Selective C(sp3)–H arylation/alkylation of alkanes enabled by paired electrocatalysis [PDF]
Nature Communications, 2023 We report a combination of electrocatalysis and photoredox catalysis to perform selective C(sp3)–H arylation/alkylation of alkanes, in which a binary catalytic system based on earth-abundant iron and nickel is applied.
Long Zou +3 more
doaj +2 more sources
Direct C-H:C-H Arylation Polymerization of 3,4-Propylenedioxythiophene Derivatives [PDF]
, 2021 In this manuscript, we report, for the first time, a direct C-H:C-H arylation process for the polymerization of 3,4-propylenedioxythiophene derivatives.
Nagaraj , Nayak +3 more
core +2 more sources
Illuminating Synergistic Catalysis: SET-HAT Unlocks Proximal C–H Arylation of Aromatic Amines [PDF]
JACS AuVishal Jyoti Roy +3 more
doaj +2 more sources
Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Pd(II)-MPAA Catalyzed C-H Arylation and Olefination [PDF]
, 2021 A direct Pd(II)-catalyzed kinetic resolution of heteroaryl-enabled sulfoximines through an ortho-C-H alkenylation/arylation of arenes has been developed for the first time.
Vincent , Gandon +6 more
core +1 more source
Challenging Atroposelective C–H Arylation
SynOpen, 2020 Atropisomeric molecules are privileged scaffolds, not only as ligands for asymmetric synthesis, but also as biologically active products and advanced materials.
Joanna Wencel-Delord +1 more
doaj +1 more source
Pd(II)-Catalyzed Synthesis of Benzocyclobutenes by β-Methylene-Selective C(sp3)‒H Arylation with a Transient Directing Group [PDF]
, 2021 Methylene-selective C‒H functionalization is a significant hurdle that remains to be addressed in the field of Pd(II) cataly-sis. In this paper we report a Pd(II) catalyzed synthesis of benzocyclobutenes by methylene-selective C(sp3)‒H arylation of ...
Jonathan, Wong +6 more
core +1 more source
Twofold C-H Activation-Based Enantio- and Diastereoselective C-H Arylation Using Diarylacetylenes as Rare Arylating Reagents [PDF]
, 2021 C-H bond activation has been established as an attractive strategy to access axially chiral biaryls, and the most straightforward method is direct C-H arylation of arenes.
Xingwei, Li +4 more
core +2 more sources
Synthesis of Novel 3,6-Dithienyl Diketopyrrolopyrrole Dyes by Direct C-H Arylation
Molecules, 2020 Direct C-H arylation coupling is potentially a more economical and sustainable process than conventional cross-coupling. However, this method has found limited application in the synthesis of organic dyes for dye-sensitized solar cells. Although direct C-
Amsalu Efrem Yemene +4 more
doaj +1 more source
Research, 2020 Controllable direct C-H arylation with high regioselectivity is highly desirable yet remains a formidable challenge. Herein, a facile regioselective direct C-H arylation is developed for efficient construction of a variety of symmetrical ...
Xiang-Chun Li +8 more
doaj +1 more source
Nature Communications, 2023 Transition metal-catalyzed C–H bond functionalization is an important method in organic synthesis, but the development of methods that are lower cost and have a less environmental impact is desirable. Here, a Cu-catalyzed asymmetric C(sp2)–H arylation is
Shao-Bai Yan +5 more
doaj +1 more source