Enantioselective Route to Terminal 2,3-Epoxy Tosylates Enabled by Cooperative Organocatalytic Desymmetrization of 2-Substituted Glycerol Derivatives. [PDF]
Astone A, Meninno S, Lattanzi A.
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3,14-Diselena-4,5,12,13-tetra-aza-tri-cyclo-[9.3.0.0<sup>2,6</sup>]tetra-deca-1(11),2(6),4,12-tetra-ene. [PDF]
Detert H, Schollmeyer D.
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Geminal difunctionalization of readily available building blocks provides rapid access to molecular complexity. This work introduces a strategy for installing two distinct functional groups on a carbonyl carbon by transforming it into a donor–donor diazo compound, enabling both batch and flow applications with broad solvent compatibility.
Vincent George +13 more
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Alumanyl silanides as multifunctional reagents for olefin cycloaddition, CO hydrosilylation, and reductive CO coupling. [PDF]
Ludwig M +4 more
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In Situ Construction of Imidazopyridinium Fluorescent Labels for Bioconjugation
Chromophore engineering of isoquinoline aldehydes generates TICT‐based fluorogenic dyes for in situ labeling of diverse (bio)molecules with large Stokes shifts compatible with cell imaging. ABSTRACT Simple, efficient transformations of fluorogenic nature that proceed under biocompatible conditions without the formation of byproducts are of high ...
Dongchen Du +7 more
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Recent Advances in Heterocyclic HIV Protease Inhibitors. [PDF]
Funicello M +4 more
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Hydrazine Derivatives as C-Centered Radical Precursors for C-C Bond Formation Reactions. [PDF]
Lopat'eva ER, Krylov IB, Terent'ev AO.
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Boraindenes as versatile precursors to benzannulated boron heterocycles. [PDF]
Wieprecht N +7 more
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Access to Nitrogen-nitrogen Bond-Containing Heterocycles Through Substrate Promiscuity of Piperazate Synthases. [PDF]
Li Y +9 more
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Experimental Evidence for a Metal‐Related Function of a Cyanobactin
Cyanobactins such as patellamides are produced by cyanobacteria profusely and have been studied extensively, but almost exclusively for their cytotoxic properties. Discussed is unprecedented experimental evidence for a metal‐related biological function – likely CO2 transport from the ascidian to the cyanobacterial symbiont.
Philipp Baur +8 more
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