Results 31 to 40 of about 20,263 (222)
(Figure Presented) At long last, the crystal structure of the metastable form of benzamide, whose existence has been known of for over 170 years, has finally been solved by using a combination of in situ crystallization, high-speed synchrotron X-ray powder diffraction, and global-optimization methods of structure determination (see picture).
W. I. F. David +5 more
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N-(2,6-Dimethylphenyl)benzamide [PDF]
The title compound, C(15)H(15)NO, crystallizes with two mol-ecules in the asymmetric unit. The H-N-C=O units are in a trans conformation, similar to that observed in N-(3,4-dimethyl-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benz-amide and other benzanilides.
B. Thimme Gowda +4 more
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4’-Methyl-2’-(quinolin-8-ylcarbamoyl)-biphenyl-4-carboxylic Acid Ethyl Ester
In this short note communication, we report the synthesis of a novel amide 4’-methyl-2’-(quinolin-8-ylcarbamoyl)-biphenyl-4-carboxylic acid ethyl ester by the Ru-catalyzed C(sp2)-H bond arylation reaction.
Hamad H. Al Mamari, Anfal Al Hasani
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N-(4-Ferrocenylphenyl)benzamide [PDF]
In the title compound, [Fe(C(5)H(5))(C(18)H(14)NO)], the unsubstituted cyclo-penta-dienyl ring is disordered over two sets of sites with occupancy ratio of 0.55 (1):0.45 (1). One conformation has the rings eclipsed and the other staggered. An intra-molecular C-H⋯O hydrogen bond forms an S(6) ring motif.
Ataf Ali Altaf +3 more
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The continuously increasing global impact of fungal infections is requiring the rapid development of novel antifungal agents. Due to their multiple pharmacological activities, thiourea derivatives represent privileged candidates for shaping new drugs. We
Carmen Limban +8 more
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5-(4H)-Oxazolones and Their Benzamides as Potential Bioactive Small Molecules
The five membered heterocyclic oxazole group plays an important role in drug discovery. Oxazolones present a wide range of biological activities. In this article the synthesis of 4-substituted-2-phenyloxazol-5(4H)-ones from the appropriate substituted ...
Evangelos Mavridis +3 more
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Recent Advances in Homogeneous Metal-Catalyzed Aerobic C–H Oxidation of Benzylic Compounds [PDF]
Csp(3)-H oxidation of benzylic methylene compounds is an established strategy for the synthesis of aromatic ketones, esters, and amides. The need for more sustainable oxidizers has encouraged researchers to explore the use of molecular oxygen.
Domínguez Pérez, Pilar Esther +3 more
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N-(3-Methylphenyl)benzamide [PDF]
The asymmetric unit of the title compound, C(14)H(13)NO, contains four mol-ecules, which are linked through N-H⋯O hydrogen bonds into two symmetry-independent chains running parallel to [001] and [101]. The N-H and C=O bonds of the amide groups are trans oriented in all four mol-ecules.
B. Thimme Gowda +3 more
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2-(Methylsulfinyl)benzamide [PDF]
In the crystal of the title compound, C(8)H(9)NO(2)S, synthesized by the oxidation of 2-(methyl-sulfan-yl)benzamide using NaOCl with 2,2,6,6-tetra-methyl-piperidyl-1-oxy (TEMPO) as the catalyst, mol-ecules are linked via inter-molecular N-H⋯O(amide) hydrogen bonds, forming centrosymmetric amide-amide dimers which are extended into a two-dimensional ...
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N-(2-Nitrophenyl)benzamide [PDF]
In the title compound, C(13)H(10)N(2)O(3), the central C-C(=O)-N-C amide unit makes dihedral angles of 21.68 (4) and 19.08 (4)°, respectively, with the phenyl and nitro-benzene rings. The two aromatic rings are inclined at 3.74 (3)° and the nitro group is skewed out of the attached benzene ring plane by 18.55 (8)°. An intra-molecular N-H⋯O inter-action
Aamer Saeed, Jim Simpson
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