Design and synthesis of a photoswitchable guanidine catalyst
A novel design as well as a straight-forward synthesis for a photoswitchable guanidine catalyst is reported. Intense studies of the photochromic properties demonstrated the reversible switchability of its photosensitive azobenzene moiety. Its activity in
Philipp Viehmann, Stefan Hecht
doaj +1 more source
Light-induced reversible modification of the work function of a new perfluorinated biphenyl azobenzene chemisorbed on Au (111) [PDF]
This work was financially supported by EC through the Marie-Curie ITN SUPERIOR (PITN-GA-2009-238177) and IEF MULTITUDES (PIEF-GA-2012-326666), the ERC project SUPRAFUNCTION (GA-257305), the Agence Nationale de la Recherche through the LabEx project ...
Cornil, J +8 more
core +2 more sources
Photomodulation of Two-Dimensional Self-Assembly of Azobenzene–Hexa-peri-hexabenzocoronene–Azobenzene Triads [PDF]
Achieving exquisite control over self-assembly of functional polycyclic aromatic hydrocarbons (PAH) and nanographene (NG) is essential for their exploitation as active elements in (nano)technological applications. In the framework of our effort to leverage their functional complexity, we designed and synthesized two hexa-peri-hexabenzocoronene (HBC ...
Ian Cheng-Yi Hou +8 more
openaire +6 more sources
Amphiphilic chloroazobenzenes, bearing different amino acids as end groups alanine, phenylalanine, and valine, exhibit excellent photoisomerizations. Varying structures of three amino acid groups participate in supramolecular formations and therefore photoinduced morphological transformations via adjusting intermolecular interactions. These interaction
Shuangshuang Meng +3 more
wiley +1 more source
A perspective on using experiment and theory to identify design principles in dye-sensitized solar cells [PDF]
Dye-sensitized solar cells (DSCs) have been the subject of wide-ranging studies for many years because of their potential for large-scale manufacturing using roll-to-roll processing allied to their use of earth abundant raw materials.
Abuabara SG +18 more
core +4 more sources
Waveguide Photoactuators: Materials, Fabrication, and Applications
Waveguide photoactuators convert guided light into mechanical motion. Their tethered‐flexible design enables minimally invasive surgery and confined‐space robotics. This review aims to guide materials selection, device design, and system integration, accelerating the transition of waveguide photoactuators from laboratory prototypes to versatile ...
Minjie Xi +4 more
wiley +1 more source
Plasma dye coating as straightforward and widely applicable procedure for dye immobilization on polymeric materials [PDF]
Here, we introduce a novel concept for the fabrication of colored materials with significantly reduced dye leaching through covalent immobilization of the desired dye using plasmagenerated surface radicals.
De Clerck, Karen +9 more
core +3 more sources
Liquid Crystalline Elastomers in Soft Robotics: Assessing Promise and Limitations
Liquid crystalline elastomers (LCEs) are programmable soft materials that undergo large, anisotropic deformation in response to external stimuli. Their molecular alignment encodes directional actuation in a monolithic structure, making them long‐standing candidates for soft robotic systems.
Justin M. Speregen, Timothy J. White
wiley +1 more source
A combinatorial approach to improving the performance of azoarene photoswitches
Azoarenes remain privileged photoswitches – molecules that can be interconverted between two states using light – enabling a huge range of light addressable multifunctional systems and materials.
Joaquin Calbo +4 more
doaj +1 more source
A snap‐top delivery nanosystem based on an azobenzene metal–organic framework achieves targeted release of 6‐mercaptopurine via acid‐stable frameworks and hypoxia/pH dual‐responsive β‐cyclodextrin gates. This multifunctional platform integrates three synergistic mechanisms: precision drug delivery to inflammatory sites, intrinsic antioxidant properties
Xin Li +6 more
wiley +1 more source

