Gold(I) Phosphine/Phosphido‐Borohydride Complexes
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair +3 more
wiley +1 more source
Far-infrared spectroelectrochemistry: a study of linear molybdenum/iron/sulfur clusters [PDF]
The far-infrared spectroelectrochemistry of linear M/Fe/S (M=Mo, W) complexes was investigated in methylene chloride and dichloroethane. With CsI as spectral windows, bands above 200 cm−1 can be observed in methylene chloride, except for a weak methylene
Li, Lin, Ryan, Michael D.
core +1 more source
Threefold reduction of 9,10,11‐triptindanetrione with LiAlH4 or NaBH4 yields exclusively the C3‐symmetric triol, suggesting an intracomplex (“rolling”) mechanism. However, use of LiAlH4/LiAlD4 (1 : 1) reveals a preceding hydride exchange. Mechanistic implications are discussed including the reduction of the related diketone.
Thorsten Hackfort +5 more
wiley +1 more source
Dextran enzyme imine complexes : a preliminary study : this thesis was presented in partial fulfilment of the requirements for the degree of Master of Science in Biochemistry at Massey University [PDF]
A model system involving the formation of protein-dextran complexes has been investigated with a view to improving existing methods of drug administration.
Fisher, Louisa Jane
core
A personal 360° view of applications of ‘biomimetic’ molecular recognition
Abstract Molecular recognition between biological molecules has formed the basis for innumerable applications in biotechnology for the last seven decades or so. Techniques such as affinity chromatography, solid‐phase and aqueous two‐phase extraction, affinity precipitation, biomimetic catalytic systems, biosensors and molecular imprinting all exploit ...
Christopher R Lowe
wiley +1 more source
Synthesis and Characterization of Au:Ag Core-Shell Nanoparticles with 4-Aminothiophenol Surface Enhance Raman Spectroscopy (SERS) Tag [PDF]
At the Linfield Symposium the research on silver coated gold nanoparticles tagged SERS will be presented. Gold core nanoparticles were synthesized and coated with a silver shell.
Gilbert, Brian, Gladding, Madison
core +1 more source
Selective plane illumination (SPI) is combined with SERS spectral imaging to reduce background, improve image contrast, and enable improved spectroscopy from molecules on the surface of nanoparticles. This approach provides improved imaging and spectroscopy from nanoparticles in complex environments, such as biological cells.
Abigail E. Smith, Zachary D. Schultz
wiley +1 more source
Photooxidation of 18‐Carbon Polyunsaturated Fatty Acids to Prepare Mono‐Hydroxylated Octadecanoids
We developed a fast and simple one‐step synthetic strategy to produce mono‐hydroxylated metabolites based on the photosensitized oxidation of 18‐carbon polyunsaturated fatty acids (PUFAs). This approach could likely be extended to other PUFAs, suggesting that photosensitized oxidation could be employed to rapidly prepare hydroperoxides from multiple ...
Johanna Revol‐Cavalier +2 more
wiley +1 more source
Synthesis of Silver Nanoparticles using Non-Fouling Microfluidic Devices with Fast Mixing [PDF]
This paper was presented at the 4th Micro and Nano Flows Conference (MNF2014), which was held at University College, London, UK. The conference was organised by Brunel University and supported by the Italian Union of Thermofluiddynamics, IPEM, the ...
4th Micro and Nano Flows Conference (MNF2014) +4 more
core
Low‐Hysteresis Cellulose‐Based Hydrogels for Strain Detecting
Low‐hysteresis hydrogel with high cellulose content is prepared. The modified cellulose is prepared through a sequential periodate oxidation and borohydride reduction process. The hydrogel can be used as a strain sensor with a gauge factor of 1.1 in the 0%–300% sensing range.
Xia Sun, Fanghan Luo, Feng Jiang
wiley +1 more source

