ-lactams by tandem radical cyclization of iodoaryl allyl azides with CO was achieved. The reaction of iodoaryl allyl azides, TTMSS and AIBN under CO pressure (80 atm) in THF at 80 °C gave the desired ...
Mitsuhiro Ueda   +6 more
doaj   +1 more source

Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines

open access: yesMolecules, 2020
The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials.
Ana R. L. Araújo   +8 more
doaj   +1 more source

Design of Conjugates Based on Sesquiterpene Lactones with Polyalkoxybenzenes by “Click” Chemistry to Create Potential Anticancer Agents

open access: yesMolecules, 2022
Using the methodology of “click” chemistry, a singular method has been developed for the synthesis of unique conjugates based on sesquiterpene lactones: dehydrocostuslactone and alantolactone with polyalkoxybenzenes. To expand the structural range of the
Margarita E. Neganova   +7 more
doaj   +1 more source

4-Azidocinnoline—Cinnoline-4-amine Pair as a New Fluorogenic and Fluorochromic Environment-Sensitive Probe

open access: yesMolecules, 2021
A new type of fluorogenic and fluorochromic probe based on the reduction of weakly fluorescent 4-azido-6-(4-cyanophenyl)cinnoline to the corresponding fluorescent cinnoline-4-amine was developed.
Natalia A. Danilkina   +7 more
doaj   +1 more source

Reaction of aromatic azides with strong acids: formation of fused nitrogen heterocycles and arylamines

open access: yesJournal of the Brazilian Chemical Society, 1999
We describe in this paper the action of trifluoroacetic acid, trifluoromethanesulfonic acid and aluminum chloride upon ortho-substituted aryl azides to form indoles, azepines and arylamines in good yields.
Carvalho Marcia de   +2 more
doaj  

Synthesis and Biological Evaluation of Some Coumarin–Triazole Conjugates as Potential Anticancer Agents

open access: yesScientia Pharmaceutica
Despite the discovery of many chemotherapeutic drugs that prevent uncontrolled cell division processes, the development of compounds with higher anticancer efficacy and a lower level of side effects is an important task in modern pharmaceutical chemistry.
Anarkul S. Kishkentayeva   +8 more
doaj   +1 more source

Crystal structure of (E)-1,3-dimethyl-2-[3-(3-nitrophenyl)triaz-2-en-1-ylidene]-2,3-dihydro-1H-imidazole

open access: yesActa Crystallographica Section E, 2014
The title compound, C11H12N6O2, a π-conjugated triazene, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the –N=N– bond and have slightly twisted overall conformations. In molecule
Siddappa Patil, Alejandro Bugarin
doaj   +1 more source

Butyl 2-[(azidocarbonyl)amino]benzoate

open access: yesIUCrData, 2016
The title compound, C12H14N4O3, is planar with an r.m.s deviation of 0.025 Å from the plane through all 19 non-hydrogen atoms. An intramolecular N—H...O interaction closes an S(6) ring.
Hasna Yassine   +4 more
doaj   +1 more source

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