Results 31 to 40 of about 2,581 (118)

Bicyclo(3.2.1)octan-8-ones

open access: yes, 1974
The first part of this thesis is concerned with the development of a general synthetic approach to-the bicyclo(3.2.1)octane ring system. This work resulted in the successful synthesis of 1,5-dimethylbicyclo (3.2.1)octan-8-one(54) , 1,5-dimethylbicyclo (3.
Herbert, David John
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Novel approaches to medium rings, enantiomerically enriched alcohols and haloalkynes [PDF]

open access: yes, 2012
Medium rings (8-12 atoms) are present in many naturally occurring molecules which in many cases have potentially useful biological activity. Unfortunately current synthetic methods to synthesise medium rings lack general applicability or require high ...
Rota, F
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Multivalent activation in temporary phosphate tethers: A new tether for small molecule synthesis [PDF]

open access: yes, 2007
Dissertation (Ph.D.)--University of Kansas, Chemistry, 2007.The use of phosphate esters as temporary tethers, capable of multivalent activation is the broad focus of the dissertation research reported herein.
Whitehead, Alan
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Stereodivergent, Diels–Alder-initiated organocascades employing α,β-unsaturated acylammonium salts: scope, mechanism, and application [PDF]

open access: yes, 2017
Chiral α,β-unsaturated acylammonium salts are novel dienophiles enabling enantioselective Diels-Alder-lactonization (DAL) organocascades leading to cis- and trans-fused, bicyclic γ- and δ-lactones from readily prepared dienes, commodity acid chlorides ...
Hudson, Brandi M   +3 more
core   +1 more source

OH-Initiated Reactions of p-Coumaryl Alcohol Relevant to the Lignin Pyrolysis. Part I. Potential Energy Surface Analysis

open access: yes, 2019
Cinnamyl alcohols such as p-coumaryl alcohol (p-CMA) are lignin models and precursors (monolignols) and the most important primary products of lignin pyrolysis. However, the detection of monomers is not straightforward since they either undergo secondary
Bozzelli, Joseph W.   +4 more
core   +1 more source

OH-Initiated Reactions of p-Coumaryl Alcohol Relevant to the Lignin Pyrolysis. Part I. Potential Energy Surface Analysis

open access: yes, 2019
Cinnamyl alcohols such as p-coumaryl alcohol (p-CMA) are lignin models and precursors (monolignols) and the most important primary products of lignin pyrolysis. However, the detection of monomers is not straightforward since they either undergo secondary
Rubik Asatryan (1894288)   +4 more
core   +1 more source

Studies on the tandem oxy-CopeeneClaisen reaction Applications of the hydroxy-directed Diels-Alder reaction towards the total synthesis of havellockate and synthesis of isovelleral analogues

open access: yes, 2004
The synthesis of decalin systems possessing a quaternary carbon at C-9 was achieved via the tandem oxy-Cope/ene/Claisen rearrangement. Depending on the substitution pattern of the allyl ether 1, different reaction pathways may be followed to generate the
Farand, Julie Aline
core   +2 more sources

Thermochemical Properties and Bond Dissociation Enthalpies of 3- to 5‑Member Ring Cyclic Ether Hydroperoxides, Alcohols, and Peroxy Radicals: Cyclic Ether Radical + 3O2 Reaction Thermochemistry

open access: yes, 2016
The formation of cyclic ethers is a major product in the oxidation of hydrocarbons, and the oxidation of biomass derived alcohols. Cyclic ethers are formed in the initial reactions of alkyl radicals with dioxygen in combustion and precombustion processes
Itsaso Auzmendi-Murua (1815334)   +1 more
core   +1 more source

A comparative study of Jones's, Collins's and Corey's reagents in the chromium(VI) oxidation of an epimeric pair of allylic alcohols in the benzo-fused Norbornen-5-ol series

open access: yes, 1978
A comparison has been made between a series of chromium(VI) oxidizing agents, as well as manganese dioxide, a bicyclic allylic secondary alcohol, the exo-ol (7), being the substrate.
TS Lee   +7 more
core   +1 more source

its application to hydroazulene skeletons

open access: yes, 1991
학위논문(박사) - 한국과학기술원 : 화학과, 1991.8, [ vii, 133 p. ]Cyclohept-3-3nones were prepared in four to five steps starting from cyclopentanone sily enol ether in high overall yields(42-75\%).
Kim, Sung-Kee, 김성기
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