Results 101 to 110 of about 8,870 (277)

Fused Ring Engineering Induced Topology Control in Covalent Organic Frameworks: Unlocking Promoted Photocatalytic H2O2 Production and Selective Methane Oxidation

open access: yesAngewandte Chemie, EarlyView.
By modulating the topological structures of two N‐heterocycle‐based covalent organic frameworks, Phen‐TTA with a kgd‐v topology exhibits narrower optical bandgap, lower exciton binding energy, and faster charge‐carrier kinetics compared to O‐TTA with an hcb topology.
Lei Wang   +9 more
wiley   +2 more sources

Synthesis and biological activities of novel bis‐heterocyclic pyrrodiazole derivatives

open access: yesHeteroatom Chemistry, 2008
AbstractNovel structures of bis‐heterocyclic pyrrodiazole derivatives containing pyrazole were designed and synthesized. The title compounds were characterized by 1H NMR, IR, MS, and elemental analysis. Biological activities of three intermediate compounds and 25 pyrrodiazole derivatives were tested in vivo and in vitro.
Feng‐Qi He   +3 more
openaire   +1 more source

Janus‐Type Electrostatic Potential Gradient‐Activated Dynamic Zn2+‐Coordinating Nitrogen Sites in Molecularly Locked Nanocellulose Separators for Stable Zinc‐Ion Batteries

open access: yesAdvanced Science, EarlyView.
A multifunctional benzimidazole‐terminated CNF separator is constructed via a PEI‐mediated covalent locking strategy, generating dense zincophilic sites that accelerate Zn2+ transport and desolvation while enabling uniform Zn (002) deposition and suppressing side reactions.
Jie Liang   +17 more
wiley   +1 more source

Azetidinylideneketenimines as a Multimodal Synthetic Platform: Coordination Chemistry and Cycloaddition‐Triggered Transformations

open access: yesAngewandte Chemie, EarlyView.
Cross‐coupling/homologation sequence between a stable three‐membered‐ring carbene and isocyanides enables facile and rapid access to novel methyleneketenimines and the first bis(methyleneketenimine). Reactivity studies gave rise to the first methyleneketenimine‐transition metal complexes, unique multimodal reactivity ranging from CO2, isocyanate ...
Taichi Koike   +3 more
wiley   +2 more sources

Syntheses and medicinal chemistry of spiro heterocyclic steroids

open access: yesBeilstein Journal of Organic Chemistry
There is compelling evidence that incorporating a heterocyclic moiety into a steroid can alter its pharmacological and pharmacokinetic properties, driving intense interest in the synthesis of such hybrids among research groups. In this review, we present
Laura L. Romero-Hernández   +5 more
doaj   +1 more source

2,2′-(Propane-1,3-diyl)bis(2H-indazole)

open access: yesActa Crystallographica Section E, 2011
The title molecule, C17H16N4, is a bis-indazole crystallized in the rare 2H-tautomeric form. Indazole heterocycles are connected by a propane C3 chain, and the molecule is placed on a general position, in contrast to the analogous compound with a central
Saúl Ovalle   +3 more
doaj   +1 more source

Innovations in Catalytic Syntheses of Bis- and Halogenated Heterocycles [PDF]

open access: yes
Transition metals in organic synthesis have been a groundbreaking advancement, shaping the field over the past three decades. Transition metal-catalyzed reactions have introduced novel mechanistic pathways to access previously unattainable small ...
Arora, Ramon
core   +1 more source

Decoupling Intrinsic Molecular Efficacy From Platform Effects: An Interpretable Machine Learning Framework for Unbiased Perovskite Passivator Discovery

open access: yesAdvanced Science, EarlyView.
This study establishes an interpretable machine learning framework that disentangles the intrinsic molecular efficacy of passivators from experimental platform effects—enabling unbiased, high‐throughput discovery of effective perovskite surface modifiers.
Jing Zhang   +5 more
wiley   +1 more source

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