Results 81 to 90 of about 11,623 (281)

Rewriting Polymer Fate via Chemomechanical Coupling

Advanced Materials, EarlyView.
This work introduces a life‐like “living” polymer platform that can grow, degrow, and reprogram its properties after fabrication. By integrating mass transport, reversible polymerization, and controlled catalysis, the material achieves on‐demand changes in size, shape, and mechanical properties.
Jiahe Huang, Haohui Zhang, Jiehao Chen, Xuelin Sui, Febby Krisnadi, Dongjing He, Huajian Ji, Will R. Gutekunst, Michael D. Dickey, Yuhang Hu   +9 more
wiley   +1 more source

Mechanism‐Guided Precision Hydrolysis of Early Transition Metals to Access (Mixed‐Metal) Oxo Clusters

Angewandte Chemie, EarlyView.
Precision hydrolysis enables the rational, room‐temperature synthesis of Zr and Hf oxo clusters with improved atom economy, sustainable solvents, and gram‐scale yields. By adding exactly 1.33 equivalents of water, Zr6, Hf6, and elusive bimetallic clusters are accessed, alongside new group 5 oxo clusters, providing a versatile and economical platform ...
Muhammed Jibin Parammal, Jikson Pulparayil Mathew, Alessandro Prescimone, Ajmal Roshan Unniram Parambil, Harry Wilson, Jonathan De Roo   +5 more
wiley   +2 more sources

3-Chlorophenyl 4-methylbenzoate

Acta Crystallographica Section E, 2008
The crystal structure of the title compound 3CP4MBA, C14H11ClO2, resembles those of 3-methylphenyl 4-methylbenzoate (3MP4MBA), 4-methylphenyl 4-methylbenzoate (4MP4MBA), 4-methylphenyl 4-chlorobenzoate (4CP4MBA) and other aryl benzoates with similar bond
B. Thimme Gowda, Sabine Foro, K. S. Babitha, Hartmut Fuess   +3 more
doaj   +1 more source

Benzofuranyl Esters: Synthesis, Crystal Structure Determination, Antimicrobial and Antioxidant Activities [PDF]

, 2015
A series of five new 2‐(1‐benzofuran‐2‐yl)‐2‐oxoethyl 4-(un/substituted)benzoates 4(a–e), with the general formula of C8H5O(C=O)CH2O(C=O)C6H4X, X = H, Cl, CH3, OCH3 or NO2, was synthesized in high purity and good yield under mild conditions.
C. S., Chidan Kumar, Chandraju, Siddegowda, Ching, Kheng Quah, Fun, Hoong Kun, Hashim, Nurul Shafiqah, Kheng, Leong Ooi, Li, Yee Then, Sulaiman, Shaida Fariza, Tze, Shyang Chia, Win, Yip Foo   +9 more
core   +1 more source

2D MOF with Intrinsic Porosity for Colorimetric Volatile Organic Compounds (VOCs) Detection

Advanced Materials, EarlyView.
An uncommon 2D MOF with intrinsic in‐plane porosity that can be mechanically exfoliated undergoes a distinct and reversible colour change upon exposure to various volatile organic compounds. ABSTRACT In this work, we report an uncommon 2D metal–organic framework (MOF) with intrinsic in‐plane porosity that undergoes a distinct and reversible colour ...
Sergio R. Gamarra, Alberto Fernández‐Alarcón, Joaquín Calbo, Enrique Ortí, Guillermo Mínguez Espallargas   +4 more
wiley   +1 more source

NiH‐Catalyzed Enantioconvergent α‐Alkenylation of Carbonyl Compounds via Markovnikov Alkyne Hydronickellation

Angewandte Chemie, EarlyView.
A NiH‐catalyzed α‐alkenylation via Markovnikov hydronickellation of alkynes enables convenient access to α‐chrial β‐methylene carbonyl frameworks that are prevalent in biorelevant molecules. High regio‐ and enantioselectivities have been achieved with excellent functional group tolerance and applicability toward complex structures. The β‐methylene unit
Hyeontaek Nam, Seji Jang, Dongwook Kim, Sangwon Seo   +3 more
wiley   +2 more sources

Iridium-catalysed ortho-directed deuterium labelling of aromatic esters – an experimental and theoretical study on directing group chemoselectivity [PDF]

, 2015
Herein we report a combined experimental and theoretical study on the deuterium labelling of benzoate ester derivatives, utilizing our developed iridium N-heterocyclic carbene/phosphine catalysts.
Devlin, Jennifer, Kerr, William J., Lindsay, David M., McCabe, Timothy J.D., Reid, Marc, Tuttle, Tell   +5 more
core   +2 more sources

Self‐Assembled Monolayers in p–i–n Perovskite Solar Cells: Molecular Design, Interfacial Engineering, and Machine Learning–Accelerated Material Discovery

Advanced Materials, EarlyView.
This review highlights the role of self‐assembled monolayers (SAMs) in perovskite solar cells, covering molecular engineering, multifunctional interface regulation, machine learning (ML) accelerated discovery, advanced device architectures, and pathways toward scalable fabrication and commercialization for high‐efficiency and stable single‐junction and
Asmat Ullah, Ying Luo, Stefaan De Wolf
wiley   +1 more source

The rodent uterotrophic assay: Critical protocol features, studies with nonyl phenols, and comparison with a yeast estrogenicity assay [PDF]

, 1997
The major protocol features of the immature rat uterotrophic assay have been evaluated using a range of reference chemicals. The protocol variables considered include the selection of the test species and route of chemical administration, the age of the ...
Ashby, J, Beresford, NA, Lefevre, PA, Odum, J, Paton, D, Routledge, EJ, Sumpter, JP, Tittensor, S   +7 more
core   +2 more sources

Multifunctional Oxadiazole‐Based Polycatenars: A Pathway to Polar Columnar Phases

Advanced Materials Interfaces, EarlyView.
Aromatic core fluorination directs oxadiazole‐based polycatenars into ferroelectric and antiferroelectric columnar phases with supergelation and photo‐responsiveness. ABSTRACT Polar columnar liquid crystals (LCs) offer a promising pathway to nanostructured architectures for next‐generation ferroelectric devices.
Yu Cao, Tejal Nirgude, Jonathan Jende, Alexander Jarosik, Alexey Eremin, Feng Liu, Masafumi Yoshio, Mohamed Alaasar   +7 more
wiley   +1 more source