Sodium benzoate and potassium sorbate preservatives in food stuffs in Iran [PDF]
A high-performance liquid chromatography method was applied for the determination of the levels of benzoate and sorbate in 400 food samples, including pickled cucumbers, canned tomato pastes, sour cherry jams, soft drinks, fruit juices and dairy products
Akbari Azam, M.+4 more
core
Computational Modeling of Reticular Materials: The Past, the Present, and the Future
Reticular materials are advanced materials with applications in emerging technologies. A thorough understanding of material properties at operating conditions is critical to accelerate the deployment at an industrial scale. Herein, the status of computational modeling of reticular materials is reviewed, supplemented with topical examples highlighting ...
Wim Temmerman+3 more
wiley +1 more source
Iridium‐Catalyzed Reductive Deoxygenation of Esters for the Synthesis of Sterically Hindered Ethers
A general method for accessing sterically hindered ethers via reductive deoxygenation of readily prepared ester starting materials is reported. Employing commercially available and bench‐stable IrCl(CO)(P[OCH(CF3)2]3)2 (1–2 mol%) and tetramethyldisiloxane (TMDS) as reductant, this single‐vessel approach operates under mild conditions and provides a ...
Yaseen A. Almehmadi+3 more
wiley +2 more sources
Selective Oxidation of Xylenes to Toluic Acids [PDF]
A mixture of manganese, cobalt and lead para-amino benzoates supported on silica gel is used to catalyze oxidation of xylenes to toluic acids in presence of oxygen or air. Reactions are clean and catalysts can be recovered easily and reused.
Mohammad M. Hashemi, Nasrin Manuchehri
doaj
Effect of silica colloids on the rheology of viscoelastic gels formed by the surfactant cetyl trimethylammonium tosylate [PDF]
The effects of the addition of sub-micrometer sized colloidal silica spheres on the linear and nonlinear rheology of semi-dilute solutions of a viscoelastic gel are studied.
Bandyopadhyay, R., Sood, A. K.
core +2 more sources
Structural Control of Photoconductivity in a Flexible Titanium‐Organic Framework
The concept of flexibility is extended to titanium frameworks and use it to gain control over charge transport. MUV‐35 is a flexible doubly interpenetrated framework that can shrink spontaneously its volume by ≈40% to afford a photoconductive, porous state that is thermodynamically favored by non‐covalent interactions. Abstract The soft nature of Metal‐
Clara Chinchilla‐Garzón+6 more
wiley +1 more source
Electrochemical Deoxygenative Silylation of Alcohols
Herein, electroreductive deoxysilylation of benzylic and allylic alcohols is demonstrated. The cathodic transformation proceeds via carbanionic intermediates and can be extended to aldehydes and ketones. Mechanistic studies reveal that the reaction outcome is dependent on the thermodynamics and kinetics for the coupling step in combination with the ...
Piret Villo+7 more
wiley +2 more sources
Electrogenerated N-Heterocyclic Carbene in Ionic Liquid: An Insight into the Mechanism of the Oxidative Esterification of Aromatic Aldehydes [PDF]
An N-heterocyclic carbene (NHC), generated by cathodic reduction of BMImBF4, mediates the oxidative esterification of aromatic aldehydes with organic bromides in the corresponding ionic liquid as solvent. The product recovery by simple extractive work-up
CHIAROTTO, Isabella+4 more
core +1 more source
Adsorption and Separation by Flexible MOFs
Flexible metal–organic frameworks (MOFs) present significant potential for gas storage and separation due to their structural dynamic. This review explores the rationale behind the flexible MOFs' enhanced working capacity and separation factors. It also addresses key challenges, including phase transition kinetics, crystal robustness, cycling, shaping,
Irena Senkovska+4 more
wiley +1 more source
2,6-Dichlorophenyl 4-methylbenzoate
The structure of the title compound (26DCP4MeBA), C14H10Cl2O2, resembles those of phenyl benzoate (PBA), 2,6-dichlorophenyl benzoate (26DCPBA), 2,4-dichlorophenyl 4-methylbenzoate (24DCP4MeBA) and other aryl benzoates, with similar bond parameters.
Hartmut Fuess+3 more
doaj +1 more source