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Boryl ligands and their roles in metal-catalysed borylation reactions
Chemical Communications, 2009In this feature article, we discuss selected recent aspects of metal boryl (M-BR2) chemistry pertaining, in particular, to the role of late and post-transition metal boryl complexes in various catalytic processes. The exceptionally strong sigma-donor properties of boryl ligands and their related nucleophilic behaviour are highlighted.
Dang, Li, Lin, Zhenyang, Marder, Todd B.
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Journal of the American Chemical Society, 2011
A new class of stable molecules, α-boryl aldehydes, has been prepared from oxiranyl N-methyliminodiacetyl boronates by a 1,2-boryl migration with concomitant epoxide scission. A range of boryl imines, alkenes, alcohols, acids, enol ethers, enamides, and other functionalized boronic acid derivatives that are difficult or impossible to prepare using ...
Zhi, He, Andrei K, Yudin
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A new class of stable molecules, α-boryl aldehydes, has been prepared from oxiranyl N-methyliminodiacetyl boronates by a 1,2-boryl migration with concomitant epoxide scission. A range of boryl imines, alkenes, alcohols, acids, enol ethers, enamides, and other functionalized boronic acid derivatives that are difficult or impossible to prepare using ...
Zhi, He, Andrei K, Yudin
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Thermal C–H borylation using a CO-free iron boryl complex
Chemical Communications, 2015Thermal C–H borylation was observed from a phosphine-supported iron boryl complex.
Thomas J, Mazzacano, Neal P, Mankad
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Direct deoxygenative borylation
Pure and Applied Chemistry, 2022Abstract Direct deoxygenative borylation is a highly enabling chemical transformation considering the attractive synthetic features of oxygenous feedstocks and organoboron compounds. Despite ranking among the synthetic ideality in different settings, such chemical space remained largely uncharted and underutilized until recent decades ...
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Science, 2020
C–H Bond Activation Catalytic borylation is the rare reaction that can selectively target stronger over weaker saturated carbon–hydrogen (C–H) bonds. However, the trade-off has been that the reaction is slow and requires high excess of the hydrocarbon. Oeschger et al.
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C–H Bond Activation Catalytic borylation is the rare reaction that can selectively target stronger over weaker saturated carbon–hydrogen (C–H) bonds. However, the trade-off has been that the reaction is slow and requires high excess of the hydrocarbon. Oeschger et al.
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Borylated Ferrocenium Compounds
2001In industrialized countries, cancer is the most frequent cause of death, apart from cardiovascular diseases. Surgery, radiotherapy and chemotherapy are the most common treatments, but the destruction of primary tumors by irradiation often fails due to radiosensitive tissues next to the neoplasm.
L. Weissfloch +10 more
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Enantioselective Conjugate Borylation
Angewandte Chemie International Edition, 2010Julia A, Schiffner +2 more
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Organoaluminum Boryl Complexes
Angewandte Chemie International Edition, 2012Nicole, Dettenrieder +5 more
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Photoinduced Borylation for the Synthesis of Organoboron Compounds
Chemical Reviews, 2021Ya-Ming Tian +2 more
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