Results 101 to 110 of about 17,314 (245)

Atomically precise metal cluster enzymes for pathological tissue regeneration

BMEMat, EarlyView.
Schematic illustration of atomically precise metal cluster enzymes (MCEs) for pathological tissue regeneration. Atomically precise MCEs can modulate biological processes, such as attenuation of inflammatory responses, eradication of bacterial pathogens, regulation of angiogenesis, and promotion of cell development.
Ziqiang Xiong, Zhifeng Shi, Mengqing Li, Jien Han, Haoyan Chen, Maofei Ran, Shaojian Zhong, Limin Ma, Chengyun Ning, Youzhun Fan, Zhenghua Tang, Peng Yu   +11 more
wiley   +1 more source

Metal ion-manipulated afterglow on rhodamine 6G derivative-doped room-temperature phosphorescent PVA films

Frontiers in Chemistry
The long-lived room-temperature phosphorescence (RTP) originating from thiophene boronate polyvinyl alcohol (PVA) has enabled the creation of metal-ion-responsive RTP films doped with spirolactam ring-containing rhodamine 6G (1).
Margarita Claudya Maida, Natsumi Sugawara, Airi Suzuki, Masato Ito, Yuji Kubo   +4 more
doaj   +1 more source

C–H insertion as a key step to spiro-oxetanes, scaffolds for drug discovery [PDF]

, 2016
A new route to spiro-oxetanes, potential scaffolds for drug discovery, is described. The route is based on the selective 1,4-C–H insertion reactions of metallocarbenes, generated from simple carbonyl precursors in flow or batch mode, to give spiro-β ...
Corrado Guarnaccia, Domenico Origi, Marco Baralle, Nataša Skoko, Sergio G Tisminetzky, Sotir Zahariev, Sulena Polez   +6 more
core   +6 more sources

Metal‐Free Covalent Organic Frameworks for Photocatalytic CO2 Reduction

ChemistryEurope, EarlyView.
This review presents an environmentally sustainable strategy to address the critical issue of escalating atmospheric CO2 levels. It explores the application of metal‐free covalent organic frameworks in a photocatalytic approach, offering a green and efficient strategy for carbon dioxide reduction and contributing to climate change mitigation.
Supriti Dutta, Akhtar Alam, Pekham Chakrabortty, Pradip Pachfule   +3 more
wiley   +1 more source

Copper-Catalyzed Borylation of Cyclic Sulfamidates:Access to Enantiomerically Pure (β-and γ-Amino-alkyl)boronic Esters [PDF]

, 2016
Cyclic sulfamidates undergo borylation under copper‐catalyzed conditions using B(2)pin(2) to give enantiomerically (and diasteromerically) defined (aminoalkyl)boronic esters.
Atack, Awano, Bedford, Bose, Bower, Butler, Butler, Chemler, Decicco, Denniel, Dicko, Dudnik, Fernandez, Georgiou, Glasspoole, Harvey, Hildebrand, Imao, Ito, Iwamoto, Jana, Joshi-Pangu, Kataoka, Kim, Kirchhoff, Kleeberg, Kubota, Larouche-Gauthier, Lee, Meléndez, Molander, Ohmura, Quasdorf, Stymiest, Wang, Wehn, Yang, Yang, Yi   +38 more
core   +1 more source

Rubrolides A, D, P, T, U: Total Syntheses and Antibacterial Evaluation of Highly Brominated Marine Natural Products

ChemistryEurope, EarlyView.
Following the Danube Flow. The first total syntheses of highly brominated rubrolides T, U, and U‐analog, together with the efficient and divergent syntheses of rubrolides A, D, and P. The dibrominated key intermediate, obtained via a Suzuki‐Miyaura cross‐coupling reaction, is the centerpiece of the synthesis.
Jasmin Janneschütz, Paul G. Schebek, Alexander Meyer, Celina Haller, Sophia Khom, Wolfgang R. Streit, Ifey Alio, Nina Schützenmeister   +7 more
wiley   +1 more source

Dynamic foldamer chemistry [PDF]

, 2016
Foldamers can be made more than pieces of static, conformationally uniform molecular architecture by designing into their structure the conformational dynamism characteristic of functional molecular machines.
Amit, Azeroual, Azzarito, Berthelot, Boddaert, Brioche, Brodsky, Brown, Brown, Bryden A. F. Le Bailly, Bunkóczi, Byrne, Chouaieb, Clayden, Clayden, Cornelissen, Crisma, Dawkins, De Poli, De Poli, De Poli, De Zotti, Dolain, Dumitru, Dunitz, Fletcher, Formaggio, Fuxreiter, Gan, Gellman, Granier, Green, Ha, Habchi, Hecht, Hill, Huc, Hummel, Inai, Inai, Inai, Inai, Inai, Inai, Ishikawa, Ito, James, Jonathan Clayden, Jones, Juwarker, Kolomiets, Komori, Le Bailly, Le Bailly, Le Bailly, Lehn, Lehn, Lettieri, Maeda, Mamiya, Manglik, Müller, Nakano, Nicolaou, Okino, Orcel, Ousaka, Ousaka, Ousaka, Pengo, Perutz, Pijper, Pijper, Pike, Prasad, Prince, Qi, Reggelin, Saraogi, Smaldone, Smith, Solà, Solà, Suginome, Tomsett, Toniolo, Toniolo, Toniolo, Toniolo, Ute, Whitesides, Yashima, Yashima, Yashima, Yonath, Zhang, Zhang   +96 more
core   +3 more sources

Design of a Fluorescent Boronic Acid‐Functionalized Pyranoflavylium Receptor to Host and Release Diol‐Rich Bioactive Analytes in a pH‐Dependent Manner

ChemFoodChem, EarlyView.
This work presents a pH‐responsive ON–OFF fluorescent system based on a novel pyranoflavylium dye functionalized with a boronic acid receptor. The receptor exhibits a markedly higher affinity for the catechol‐containing polyphenol (+)‐catechin than for conventional diol‐rich molecules such as glucose and lactic acid.
Beatriz Senra, Mariana Cunha, Ana Sofia Pires, Ricardo Dias, Victor de Freitas, Luís Cruz   +5 more
wiley   +1 more source

Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives

Chemistry – A European Journal, EarlyView.
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome, Péter P. Fehér, András Stirling, Csongor G. Németh, Tamás Hergert, György M. Keserű, Péter Ábrányi‐Balogh   +6 more
wiley   +1 more source

New synthetic strategies for the stereocontrolled synthesis of substituted ‘skipped’ diepoxides [PDF]

, 2009
This report describes a number of new synthetic approaches toward methyl-substituted mono- and diepoxy alcohols that serve as substrates for endo-selective epoxide-opening cascades. The key transformations involve the manipulation of alkynes. Highlighted
Jamison, Timothy F., Morten, Christopher J.   +1 more
core   +1 more source