Results 101 to 110 of about 6,146 (188)
Eine divergente Aldehyd‐Funktionalisierungssequenz, ermöglicht durch ein anomeres Amid, erlaubt den Ein‐Topf‐Zugang zu unsymmetrischen Harnstoffen, Carbamaten, Thiocarbamaten, Thioestern und Amiden. Entscheidend für diese Transformation ist die Bildung von N‐Boc‐Hydroxamat‐Intermediaten, die als Plattformen für eine orthogonale Aktivierung über Lossen ...
Jasper L. Tyler +6 more
wiley +1 more source
An anomeric amide‐enabled divergent aldehyde functionalization sequence provides one‐pot access to unsymmetrical ureas, carbamates, thiocarbamates, thioesters, and amides. Key to this transformation is the formation of N‐Boc‐hydroxamate intermediates, which serve as platforms for orthogonal activation via Lossen‐type rearrangements, single‐electron ...
Jasper L. Tyler +6 more
wiley +1 more source
Revised Formal Total Synthesis of Dehydro-δ-Viniferin and Anigopreissin A
This work presents a revised total synthesis of two pharmacologically relevant benzofurans using newly developed environmentally friendly methodologies.
Alessandro Santarsiere +2 more
doaj +1 more source
Correction to Iridium-Catalyzed Hydrogen Transfer: Synthesis of Substituted Benzofurans, Benzothiophenes, and Indoles from Benzyl ...
Kai Rossen (1458208) +4 more
core +1 more source
This review presents the visible‐light‐mediated photochemical reaction for the synthesis of aza, oxa, and aza–oxa spirocyclic compounds via photoinduced electron transfer (PET), hydrogen atom transfer (HAT), single‐electron transfer (SET), or energy transfer (EnT) pathways.
Annu Bhardwaj +4 more
wiley +1 more source
Endophytic Fungi Natural Factories of Novel Bioactive Compounds
This review provides a systematic analysis of 242 natural products isolated from 42 genera of endophytic fungi, highlighting their remarkable structural diversity and broad spectrum of biological activities . ABSTRACT Endophytic fungi represent a prolific and chemically diverse source of novel specialized metabolites with significant pharmacological ...
Dilmurod Murodullayev +18 more
wiley +1 more source
Tandem [4 + 2]/[2 + 2] Cycloaddition Reactions Involving Indene or Benzofurans and Arynes
The reaction of arynes with indene/benzofurans has been developed. The arynes were generated from 2-(trimethylsilyl)aryl triflates by the fluoride-induced 1,2-elimination react with indene or various benzofurans proceeding via a cascade reaction ...
Sachin Suresh Bhojgude (1458001) +3 more
core +1 more source
Antioxidant Chemistry of Phenolics in Chinese Herbal Medicines: A Holism‐Based Review
Phenolic antioxidants in CHMs mainly include chalcone, stilbene, flavonoid, xanthone, and Diels–Alder‐type adducts. They undergo direct and indirect pathways to exert antioxidant action. The indirect pathway is transition metal‐chelating, while the direct pathway comprises several redox‐based reactions (e.g., SET and HAT) and RAF reactions.
Xican Li
wiley +1 more source
Synthesis of functionalized polyfluorinated biphenyl moieties via one‐pot Heck coupling followed by temperature‐controlled cyclization reaction of polyfluoro diene intermediate. The cyclization reaction proceeds via a palladium‐catalyzed β‐fluoro elimination step.
Bálint Varga +7 more
wiley +1 more source
The front cover image demonstrates how seasonal environmental factors influence the phenolic composition and bioactivity of Piptadenia gonoacantha leaves. The visual elements represent ultrasound‐assisted extraction and chromatographic separation, while the light and natural images reflect how solar radiation and phenological stage directly influence ...
Nicole Werle da Silva +5 more
wiley +1 more source

