Results 101 to 110 of about 8,390 (243)
Emerging Trends in Organic Photoreactions Utilizing Disulfides
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar +3 more
wiley +1 more source
Ultrasound promoted green synthesis of benzofuran substituted thiazolo[3,2-b][1,2,4]triazoles
A highly efficient, eco-friendly and one-pot synthesis of benzofuran substituted thiazolo[3,2-b][1,2,4]triazoles was developed involving the reaction of 2-acetyl benzofurans and 5-mercapto-3-(4-chlorophenyl)-1,2,4triazole in the presence of molecular ...
Kumar Surender, Sharma Dinesh Kumar
doaj +1 more source
Plasmin Regulation through Allosteric, Sulfated, Small Molecules [PDF]
Plasmin, a key serine protease, plays a major role in clot lysis and extracellular matrix remodeling. Heparin, a natural polydisperse sulfated glycosaminoglycan, is known to allosterically modulate plasmin activity.
Al-Horani, Rami A. +3 more
core +3 more sources
The catalytic carbonylation of alkynes is a powerful route to heteroaromatic scaffolds, yet achieving regioselectivity remains challenging. Herein, we report a divergent carbonylative cyclization of 2‐alkynylphenol derivatives that affords either coumarins (6‐endo‐dig) or 2‐coumaranones (5‐exo‐dig) by tuning the palladium‐based catalytic system. Pd(OAc)
Aleksandr Voronov +11 more
wiley +1 more source
Biochemical, haematological and histopathological studies of extract of Ageratum conyzoides L. in Sprague Dawley rats [PDF]
This study was conducted to evaluate the safety potential of the leaf extract of Ageratum conyzoides Linnaeus in Sprague Dawley (SD) rats using biochemical, haematological and histological indices of toxicity.
Adebayo, H. A. +9 more
core +2 more sources
The use of transition‐metal catalysts and design of chiral ligands have allowed chemists to access highly functionalized benzofused 5‐ and 6‐ membered rings in high yield and enantioselectivity. A common strategy used relies on an intermolecular carbometalation across alkynes and olefins, usually followed by a subsequent intramolecular carbometalation.
Clara Jans +3 more
wiley +1 more source
Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP
An operationally simple protocol using a strongly basic sodium amide in combination with sterically emcumbered silicon electrophiles enables the deprotonative C–H (multi)silylation of a myriad of (hetero)arenes. Mechanistic investigations highlight the pivotal role of steric and coordination effects in controlling the regioselectivity and efficiency of
David Sánchez‐Roa +6 more
wiley +2 more sources
A rhodium(I)-catalyzed domino-type sequential 5-endo/5-exo cyclization reaction of [(2-acylphenyl) ethynyl]phenols produces indene/benzofuran-fused alcohols.
Takanori Matsuda +5 more
doaj +1 more source
Novel Pt catalysts supported on zeolitic silicoaluminophosphate efficiently promoted the hydrogenative conversion of furoic acid to δ‐valerolactone under mild conditions. High activity arose from finely dispersed Pt nanoparticles stabilized by the porous support. Mechanistic studies indicated site‐selective partial hydrogenation followed by Csp²–O bond
Haruro Ishitani +3 more
wiley +1 more source
A Pd‐catalyzed regioselective synthesis of benzylsilanols from Kobayashi‐type reagents has been developed through a mechanistically distinct approach involving 1,4‐Pd migration followed by intramolecular transmetalation. The reaction can be combined with various prior transition‐metal‐catalyzed processes and the resulting benzylsilanols have been ...
Ryo Shintani, Keisuke Tachibana
wiley +2 more sources

