Counterion Effects on the Properties and Reactivity of Charged Photoredox Catalysts
The choice of a counterion for a charged photocatalyst has long been overlooked. In this review, we summarize recent reports on counterion effects in photocatalysis, providing readers with a comprehensive theoretical understanding and synthetic applications for the use of a carefully chosen counterion. Electrostatic interactions represent the strongest
Elina K. Taskinen, Burkhard König
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Push-pull benzophenone derivative-based visible photoinitiating systems: synthesis, characterization, properties, and application for free radical photopolymerization under LEDs. [PDF]
Wu Q, Guo J, Deng M, Li F.
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Gold(I) Phosphine/Phosphido‐Borohydride Complexes
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair +3 more
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Studies toward Pestalachloride B: Synthesis of the 6/7/6 Tricyclic Scaffold. [PDF]
Deprez BE +4 more
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Bio‐derived lignin–Eosin Y macromolecular networks are developed as visible‐light‐responsive self‐sterilizing coatings that generate reactive oxygen species without leaching. The spray‐coated photopolymerized surfaces exhibit durable antibacterial and antiviral activity under ambient light for extended periods, demonstrating a scalable and sustainable ...
Euna Oh +7 more
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A renewable glucose-derived methacrylate monomer for photopolymerization: synthesis, copolymerization with MMA, and structure-property relationships. [PDF]
Un RN, Saltan F, Kok G.
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Trifluoromethylation‐Induced Lactonization: A Novel Transformation of Unsaturated Carboxylic Acids
Fluorinated drugs often contain trifluoromethyl groups. The increasing importance of such drugs has resulted in more and more attention toward new or improved trifluoromethylation reactions. This review discusses possible reaction mechanisms and existing methods for one such process, trifluoromethylation‐induced lactonization, a distant relative of the
Attila M. Remete
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Photochromic carbazole photoinitiators for precision visible‐light photopolymerization
New carbazole–naphthopyran derivatives were employed as visible‐light‐activated photoinitiators, enabling rapid and localized radical photopolymerization to produce well‐defined thin solid objects within minutes. Abstract Two carbazole derivatives, each incorporating a naphthopyran unit and an aromatic ketone, were synthesized and evaluated as ...
Mauro Magalhães +3 more
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Association of exposure to synthetic phenols and metal(loid)s with early puberty in Spanish girls: a multicentric case-control study. [PDF]
Olivas-Martinez A +13 more
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Photochemistry of N‐Substituted, N′‐Tosyl Diphenyl Sulfondiimines
The irradiation of N‐substituted, N′‐tosyl diphenyl sulfondiimines with UV light induces the sequential photorelease of two different nitrenes. ABSTRACT Sulfondiimines are an emerging sulfur(VI) functional group with increasing use in synthesis and medicinal chemistry, yet their photochemical behavior has remained largely unexplored.
Bashar Aziz +3 more
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