Results 81 to 90 of about 42,640 (273)

Method for forming pyrrone molding powders and products of said method [PDF]

open access: yes, 1972
The formation of pyrrone resins of the ladder or semiladder structure is described. The technique involves initial formation of fully cyclized prepolymers having an average degree of polymerization of about 1.5, one with acidic terminal groups, another ...
Hughes, C. T., Mchenry, R. J.
core   +1 more source

On the strong difference in reactivity of acyclic and cyclic diazodiketones with thioketones: experimental results and quantum-chemical interpretation [PDF]

open access: yes, 2015
The 1,3-dipolar cycloaddition of acyclic 2-diazo-1,3-dicarbonyl compounds (DDC) and thioketones preferably occurs with Z,Econformers and leads to the formation of transient thiocarbonyl ylides in two stages.
Holleman   +8 more
core   +4 more sources

PHOTOINTERACTION OF BENZOPHENONE TRIPLET WITH LYSOZYME

open access: yesPhotochemistry and Photobiology, 1989
AbstractThe quenching of the benzophenone triplet by lysozyme and its constituent amino acids in aqueous solutions have been studied. Native lysozyme quenches the benzophenone triplet with a high rate constant, 4 × 109M‐1s‐1. The quenching process takes place with production of significant amounts of free ketyl radicals, φketyl=0.56, but with a very ...
ENCINAS, MV   +4 more
openaire   +3 more sources

Glyoxylic‐Acetal‐Based Gel‐Polymer Electrolytes for Lithium‐Ion Batteries

open access: yesBatteries &Supercaps, Volume 8, Issue 3, March 2025.
A safe electrolyte based on tetraethoxyglyoxal (LE) is combined with a methacrylate polymer matrix. The resulting gel‐polymer electrolyte (GPE) exhibits an increased flash point, suitable ionic conductivity, and a stable performance in lithium‐ion battery cells.
Christian Leibing   +4 more
wiley   +1 more source

Three cases of photoallergic contact dermatitis induced by the ultraviolet absorber benzophenone that occurred after dermatitis due to ketoprofen‐Investigation of cosensitization with other ultraviolet absorbers and patient background

open access: yesJournal of Cutaneous Immunology and Allergy, 2019
Objectives Three teenage patients developed dermatitis at the site of contact of a free‐pass wristband from an amusement park. Each had experienced dermatitis due to ketoprofen.
Tomoko Tanahashi   +3 more
doaj   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

New Ent-Kaurane-Type Diterpene Glycosides and Benzophenone from Ranunculus muricatus Linn.

open access: yesMolecules, 2015
Two new ent-kaurane diterpene glycosides, ranunculosides A (1) and B (2), and a new benzophenone, ranunculone C (3), were isolated from the aerial part of Ranunculus muricatus Linn. The chemical structures of compounds 1–3 were established to be (2S)-ent-
Bi-Ling Wu   +4 more
doaj   +1 more source

Arene Incorporation and Ring Expansion in the Thermal Decomposition of a Divanadium(III) Complex With Four Bridging Methyl Groups

open access: yesChemistry – A European Journal, EarlyView.
Thermolysis of [{VCp*(µ‐CH3)2}2] (Cp* = η5‐C5Me5) in hexane leads to a tetranuclear cube‐type methylidene complex [{VCp*(µ3‐CH2)}4], while in benzenic solvents C6H5R produces the formal insertion of a CH fragment into the six‐membered aromatic ring of a solvent molecule to give trovacene derivatives with η7‐cycloheptatrienyl ligands [VCp*(η7‐C7H6R ...
Adrián Calvo‐Molina   +5 more
wiley   +1 more source

Unveiling the Triplet-State Interaction Mechanism Between 4-Carboxybenzophenone and 2-Naphthalene Sulfonate—A Laser Flash Photolysis Study

open access: yesPhotochem
This communication aims to comprehensively elucidate the intricate mechanism governing the interaction between the excited triplet state of 4-Carboxybenzophenone (CB*) and the anionic form of 2-Naphthalene Sulfonate (NpSO3−), employing the 337 nm ...
Piotr Filipiak   +3 more
doaj   +1 more source

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