Comprehensive perspectives of metal and metal-free C-H activation approaches in pyrimidines and related heteroarenes: scope, mechanistic insights, and synthetic utility. [PDF]
Mirfarah A, Hatami S, Shiri A.
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Titanium-Mediated Rearrangement of Bis(alkynyl)boranes: B─C Activation versus C─H Activation. [PDF]
Ma C +6 more
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Divergent Kinetic/Thermodynamic Selectivity in Palladium(II)-Mediated C-H Activation to Form 5- and 6-Membered Palladacycles. [PDF]
Zhou PS +4 more
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Orchestrating Multi-Ångstrom Spaced Cu─Ni Dual-Atom Pair for Synergistic C─H Activation in Direct Methane Oxidation to Methanol. [PDF]
Jin J, Li W, Wang L, Zhang L, Zhang X.
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Deuteration of Arenes via Pd-Catalyzed C-H Activation: A Lesson in Nondirected C-H Activation, Isotopic Labeling, and NMR Characterization. [PDF]
Deufel F, van Gemmeren M.
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Flash Communication: Flexibility of a Biologically Inspired Ligand Framework for Intramolecular C-H Activation. [PDF]
Moore JM, Park YJ, Fout AR.
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Copper Catalyzed C−H Activation
The Chemical Record, 2018AbstractActivation of C−H bonds and their application in cross coupling chemistry has received a wider interest in recent years. The conventional strategy in cross coupling reaction involves the pre‐functionalization step of coupling reactants such as organic halides, pseudo‐halides and organometallic reagents.
M Lakshmi, Kantam +4 more
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Although the biocatalytic activation of carbon-hydrogen bonds by oxidation to alcohols was one of the first biotransformations to be exploited by the chemical industry, this remarkable process continues to be the subject of intense research activity.
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AbstractFor Abstract see ChemInform Abstract in Full Text.
Fumitoshi Kakiuchi, Naoto Chatani
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Cobalt-Catalyzed C–H Activation
Catalytic C-H activation has emerged as a powerful tool for sustainable syntheses. In the recent years, notable success was achieved with the development of cobalt catalyzed C-H functionalizations with either in situ generated or single-component cobalt ...
Lutz Ackermann
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