Results 11 to 20 of about 2,581 (118)

Application of deuterated THENA for assigning the absolute configuration of chiral secondary alcohols [PDF]

, 2019
The structure of a constrained bicyclic CDA, 1,2,3,4-tetrahydro-1,4-epoxynaphthalene-1-carboxylic acid, THENA 1, was modified by replacing both exo-methylene protons with deuterium atoms.
Thongpanchang, Chawanee, Soponpong, Jakapun, Dolsophon, Kulvadee, Linden, Anthony; https://orcid.org/, Thongpanchang, Tienthong; https://orcid.org/   +4 more
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Extreme halophilic alcohol dehydrogenase mediated highly efficient syntheses of enantiopure aromatic alcohols [PDF]

, 2017
Enzymatic synthesis of enantiopure aromatic secondary alcohols (including substituted, heteroaromatic and bicyclic structures) were carried out using the halophilic alcohol dehydrogenase ADH2 from Haloferax volcanii (HvADH2).
Francesca Paradisi, Alsalman, Safaa, Alsafadi, Diya, Paradisi, Francesca, Diya Alsafadi, Safaa Alsalman   +5 more
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Efficient Aerobic Oxidation of Secondary Alcohols at Ambient Temperature with an ABNO/NO_x Catalyst System

, 2016
New highly practical methods are presented for aerobic oxidation of secondary alcohols with a nitroxyl radical in combination with HNO3, NaNO2, or both as cocatalysts. Diverse nitroxyls are compared, including several novel bicyclic derivatives. Catalyst
Shannon S. Stahl (1291731), Markus B. Lauber (1891699)   +1 more
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Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects

, 2015
Bicyclic nitroxyl derivatives, such as 2-aza­adamantane N-oxyl (AZADO) and 9-aza­bicyclo­[3.3.1]­nonane N-oxyl (ABNO), have emerged as highly effective alternatives to TEMPO-based catalysts for selective oxidation reactions (TEMPO = 2,2,6,6-tetra­methyl ...
Shannon S. Stahl (1291731), Kelsey C. Miles (1474579), Mohammad Rafiee (1474582)   +2 more
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Identification of the Optimal Framework for Nitroxyl Radical/Hydroxylamine in Copper-Cocatalyzed Aerobic Alcohol Oxidation

, 2023
8-Azabicyclo[3.2.1]octan-8-ol (ABOOL) and 7-azabicyclo[2.2.1]heptan-7-ol (ABHOL) are the main homologues of hydroxylamine 2-azaadamantan-2-ol (AZADOL) and 9-azabicyclo[3.3.1]nonan-9-ol.
Katsuhiko Sato, Masaya Takahashi (74318), Masaki Toda, Masaya Takahashi, Koki Kasabata, Shogo Fujiki, Shogo Fujiki (10692093), Katsuhiko Sato (1767925), Tetsuya Ono (2405377), Yusuke Sasano (1703623), Koki Kasabata (5754449), Yoshiharu Iwabuchi (1389561), Yusuke Sasano, Yoshiharu Iwabuchi, Yoshitomo Kashiwagi (2706976), Tetsuya Ono, Yoshitomo Kashiwagi, Masaki Toda (10150496)   +17 more
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Enzimas imobilizadas em crisotila e organogel: aplicação na resolução de acidos racemicos [PDF]

, 1998
Tese (Mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.Neste trabalho dois suportes diferentes foram avaliados para a imobilização de enzimas: o organo-gel contendo lipase de Chromobacterium viscosum (CVL), e a
Jesus, Paulo Cesar de
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Chiral Synthesis via Organoboranes. 48. Efficient Synthesis of Trans-Fused Bicyclic and Cyclic Ketones and Secondary Alcohols in High Optical Purities via Asymmetric Cyclic Hydroboration with Isopinocampheylchloroborane Etherate

, 2016
Highly stereo- and enantioselective annelation has been achieved for the synthesis of trans-fused bicyclic and cyclic ketones via the asymmetric cyclic hydroboration of suitable cyclic dienes, such as 1-allyl-1-cycloalkenes or 1-vinyl-1-cycloalkenes and ...
Ulhas P. Dhokte (2986728), Herbert C. Brown (3008829), Verinder K. Mahindroo (3045606), Pradip M. Pathare (2726698)   +3 more
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Synthesis of 3-Substituted Bicyclic Imidazo[1,2-d][1,2,4]thiadiazoles and Tricyclic Benzo[4,5]imidazo[1,2-d][1,2,4]thiadiazoles

, 2016
A versatile synthetic route to potentially useful fused-ring [1,2,4]thiadiazole scaffolds (e.g., 7a and 10b) via exchange reactions of the precursor [1,2,4]thiadiazol-3-(2H)one derivatives (e.g., 6 and 9) with appropriately substituted nitriles (e.g ...
Craig D. Simpson (150183), Tim F. Tam (2674951), Khashayar Karimian (2674960), Denis Desilets (2674963), Regis Leung-Toung (2674954), Wanren Li (2674957), Yanqing Zhao (778177)   +6 more
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Oxidation of alcohols: Synthesis of bicyclic and tricyclic spiral derivatives of tetrahydrofuran

, 1996
Tertiary alcohols with a delta-hydrogen undergo cyclization reactions when treated with silver salts and bromine in the dark to produce substituted tetrahydrofurans.
Bruck Kifle (16771554)
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Intramolecular PhIO Mediated Copper-Catalyzed Aziridination of Unsaturated Sulfamates: A New Direct Access to Polysubstituted Amines from Simple Homoallylic Alcohols

, 2016
Olefinic sulfamates derived from primary and secondary alcohols undergo intramolecular copper-catalyzed aziridination in the presence of iodosylbenzene to afford novel bicyclic fused aziridines.
Alberto Ghini (3065124), Robert H. Dodd (255173), Gerardo Burton (240155), Fernando Duran (3065118), Philippe Dauban (255170), Loïc Leman (3065121)   +5 more
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