Results 71 to 80 of about 4,664 (217)

C–N bond formation between alcohols and amines using an iron cyclopentadienone catalyst [PDF]

, 2015
An iron-tetraphenylcyclopentadienone tricarbonyl complex is demonstrated to act as a precursor of a catalyst for the formation of C–N bonds through a “hydrogen-borrowing” reaction between amines and ...
Diorazio, Louis J., Rawlings, Andrew J., Wills, Martin   +2 more
core   +1 more source

Synthesis and Characterization of π‐Extended Azulenes via Nucleophilic Substitution and Intramolecular Cyclization of 5‐Alkynyl‐6‐Fluoroazulenes

ChemistryEurope, EarlyView.
A modular synthetic approach enables the preparation of azulene‐fused heterocycles via nucleophilic aromatic substitution followed by intramolecular cyclization of alkynyl fluoroazulenes. The method allows the incorporation of various heteroatoms (N, O, S, Se, and Te), leading to structurally diverse heteroannulated azulenes.
Martin C. Dietl, Matthias Scherr, Christopher Hüßler, Henrik T. Habeck, Carmen L. M. Henel, Jürgen Graf, Frank Rominger, Matthias Rudolph, A. Stephen K. Hashmi   +8 more
wiley   +1 more source

Stafib‐2‐CR: an Improved Nanomolar and Selective Inhibitor of the Transcription Factor STAT5b Developed by Conformational Restriction of Stafib‐2

Chemistry – A European Journal, EarlyView.
Conformational restriction strategies to increase the activity and selectivity of the STAT5b inhibitor Stafib‐2 are presented. The best conformationally restricted inhibitor Stafib‐2‐CR has threefold higher activity against STAT5b than Stafib‐2. A cell‐permeable prodrug of Stafib‐2‐CR inhibits phosphorylation of STAT5b in cultured human leukemia cells ...
Theresa Münzel, Angela Berg, Christoph Protzel, Sylvie Schäfer, Alexander Jensen‐Feinhals, Thorsten Berg   +5 more
wiley   +1 more source

AIEE Active Nanoassemblies of Pyrazine Based Organic Photosensitizers as Efficient Metal-Free Supramolecular Photoredox Catalytic Systems

Scientific Reports, 2019
Pyrazine derivatives DIPY, TETPY and CNDIPY have been designed and synthesized which form fluorescent supramolecular assemblies in mixed aqueous media due to their AIEE and ICT characteristics.
Shruti Dadwal, Harnimarta Deol, Manoj Kumar, Vandana Bhalla   +3 more
doaj   +1 more source

Synthesis and disinfection effect of the pyridine-4-aldoxime based salts [PDF]

, 2015
PubMed ID: 25719739A set of new quaternary ammonium compounds based on pyridine-4-aldoxime was synthesized, characterized with analytical data (NMR, EA, HPLC, MS) and tested for in vitro antimicrobial activity (antibacterial, antifungal) and cytotoxicity.
Doležal, Martin, Doležal, Rafael, Kuča, Kamil, Maliňák, David, Marek, Jan, Pasdiorová, Markéta, Soukup, Ondřej   +6 more
core   +3 more sources

Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis

Chemistry – A European Journal, EarlyView.
Mechanochemistry offers a sustainable, solvent‐free alternative to traditional synthesis, often enhanced by additives in a process known as additive‐assisted grinding. This review discusses how various additives, including liquids, ionic solids, and advanced materials like ionic liquids and piezoelectric compounds, improve reaction efficiency ...
Johanna Breinsperger, Nika Podlesnik, Francesco Mele, Michael Schnürch   +3 more
wiley   +1 more source

Activity of 6-aryl-pyrrolo[2,3-d]pyrimidine-4-amines to Tetrahymena [PDF]

, 2012
A series 6-aryl-pyrrolo[2,3-d]pyrimidine-4-amines (43 compounds), some of which are epidermal growth 22 factor tyrosine kinase inhibitors, were tested for their protozoal toxicity using an environmental Tetrahy- 23 mena strain as model organism.
Charnock, Colin, Hoff, Bård Helge, Kaspersen, Svein Jacob, Sundby, Eirik   +3 more
core   +4 more sources

Synthesis and characterization of amphiphilic nitroxide 1,1,3,3–tetraethylisoindoline–2–oxyl–5–sodium sulfonate (TEIOSNa)

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract The synthesis and characterization of an amphiphilic nitroxide to be used as a controlling agent in a nitroxide‐mediated living radical polymerization in aqueous dispersion media is presented. In the first stage of nitroxide synthesis (phthalimide protection), two reaction methods were employed: traditional and microwave.
Enrique García‐Leal, Martha Eugenia Albores Velasco, René O. Vargas, Rubén Mil‐Martínez   +3 more
wiley   +1 more source

Synthesis of 4-styrylquinazolines enabled by a hypervalent iodine-promoted oxidative amination cascade

Tetrahedron Chem
Efficient synthetic routes to pharmaceutically important 4-styrylquinazolines scaffolds are of considerable interest. Herein, we report a concise synthesis of 4-styrylquinazoline derivatives via a hypervalent iodine-promoted oxidative amination cascade ...
Lipeng Long, Ziyi Yu, Ziwen Huang, Min Ye, Wenjun Luo, Xunjin Jiang, Zhengwang Chen, Zhong-Xia Wang   +7 more
doaj   +1 more source

Pt Sub‐Nanoclusters on ZIF‐Derived Ultrafine CdxZn1−xS Solid Solution: High‐Performance Photoreforming Lactic Acid to H2 and Value‐Added Chemicals

Electron, EarlyView.
This work presents ZIF‐derived ultrafine CdxZn1−xS decorated with Pt sub‐nanoclusters for efficient photocatalytic reforming of lactic acid. The catalyst achieves high H2 evolution (270.6 mmol h−1 g−1) and selective pyruvic acid production (73.1%), with mechanistic insights revealing Pt‐mediated control over reaction pathways.
Feng Liu, Yi Wang, Chunyang Zhang, Zhongyuan Li, Xiaojing Ma, Maochang Liu   +5 more
wiley   +1 more source