Results 81 to 90 of about 2,664 (258)

Simultaneous Electronic and Crystallographic Modulation of Cs3Bi2Br9 by Single‐Element Sn Substitution for Enhanced CO2 Photoreduction

open access: yesAdvanced Energy Materials, EarlyView.
Aliovalent B‐site substitution with Sn2+ in lead‐free perovskite, Cs3Bi2Br9, is employed to simultaneously induce lattice contraction and bromine vacancy through charge imbalance and ionic radius mismatch. The resulting structural distortion modulates the electronic structure and improves charge separation, leading to enhanced visible‐light‐driven CO2 ...
Justin Khor   +7 more
wiley   +1 more source

Interaction Hierarchy and Polymorphic Structure–Property Dynamics in Luminescent Molecular Crystals

open access: yesAngewandte Chemie, EarlyView.
Competing homotypic and heterotypic intermolecular interactions give rise to polymorphic structure–property dynamics in luminescent molecular crystals. Thermal and mechanical stimuli induce distinct phase‐transition pathways accompanied by pronounced photoluminescence changes.
Mahiro Nakabayashi, Shotaro Hayashi
wiley   +2 more sources

Potassium bromate disrupts mitochondrial distribution within murine oocytes during in vitro maturation

open access: yesReproductive Medicine and Biology, 2018
Purpose As disturbed mitochondrial distribution is thought to be a cause of the aging of oocytes, it was investigated whether oxidizing agents exert harmful effects on nuclear maturation and mitochondrial cluster formation in murine oocytes and whether ...
Kenichi Yamada   +6 more
doaj   +1 more source

Analytical application of acidic victoria blue 4R mixture with KBrO3 for the kinetic determination of traces of antimony(III) by spectrophotometry

open access: yesMacedonian Journal of Chemistry and Chemical Engineering, 2012
The present paper describes a simple, selective and sensitive kinetic method for the determination of trace amounts of Sb(III) in the presence of Sb(V) based on its inhibition effect on the redox reaction between bromate and Victoria blue 4R (V.B.
Violeta Mitić   +2 more
doaj   +1 more source

Molecular Engineering of Polytriphenylamine: A Fluorinated Cathode for High‐Voltage, Ultrafast, and Stable Sodium‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Fluorination of polytriphenylamine lowers the HOMO energy, enabling high‐voltage operation of the PFTPA cathode. Electron‐withdrawing F substituents stabilize the nitrogen redox center and suppress polarization, leading to fast kinetics. The optimized polymer delivers ∼3.75 V vs.
Natalia Voronina   +6 more
wiley   +1 more source

Carbon‐Encapsulated Gemini Ionic Liquid as Advanced Bromine Hosts for High‐Performance Zn–Br2 Batteries

open access: yesAngewandte Chemie, EarlyView.
Rapid self‐discharge limits the practical deployment of Zn–Br2 batteries. Herein, a gemini ionic liquid featuring dual bromine‐binding sites and an aromatic linker is confined within porous carbon electrodes. The ionic liquid simultaneously complexes bromine species and interacts strongly with the carbon matrix, enabling efficient bromine retention ...
Vishwakarma Ravikumar Ramlal   +10 more
wiley   +2 more sources

From Berzelius to Hyperspace: Previously Unrecognized Network of Reactivity in Textbook Brominations

open access: yesAngewandte Chemie, EarlyView.
Robotic scans across multidimensional condition spaces of classic bromination reactions uncover regions of previously unrecognized reactivity, yielding new major products and novel substitution patterns. Correlation and anticorrelation analyses of product distributions across these hyperspaces enable reconstruction of the underlying mechanistic ...
Yankai Jia   +9 more
wiley   +2 more sources

Construction of Nafion/Hb/Au/ZIF-8/CILE and its application as electrochemical sensor for determination of bromate and nitrite

open access: yesInternational Journal of Electrochemical Science, 2019
In this paper zinc-based metal organic framework material (ZIF-8) modified carbon ionic liquid electrode (CILE) was prepared and electrodeposited with gold nanoparticles to get a composite modified electrode, which was used as the sensing interface for ...
Juan Liu   +11 more
doaj   +1 more source

New spectrophotometric method for wine quality control [PDF]

open access: yesJournal on Processing and Energy in Agriculture, 2010
This work presents a development of a rapid, relatively sensitive, and low-cost spectrophotometric method enabling the determination of the antioxidant activity of wine.
Radovanović Blaga, Bojić Jorgovanka
doaj  

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