Results 91 to 100 of about 5,886 (288)

An X‑Shaped Chiral Non‑Fullerene n‐Type Semiconductor: Application in Perovskite Solar Cells and Chirality‑Induced Spin Selectivity

open access: yesAngewandte Chemie, EarlyView.
A highly electron‑accepting derivative of cyclobisbiphenylenecarbonyl (CBBC‐TIC) is reported. CBBC‐TIC functions as an electron‐transport layer for perovskite solar cells, achieving a power conversion efficiency of 20.6%. Furthermore, the enantiomers of CBBC‐TIC exhibited spin‐selective electron transport with high enantiospecific magnetic conductance ...
Yuki Sakamoto   +15 more
wiley   +2 more sources

Determinação de bromato em melhoradores de farinha por cromatografia de troca iônica com detecção espectrofotométrica Bromate determination in flour improvers by ion exchange chromatography with spectrophotometric detection

open access: yesQuímica Nova, 2005
KBrO3 is registered by the FAO/OMS as a genotoxic and carcinogenic compound. In spite of this, KBrO3 is still employed by Brazilian bakeries. Nowadays ion exchange chromatography (IEC) is the most rapid and trustful method for BrO3- analysis.
Rogério Marcos Dallago   +3 more
doaj   +1 more source

Nickel‐Free Perovskite Solar Cells Enabled by Self‐Assembled Monolayers: A Pathway to Efficient and Recyclable Devices

open access: yesAdvanced Energy Materials, EarlyView.
Replacing toxic NiOx with phenyl‐substituted phosphonic‐acid carbazole monolayers (Ph‐5PACz) yields inverted perovskite solar cells that are efficient and recyclable. The nickel‐free interface reaches 25.3% efficiency and enables closed‐loop ITO recovery with near‐98% performance retention, while life‐cycle and techno‐economic analyses confirm lower ...
Yanxue Wang   +17 more
wiley   +1 more source

Chiroptical Switching by Stereoselective Photochemical Sigmatropic Rearrangements: Experimental Realization of Calderoselectivity

open access: yesAngewandte Chemie, EarlyView.
Calderoselectivity is established as a stereochemical principle for sigmatropic rearrangements. A homoannulene‐based chiroptical photoswitch undergoes a photochemical [1,11] sigmatropic rearrangement with control of the acyl movement on top of the cyclic π system.
Anne Krenkel   +8 more
wiley   +2 more sources

Chlorination‐Driven BODIPY Fluorescent Probes for the Selective Monitoring of Myeloperoxidase Activity in Cells and Inflamed Mouse Models

open access: yesAngewandte Chemie, EarlyView.
A meso‐carboxamide‐substituted BODIPY fluorescent probe reports myeloperoxidase (MPO) activity via electrophilic chlorination by MPO‐derived HOCl, generating a highly emissive chlorinated product with a ca. 40 nm bathochromic shift. Applications in quantitative MPO assays, cellular imaging of MPO‐derived HOCl, redox‐dependent discrimination of cancer ...
Siyoung Cho   +3 more
wiley   +2 more sources

Potassium bromate disrupts mitochondrial distribution within murine oocytes during in vitro maturation

open access: yesReproductive Medicine and Biology, 2018
Purpose As disturbed mitochondrial distribution is thought to be a cause of the aging of oocytes, it was investigated whether oxidizing agents exert harmful effects on nuclear maturation and mitochondrial cluster formation in murine oocytes and whether ...
Kenichi Yamada   +6 more
doaj   +1 more source

Analytical application of acidic victoria blue 4R mixture with KBrO3 for the kinetic determination of traces of antimony(III) by spectrophotometry

open access: yesMacedonian Journal of Chemistry and Chemical Engineering, 2012
The present paper describes a simple, selective and sensitive kinetic method for the determination of trace amounts of Sb(III) in the presence of Sb(V) based on its inhibition effect on the redox reaction between bromate and Victoria blue 4R (V.B.
Violeta Mitić   +2 more
doaj   +1 more source

Bromate removal from aqueous solutions by ordered mesoporous carbon

open access: yes, 2014
We investigated the feasibility of using ordered mesoporous carbon (OMC) for bromate removal from water. Batch experiments were performed to study the influence of various experimental parameters such as the effect of contact time, adsorbent dosage ...
Chunhua Xu (391733)   +5 more
core   +1 more source

Construction of Nafion/Hb/Au/ZIF-8/CILE and its application as electrochemical sensor for determination of bromate and nitrite

open access: yesInternational Journal of Electrochemical Science, 2019
In this paper zinc-based metal organic framework material (ZIF-8) modified carbon ionic liquid electrode (CILE) was prepared and electrodeposited with gold nanoparticles to get a composite modified electrode, which was used as the sensing interface for ...
Juan Liu   +11 more
doaj   +1 more source

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