Undirected C-H Bond Activation in Aluminium Hydrido Enaminonates [PDF]
Molecules, 2023 Two new aluminium hydrido complexes were synthesized by reacting AlH3 with the enaminone ligand N-(4,4,4-trifluorobut-1-en-3-on)-6,6,6-trifluoroethylamine (HTFB-TFEA) in different molar ratios to obtain mono- and di-hydrido-aluminium enaminonates.
Chijioke Kingsley Amadi +4 more
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Systematic Assessment of the Catalytic Reactivity of Frustrated Lewis Pairs in C-H Bond Activation [PDF]
Molecules, 2023 Unreactive C-H bond activation is a new horizon for frustrated Lewis pair (FLP) chemistry. This study provides a systematic assessment of the catalytic reactivity of recently reported intra-molecular FLPs on the activation of typical inert C-H bonds ...
Yongjie Guo +7 more
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Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization [PDF]
Molecules, 2021 Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is ...
Antonio Zucca, Maria I. Pilo
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Recent Advances in the Synthesis of Cyclic Sulfoximines via C–H Bond Activation [PDF]
Molecules, 2023 Sulfoximines, a ubiquitous class of structural motifs, are widely present in bioactive molecules and functional materials that have received considerable attention from modern organic chemistry, pharmaceutical industries, and materials science ...
Bingren Wang, Xiayu Liang, Qingle Zeng
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Transition-Metal-Catalyzed C–H Bond Activation for the Formation of C–C Bonds in Complex Molecules [PDF]
Chemical Reviews, 2023 Jamie Docherty, , Michael T Findlay
exaly +2 more sources
Coumarins Synthesis and Transformation via C–H Bond Activation—A Review
Inorganics, 2022 For several decades, coumarins have attracted considerable attention due to the fact of their application in diverse fields such as medical science and biomedical research as well as several industrial branches.
Katarzyna Szwaczko
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Strategies to transform remote C(sp3)-H bonds of amino acid derivatives
Tetrahedron Chem, 2022 Amino acids and peptides play an important role in nature as well as in the pharmaceutical industry. Therefore, transformation of amino acids and peptides into their unnatural derivatives via step and atom economical ways is highly demanding. Although, a
Supreeta Sen +2 more
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Catalytic C–H Bond Activation and Knoevenagel Condensation Using Pyridine-2,3-Dicarboxylate-Based Metal–Organic Frameworks [PDF]
ACS Omega, 2021 Rampal Pandey +3 more
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Divergent isoindolinone synthesis through palladium-catalyzed isocyanide bridging C–H activation
Cell Reports Physical Science, 2022 Summary: The formation of thermodynamically accessible metallacycle is crucial to achieve site-selective C–H bond activation. Here, we report an isocyanide-bridging C–H activation through the formation of a five-membered palladacycle. As such, a proximal
Fulin Zhang +6 more
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Selective activation of CH bond of phenol in ortho-position into COH bond in a two-phase system
Catalysis Communications, 2021 A method for the selective activation of CH bond of phenol in ortho-position into C-OH bond was developed at room temperature over Cu2+ ions in a two-phase system using marginally water-soluble polar alcohols, acetonitrile and water as solvents and ...
Ke Zheng +4 more
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