Results 101 to 110 of about 2,664 (258)

Impact of Organo‐Functionalization on the Light‐Driven Hydrogen Evolution Reactivity of Molecular Molybdenum Sulfides

Chemistry – A European Journal, EarlyView.
Organo‐functionalized molecular molybdenum sulfides were synthesized using bidentate N‐donor ligands and investigated as light‐driven homogeneous hydrogen evolution reaction (HER) catalysts. Trends observed in the HER activity of these catalysts were elucidated by combining photophysical, electrochemical and computational studies.
Moritz Jahn, Luis Kammerer, Luca Schleicher, Amelie Meyer, Mariet Sibi Puthanagady, Alexander K. Mengele, Sven Rau, Stephan Kupfer, Benjamin Dietzek‐Ivanšić, Carsten Streb   +9 more
wiley   +1 more source

FLP Mediated Conversion of Difluorobenzylalkynes to Fluoroallenyl Oniums via an SN1’ Pathway

Chemistry – A European Journal, EarlyView.
Frustrated Lewis pair (FLP) selective C‒F activation of difluorobenzylalkynes allows the formation of fluoroallenic oniums via an SN1’ substitution pathway. The fluoroallenic onium salts are synthetic precursors that allow subsequent functionalization at allenic and onium positions.
Max Coles, Tianhong Wang, Rubi McLennan, Long Kit Kwan, Bivas Mondal, Chakyu Richard Chan, Rowan D. Young   +6 more
wiley   +1 more source

Acute Renal Failure following Accidental Potassium Bromate Poisoning: A Case Report

Nigerian Journal of Paediatrics
Summary: Accidental poisoning is common in children. Potassium bromate is a commonly used additive and raising agent in many edibles particularly bread, a staple food worldwide, yet its accidental poisoning has hitherto, not been documented in Nigeria ...
Okeniyi JAO , Aladekomo TA , Oyelami OA.   +2 more
doaj  

Active Bromine Cycling Enables Bromate as an Oxidant of Mn(II) on the Low-Temperature Martian Surface. [PDF]

Inorg Chem
Qu SY, Zhao YS, Lin H, Yin Y, Yang X, Yu XW, Yang L, Zhang C, He H.   +8 more
europepmc   +1 more source

Ratiometric pH‐Responsive and Biomimetic Microparticles for Quantitative Monitoring of Phagosomal Acidification

Chemistry – A European Journal, EarlyView.
A series of hydrosoluble BODIPY pH probes allows building biomimetic pH sensors based on micrometric oil‐in‐water droplets. The ratiometric fluorescence output offers quantitative information on the evolution of pH during phagosome maturation. ABSTRACT We present a modular biomimetic fluorescent sensing platform designed to precisely interrogate the ...
Sophie Michelis, Héloïse Uhl, Florence Niedergang, Jacques Fattaccioli, Blaise Dumat, Jean‐Maurice Mallet   +5 more
wiley   +1 more source

High-Performance Liquid Chromatography Method Optimization and Validation for Potassium Bromate Detection in Bread Using a Quality-by-Design Approach. [PDF]

J Anal Methods Chem
Gebretsadikan T, Hiben MG, Gebremedhin KH, Zebrehe M, Fisseha H, Abay TH.   +5 more
europepmc   +1 more source

Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate

Chemistry – A European Journal, EarlyView.
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal, Alexandre Millanvois, Louis Fensterbank, Cyril Ollivier   +3 more
wiley   +1 more source

Synthesis of Oligonucleotide Conjugates Employing a Diselenide Linker

Chemistry – A European Journal, EarlyView.
ABSTRACT In this study, we report the synthesis of an alkylene linker containing a terminal 2‐cyanoethyl protected selenium functionality for coupling at the 5'‐end of an oligonucleotide by solid phase synthesis for the preparation of oligonucleotide conjugates.
Shivam Tikoo, Anne M. Noronha, Christopher J. Wilds   +2 more
wiley   +1 more source

Seasonal bromate formation in the Arctic snowpack: Implications for the bromine biogeochemical cycle. [PDF]

Sci Adv
Frassati S, Barbaro E, Cozzi G, Turetta C, Scoto F, Rossetti C, Roman M, Feltracco M, Kim K, Burgay F, Saiz-Lopez A, Francisco JS, Van Pelt W, Wang F, Cappelletti D, Lerda S, Bistoni G, De Angelis F, Barbante C, Gambaro A, Spolaor A.   +20 more
europepmc   +1 more source

Exploring Calixarene‐Based Pseudorotaxane Architectures: Threading Ammonium Axles With an Exo‐Rim π‐Functionalized Calix[6]Arene Macrocycle

Chemistry – A European Journal, EarlyView.
This research presents a novel 1,4‐π‐functionalized calix[6]arene with enhanced interactions with dialkylammonium axles. We investigate threading behavior in CDCl3, highlighting how exo‐rim π‐functionalization affects binding affinity and stereoselectivity.
Veronica Iuliano, Paolo Della Sala, Placido Neri, Donato De Simone, Rocco Del Regno, Margherita De Rosa, Carmine Gaeta, Carmen Talotta   +7 more
wiley   +1 more source