Results 51 to 60 of about 4,038 (213)

Ethyl 1-benzyl-1,2,3,3a,4,10b-hexa-hydro-pyrrolo-[2',3':3,4]pyrrolo-[1,2-a]benzimidazole-2-carboxyl-ate. [PDF]

open access: yes, 2011
The title mol-ecule, C(22)H(23)N(3)O(2), was obtained via an intra-molecular cyclo-addition of an azomethine ylide and an alkene tethered by a benzimidazole unit. The benzoimidazole unit is essentially planar, with an r.m.s.
Fettinger, James C   +2 more
core   +2 more sources

1,1‐Disubstituted Vinylbromides: Versatile Building Blocks for the Synthesis of Nitrogen‐Containing Heterocycles

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer   +6 more
wiley   +1 more source

Enantioselective 1,3-Dipolar Cycloaddition Using (Z)-α-Amidonitroalkenes as a Key Step to the Access to Chiral cis-3,4-Diaminopyrrolidines

open access: yesMolecules, 2022
The enantioselective 1,3-dipolar cycloaddition between imino esters and (Z)-nitroalkenes bearing a masked amino group in the β-position was studied using several chiral ligands and silver salts.
Eduardo García-Mingüens   +5 more
doaj   +1 more source

Strecker degradation of amino acids promoted by a camphor-derived sulfonamide [PDF]

open access: yes, 2016
A camphor-derived sulfonimine with a conjugated carbonyl group, oxoimine 1 (O2SNC10H13O), reacts with amino acids (glycine, L-alanine, L-phenylalanine, L-leucine) to form a compound O2SNC10H13NC10H14NSO2 (2) which was characterized by spectroscopic means
Carvalho, M. Fernanda N. N.   +6 more
core   +4 more sources

Phase‐Transfer‐Catalyzed Interrupted Barton–Zard Reaction Between Electron‐Deficient Indoles and Benzophenone‐Derived Isocyanides

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A cascade reaction under phase‐transfer conditions between 3‐nitro indoles and isocyanomethylene dibenzenes affords the construction of pyrrolo[3,4‐b]indole cores. Control experiments provide insight into moderate product yields and clarify why the reaction is not amenable to asymmetric induction. A cascade reaction enabling the construction of pyrrolo[
Ana Mikleušević   +4 more
wiley   +1 more source

Design, Synthesis, and Structural Evolution of Pseudo‐Natural Product IDO1 Inhibitors and Degraders

open access: yesAngewandte Chemie, Volume 138, Issue 3, 16 January 2026.
The combination of bicyclic monoterpene‐ and pyrrolidine‐alkaloid fragments yields novel pseudo‐natural products. Biological characterization revealed that these iDegs are inhibitors and degraders of indoleamine‐2,3‐dioxygenase. Abstract Terpenoid alkaloids are derived from the fusion of structurally diverse terpenoid‐ and alkaloid moieties.
Xiu‐Fen Cheng   +19 more
wiley   +2 more sources

Chemical Functionalization of Exfoliated Graphene [PDF]

open access: yes, 2013
Graphene is turning out to be the material that will effectively kick-start a new era for nanotechnology. The impressive properties of this atom-thick carbon layer are taking shape and form with early reports of successful applications based on it.
Economopoulos, Solon   +1 more
core   +1 more source

An Azomethine Ylide Approach to Complex Alkaloid-like Heterocycles [PDF]

open access: yesThe Journal of Organic Chemistry, 2007
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
William V, Murray   +3 more
openaire   +2 more sources

Impact of polymer aging on main‐chain poly(fullerene)s with halide chain‐ends for inverted perovskite solar cells

open access: yesPolymer International, EarlyView.
Subtle variations in halogen chemistry significantly affect the aging behavior of polymeric electron transport layers in inverted perovskite solar cells, underscoring the importance of precise chemical design for enhancing long‐term stability. Abstract As perovskite solar cells (PSCs) advance toward commercialization, the need for stable and easily ...
João V. Paulin   +7 more
wiley   +1 more source

The regioselective synthesis of spirooxindolo pyrrolidines and pyrrolizidines via three-component reactions of acrylamides and aroylacrylic acids with isatins and α-amino acids

open access: yesBeilstein Journal of Organic Chemistry, 2014
The regioselective three-component condensation of azomethine ylides derived from isatins and α-amino acids with acrylamides or aroylacrylic acids as dipolarophiles has been realized through a one-pot 1,3-dipolar cycloaddition protocol.
Tatyana L. Pavlovskaya   +6 more
doaj   +1 more source

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