Results 31 to 40 of about 16,002 (187)

Light‐Induced Anion Translocation to Control Helical Folding in an Artificial Communication System

open access: yesChemistry – A European Journal, EarlyView.
Anion‐induced helical folding of an oligomer is controlled indirectly and reversibly by light through anion uptake/release by a photoresponsive receptor. Thus, a light signal is processed into a chemical signal in a communication‐type three‐component supramolecular system.
Indigo M. Bekaert   +5 more
wiley   +1 more source

Towards interlocked structures based on H-bonded barbiturate complexes [PDF]

open access: yes, 2010
Despite the privileged position of Hamilton’s barbiturate binding system in supramolecular chemistry, this motif has never been used in generating interlocked structures, such as rotaxanes or catenanes.
Rocher, Mathias
core  

Baseline characteristics of barbiturate coma therapy.

open access: yes, 2019
Baseline characteristics of barbiturate coma therapy.
Kina Kang (6598082)   +8 more
core   +1 more source

N,N-Diethylanilinium 2,4-dioxo-5-(2,4,6-trinitrophenyl)-1,2,3,4-tetrahydropyrimidin-6-olate

open access: yesActa Crystallographica Section E, 2011
In the crystal structure of the title molecular salt, C10H16N+·C10H4N5O9−, the components are linked through a N—H...O hydrogen bonds. R22(8) ring motifs are formed between inversion-related barbiturate residues.
Manickam Buvaneswari   +1 more
doaj   +1 more source

Electrochemical Synthesis of 5‐Benzylidenebarbiturate Derivatives and Their Application as Colorimetric Cyanide Probe

open access: yesChemElectroChem, 2023
A highly efficient, fast, catalyst‐free, and atom economical method was developed for the synthesis of 5‐benzylidenebarbiturates. Thus, reacting barbituric acid and aldehydes in water as a green solvent under electrochemical conditions afforded the ...
Dr. Yara S. El‐Dash   +3 more
doaj   +1 more source

Organocatalytic Formal (3+2+1)‐Cycloaddition of Allenoates, Michael Acceptors, and Carbaldehydes

open access: yesChemistry – A European Journal, EarlyView.
The use of secondary amine Lewis base organocatalysts allows for the unprecedented activation of allenoates for formal (3+2+1)‐cycloadditions with Michael acceptors and aromatic carbaldehydes. ABSTRACT Employing secondary amines as covalently interacting Lewis basic organocatalysts allows for the activation of electron‐deficient allenes (allenoates ...
David Naderer   +5 more
wiley   +1 more source

5,5-Dihydroxybarbituric acid 1,4-dioxane hemisolvate

open access: yesActa Crystallographica Section E, 2010
The asymmetric unit of the title compound,, C4H4N2O5·0.5C4H8O2, contains one molecule of 5,5-dihydroxybarbituric acid with a nearly planar barbiturate ring and half a molecule of 1,4-dioxane.
Thomas Gelbrich   +2 more
doaj   +1 more source

Exploring Cerumen as an Alternative Matrix for Drug Detection and Quantification: Method Development and Application in Clinical Samples

open access: yesDrug Testing and Analysis, EarlyView.
An LC–MS/MS method was developed for the detection of 33 psychoactive medications in cerumen (earwax) and applied to the samples of 60 psychiatric inpatient volunteers. The findings highlighted the utility of cerumen as an innovative biospecimen in clinical toxicological analysis.
Dimitrios Phaedon Kevrekidis   +5 more
wiley   +1 more source

Vertical gaze palsy in barbiturate intoxication. [PDF]

open access: yes, 1977
Paralysis of conjugate gaze is not a well-recognised sign of barbiturate intoxication in the conscious patient. We describe here the occurrence of a vertical gaze palsy in a patient intoxicated with a medium-acting ...
Mastaglia, F.L., Edis, R.H.
core  

N,N-Diethyl-2-hydroxyethanaminium 2,6-dioxo-5-(2,4,6-trinitrophenyl)-1,2,3,6-tetrahydropyrimidin-4-olate dihydrate

open access: yesActa Crystallographica Section E, 2011
In the title molecular salt, C6H16NO+·C10H4N5O9−·2H2O, which crystallizes as a dihydrate, O—H...O hydrogen bonds link the barbiturate anion, the ethanaminium cation and the water molecules of crystallization.
Manickam Buvaneswari   +1 more
doaj   +1 more source

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