Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley +1 more source
Advanced oxidation processes (AOPs) for drinking water treatment: a state-of-the-art review on applications, efficacy, and implementation challenges. [PDF]
Attia MS +3 more
europepmc +1 more source
Expanding Cyanide‐Bridged Weakly Coordinating Anions Through the Brominated Silver Salt Ag[BCNBBr]
The brominated weakly coordinating anion [μ‐(CN)(B(C6F4Br)3)2] ([BCNBBr]−), based on two B(C6F4Br)3 units bridged by cyanide, is obtained as its silver salt Ag[BCNBBr] from CH2Cl2. Ag[BCNBBr] enables oxidation and halide abstraction reactions, affording diverse [BCNBBr]− salts with oxidizing and electrophilic cations.
Amina L. Moshtaha +4 more
wiley +1 more source
Supramolecular Polymer-Based Delayed Crosslinking Weighted Fracturing Fluid with a Double Network for Ultra-Deep Reservoirs. [PDF]
Shi S +7 more
europepmc +1 more source
Fluorogenic Sydnones for Bioorthogonal Labeling of DNA
Conjugates of sydnones with cyanine‐styryl dyes combine bioorthogonal reactivity with fluorogenicity. The reactivity with bicyclo[6.1.0]non‐4‐yne (BCN)‐modified DNA showed second‐order rate constants of up to k2 = 2,300 M−1s−1 and fluorescence turn‐on by one magnitude of order.
Kerstin Müller +1 more
wiley +1 more source
Advancing Hydraulic Fracturing Fluids with Ascorbic Acid: A Green and Multifunctional Approach. [PDF]
Almubarak T +3 more
europepmc +1 more source
A library of 21 tetrakis(phenothiazinyl)‐substituted silanes with broadly variable substituent decoration, which are fully reversible multistage redox systems with intense tunable emission from deep blue to yellow–green (441–533 nm), was rapidly synthesized by bromine–lithium exchange/borylation–Suzuki coupling of tetrakis(4‐bromophenyl)silane or by ...
Thomas P. M. Merke +4 more
wiley +1 more source
Siderite and ferric oxyhydroxides imply interlinked carbon, iron, and halogen cycles on Mars. [PDF]
Mitra K +3 more
europepmc +1 more source
Deriving General Energy Predictors for Pnictogen Bonding
This study derives general energetic predictors for pure pnictogen bonds from nitrogen to bismuth based on the potential energy density at the bond critical point. The research highlights the increasing occurrence of secondary interactions for heavier elements.
Jan Langwald, Antonio Frontera
wiley +1 more source
Bromate removal in water through electrochemical reduction using Magnéli phase titanium oxide electrode. [PDF]
Guo L +3 more
europepmc +1 more source

