Results 101 to 110 of about 5,608 (248)

Membrane‐Penetrating Molecular Device Based on a Triplex Containing Acyclic L‐Threoninol Nucleic Acid Functionalized with Cholesterol

open access: yesAngewandte Chemie, EarlyView.
A membrane‐penetrating molecular device composed of triplex containing cholesterol‐modified acyclic L‐threoninol nucleic acid (L‐aTNA) was achieved. This device is applied to a photo‐triggered signal transduction system functioning on giant unilamellar vesicles. Abstract Membrane‐penetrating molecular devices are valuable biological tools.
Kaifu Liu   +2 more
wiley   +2 more sources

Polymer-azobenzene complexes: from supramolecular concepts to efficient photoresponsive polymers [PDF]

open access: yes, 2009
Linear and nonlinear optical properties of azobenzene-containing polymers give rise to a range of exciting optical phenomena due to the unique response of the azobenzene chromophores to light fields.
Priimägi, Arri
core  

Light driven reactions of single physisorbed azobenzenes [PDF]

open access: yes, 2011
We present a successful attempt of decoupling a dye molecule from a metallic surface via physisorption for enabling direct photoisomerization. Effective switching between the isomers is possible by exposure to UV light via the rotation pathway.
Bazarnik, Maciej   +3 more
core   +2 more sources

Liquid Crystalline Elastomers in Soft Robotics: Assessing Promise and Limitations

open access: yesAdvanced Robotics Research, EarlyView.
Liquid crystalline elastomers (LCEs) are programmable soft materials that undergo large, anisotropic deformation in response to external stimuli. Their molecular alignment encodes directional actuation in a monolithic structure, making them long‐standing candidates for soft robotic systems.
Justin M. Speregen, Timothy J. White
wiley   +1 more source

Acid‐ and Nucleophile‐Gated Photoisomerization of Phosphaindirubin

open access: yesAngewandte Chemie, EarlyView.
Triply gated isomerization: In polar solvents, a phosphorus‐containing indirubin photoswitch undergoes visible‐light‐driven Z→E isomerization only when protonated, and reverts thermally via nucleophile‐catalyzed back‐isomerization. This three‐way control by light, acid, and nucleophile enables reversible photoisomerization.
Jacob Jan van der Wal   +8 more
wiley   +2 more sources

Photo-induced deformations in azobenzene-containing side-chain polymers: molecular dynamics study

open access: yesCondensed Matter Physics, 2006
We perform molecular dynamics simulations of azobenzene containing side-chain liquid crystalline polymer subject to an external model field that mimicks the reorientations of the azobenzenes upon irradiation with polarized light. The smectic phase of the
J.Ilnytskyi, M.Saphiannikova, D.Neher
doaj   +1 more source

Robotic Materials With Bioinspired Microstructures for High Sensitivity and Fast Actuation

open access: yesAdvanced Science, EarlyView.
In the review paper, design rationale and approaches for bioinspired sensors and actuators in robotics applications are presented. These bioinspired microstructure strategies implemented in both can improve the performance in several ways. Also, recent ideas and innovations that embed robotic materials with logic and computation with it are part of the
Sakshi Sakshi   +4 more
wiley   +1 more source

Electron attachment to trans-azobenzene

open access: yesPhysical Chemistry Chemical Physics, 2009
The temporary anion states of gas-phase trans-azobenzene are characterised by means of electron transmission spectroscopy (ETS) in the 0-6 eV range. The measured energies of vertical electron attachment are compared with the energies of the pi* virtual orbitals of the neutral molecule supplied by HF (at MP2 optimized geometries) and B3LYP calculations.
MODELLI, ALBERTO, P. D. Burrow
openaire   +3 more sources

Precise Regulation of Membrane Proteins: From Physical Technology to Biomolecular Strategy

open access: yesAdvanced Science, EarlyView.
This review summarizes the emerging strategies for the precise regulation of membrane proteins using physical stimuli and biomolecule‐based tools. These methods provide new insights into cell regulation and offer promising directions for future disease treatment.
Xiu Zhao   +6 more
wiley   +1 more source

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