Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer [PDF]
The reduction of a range of substituted azidonitrobenzene derivatives to the corresponding aniline is described. The chemoselective reaction proceeds cleanly and in good yield, generating minimal waste products.
Burnley, James +2 more
core +2 more sources
3‐Hydroxylactams are obtained from phthalimides through a heterogeneous catalyzed chemoselective hydrogenation, able to stop the process at the first hydrogenation level. By using a rationally designed [Ag/Al2O3] recyclable solid nanocatalyst, a wide range of cyclic hemiamidals are accesed through a full atom‐economical reaction that preserves (hetero ...
Carles Lluna‐Galán +2 more
wiley +1 more source
N,N'-1,2-Phenylenebis[4-(chloromethyl)benzamide]
N,N'-1,2-Phenylenebis[4-(chloromethyl)benzamide] (3) was obtained in 61% yield by nucleophilic acyl substitution of 4-(chloromethyl)benzoyl chloride (2) with 1,2-phenylenediamine (1) under basic conditions.
Jürgen Bachl, David D. Díaz
doaj +1 more source
The title compound has been fully characterised by NMR for the first time. Fully assigned 1H and 13C NMR spectra, and the X-ray structure of two different polymorphs are presented. The polymorphs show similar molecular geometries but exhibit significantly different patterns of intermolecular interactions.
R. Alan Aitken +4 more
openaire +2 more sources
Advanced Therapeutic Approach Based on LDHs–Mimetic Oxidoreductase
Overview of Sructure, Multienzyme‐mimicking Activity and Advanced Therapeutic Approach Based on LDHs–Mimetic Oxidoreductase. Abstract Redox dysregulation is recognized as a key driver in the pathophysiology of numerous refractory diseases, contributing significantly to the progression and poor prognosis.
Kai Song +9 more
wiley +1 more source
N,N'-(1,2-Phenylene)-bis[4-(azidomethyl)benzamide]
The synthesis of N,N''-(1,2-phenylene)-bis[4-(azidomethyl)benzamide] (2) by direct nucleophilic disubstitution of the suitable dihalogen precursor 1 with NaN3 is reported.
Jürgen Bachl, David D. Díaz
doaj +1 more source
Structural systematic studies and conformational analyses of a 3x3 isomer grid of fluoro-N-(pyridyl)benzamides; physicochemical correlations, polymorphism and isomorphous relationships [PDF]
The effect of fluorine and pyridine N atom substitution patterns on molecular structure and conformation is probed in a 3 3 isomer grid (Scheme 1) of fluoro-N-(pyridyl)benzamides (Fxx) (C12H9N2OF, x = para-/meta-/ortho-) to evaluate and correlate ...
Gallagher, John F., Mocilac, Pavle
core
A Multipronged Approach Establishes Covalent Modification of β-Tubulin as the Mode of Action of Benzamide Anti-cancer Toxins [PDF]
Juan Manuel Povedano +11 more
openalex +1 more source
Rotaxane Formation With Intramolecular Charge Transfer Properties for Phosphate Sensing
“ON‐OFF” fluorescence array in [1]rotaxane formation for selective phosphate chemosensing. ABSTRACT Mechanically interlocked molecules (MIMs), specifically rotaxanes, have been demonstrated to have immense utility as sensing materials with a wide array of analytes, owing to their unique topologies and properties afforded by the presence of a mechanical
Chi‐Hin Wong +4 more
wiley +1 more source
Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide
In the title compound, C15H14N2O5, the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intramolecular N—H...O hydrogen bond occurs between the imino and methoxy groups.
Mavişe Yaman +5 more
doaj +1 more source

