Results 31 to 40 of about 7,841,789 (286)
Angewandte Chemie, 2020 The design of synthetic routes via retrosynthetic logic is decisively influenced by the transformations available. In this context, transition metal-catalyzed C-H activation has emerged as a powerful strategy for C-C bond formation, with myriad methods ...
Nelson Y. S. Lam, K. Wu, jin-quan yu
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Hydroarylations by cobalt-catalyzed C–H activation
Beilstein Journal of Organic Chemistry, 2018 As an earth-abundant first-row transition metal, cobalt catalysts offer a broad range of economical methods for organic transformations via C–H activation.
Rajagopal Santhoshkumar +1 more
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Molecules, 2021 The regioselective C-H functionalization of the five-membered ring of the 6,5-fused heterocyclic systems is nowadays well documented due to its high reactivity compared to the six-membered ring.
Soukaina Faarasse +3 more
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Competitive Activation of a Methyl C−H Bond of Dimethylformamide at an Iridium Center [PDF]
, 2009 During the synthesis of [AsPh_4][Ir(CO)_2I_3Me] by refluxing IrCl_3·3H_2O in DMF (DMF = dimethylformamide) in the presence of aqueous HCl, followed by sequential treatment with [AsPh_4]Cl, NaI, and methyl iodide and finally recrystallization from ...
Bercaw, John E. +4 more
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Mild metal-catalyzed C-H activation: examples and concepts.
Chemical Society Reviews, 2016 Organic reactions that involve the direct functionalization of non-activated C-H bonds represent an attractive class of transformations which maximize atom- and step-economy, and simplify chemical synthesis.
T. Gensch +3 more
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Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide
Beilstein Journal of Organic Chemistry, 2011 N-(4-homoadamantyl)phthalimide (5) on excitation and population of the triplet excited state underwent intramolecular H-abstractions and gave products 6 and 7.
Nikola Cindro +4 more
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Hydrogen Motion in Magnesium Hydride by NMR [PDF]
, 2008 In coarse-grained MgH2, the diffusive motion of hydrogen remains too slow (
Bormann, Rüdiger +11 more
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Enantioselective Rhodium-Catalyzed C–C Bond Activations
CHIMIA, 2010 The catalytic activation of carbon–carbon single bonds represents a major challenge in organometallic chemistry. Strained ring substrates occupy in this respect a privileged role as their inherent ring strain facilitates the desired metal ...
Tobias Seiser, Nicolai Cramer
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Divergent isoindolinone synthesis through palladium-catalyzed isocyanide bridging C–H activation
Cell Reports Physical Science, 2022 Summary: The formation of thermodynamically accessible metallacycle is crucial to achieve site-selective C–H bond activation. Here, we report an isocyanide-bridging C–H activation through the formation of a five-membered palladacycle. As such, a proximal
Fulin Zhang +6 more
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Carboxylic Solvents and O-Donor Ligand Effects on CH Activation by Pt(II) [PDF]
, 2006 We report on the design of more efficient C−H activation catalysts based on DFT calculations. The first examples of well-defined, N,O-donor ligated platinum complexes that are competent for fast C−H activation are detailed.
Goddard, William A., III +5 more
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