Results 71 to 80 of about 2,786 (190)

Carbonyl lock enables multi‐resonant organoboron framework with substantially enhanced spin‐flip and reduced emission bandwidth

FlexMat, EarlyView.
Integrating carbonyl lock onto multi‐resonant organoboron emitters is found to go beyond conventional bridge unit. It can not only suppress the molecular relaxation as conventional bridge, but also substantially affect electronic engineering via carbonyl integration, activating multiple up‐conversion channels, thus leading to an accelerated spin‐flip ...
Tingfeng Chen, Xin Xiong, Rajat Walia, Xiaochun Fan, Wei Liu, Xiankai Chen, Jia Yu, Kai Wang   +7 more
wiley   +1 more source

Clean and fast cross-coupling of aryl halides in one-pot

Beilstein Journal of Organic Chemistry, 2014
Unsymmetrically coupled biaryls are synthesized in high yield starting from different aryl bromides and bis(pinacolato)diboron by carrying out the Miyaura borylation reaction followed by the Suzuki–Miyaura reaction in the same reaction pot over 1–2 mol %
Valerica Pandarus, Geneviève Gingras, François Béland, Rosaria Ciriminna, Mario Pagliaro   +4 more
doaj   +1 more source

AI‐Driven Synthesis in Medicinal Chemistry: Integrating Large Language Models, Robotic Automation, and Sustainability Metrics to Accelerate Drug Discovery

Medicinal Research Reviews, EarlyView.
ABSTRACT Artificial intelligence (AI) is transforming synthetic chemistry from task‐specific predictors into integrated platforms that unify retrosynthesis, reaction optimization, and closed‐loop robotic automation. This review highlights how AI‐assisted planning and robotic execution shorten cycle times, reduce step counts, and improve route ...
Amit Gangwal, Antonio Lavecchia
wiley   +1 more source

Solid-phase synthesis of biaryl bicyclic peptides containing a 3-aryltyrosine or a 4-arylphenylalanine moiety

Beilstein Journal of Organic Chemistry, 2019
A methodology for the solid-phase synthesis of biaryl bicyclic peptides containing a Phe-Phe, a Phe-Tyr or a Tyr-Tyr motif has been devised. This approach comprises two key steps.
Iteng Ng-Choi, Àngel Oliveras, Lidia Feliu, Marta Planas   +3 more
doaj   +1 more source

Activation of Aryl Halides by Triplet–Triplet Annihilation Upconversion Enabling Coupling Processes Under an Open‐to‐Air Environment

European Journal of Organic Chemistry, Volume 29, Issue 24, 23 June 2026.
Triplet–triplet annihilation upconversion (TTA‐UC) performed inside supramolecular viscoelastic gels enables efficient CC and C–heteroatom coupling reactions under green LED irradiation in open‐air conditions. The gel network restricts oxygen diffusion, preserves triplet states, and allows aryl halide activation through upconverted excited states ...
Daniel Álvarez‐Gutiérrez, Paola Domínguez Domínguez, M. Consuelo Jiménez, David Díaz Díaz, Raúl Pérez‐Ruiz   +4 more
wiley   +1 more source

Mechanochemical borylation of aryldiazonium salts; merging light and ball milling

Beilstein Journal of Organic Chemistry, 2017
Merging of photo- and mechanochemical activation permitted studying the role of eosin Y in the borylation of aryldiazonium salts in a ball mill. Simultaneous neat grinding/irradiation of the reactants and the photocatalyst led to the formation of ...
José G. Hernández
doaj   +1 more source

1,1‐and 1,2‐Diborylalkenes: Preparation and Synthetic Applications

Advanced Synthesis &Catalysis, Volume 368, Issue 12, 17 June 2026.
In this review, we highlight recent advances in the synthesis and reactivity of 1,1‐diborylalkenes and 1,2‐diborylalkenes, along with various transformations leading to C‐C, C‐heteroatom, and multicomponent products. By providing a comprehensive and practical resource, this review aims to assist researchers in exploring the synthetic utility of 1,1 and
Jayaram Vankudoth, Maruti Mali, Fabienne Berrée   +2 more
wiley   +1 more source

Visible Light‐Induced N‐Heterocyclic Nitrenium‐Catalyzed Deoxygenative Borylation of Acyl Chlorides

ChemistryEurope
Considering the appealing synthetic properties of oxygenous feedstocks and organoboron compounds, direct deoxygenative borylation is a very desirable chemical transformation.
Rahul Mondal, Apurba Kumar Pal, K. Geetharani   +2 more
doaj   +1 more source

Photocatalytic Vanadium‐Mediated Amination of Benzene With Hydroxylamine

Chemistry – A European Journal, Volume 32, Issue 22, 9 June 2026.
Photochemical activation of N‐phenylphenothiazine (PPT) enables a selective direct benzene amination with hydroxylamine in the presence of various vanadium catalysts under mild reaction conditions. Spectroscopic and kinetic analyses identify a key vanadium(IV)‐hydroxylamine intermediate, elucidate the crucial roles of the acidic medium, the ...
Dana Králová, Maximilian Philipp, Matthias Schmalzbauer, Thilo Reiter, Bernd Schäfer, Ruth M. Gschwind, Burkhard König   +6 more
wiley   +1 more source

Rhodium(I)‐Catalyzed P(III)‐Directed C–H Alkylation of Biarylphosphines With Maleimides

Advanced Synthesis &Catalysis, Volume 368, Issue 11, 3 June 2026.
A Rh(I)‐catalyzed P(III)‐directed ortho‐C–H bond alkylation of biarylphosphines with maleimides is disclosed. The reaction accommodates substituted alkenes, proceeds efficiently on gram scale, and consistently generates diastereomeric phosphines. NMR and mechanistic studies reveal that the stereochemical outcome arises from conformational restriction ...
Jian Zhang, Tao Ma, Marie‐Noelle Rager, E. Daiann Sosa Carrizo, Jean‐François Soulé   +4 more
wiley   +1 more source