Results 251 to 260 of about 31,423,583 (299)
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Copper Catalyzed C−H Activation
The Chemical Record, 2018AbstractActivation of C−H bonds and their application in cross coupling chemistry has received a wider interest in recent years. The conventional strategy in cross coupling reaction involves the pre‐functionalization step of coupling reactants such as organic halides, pseudo‐halides and organometallic reagents.
M Lakshmi, Kantam +4 more
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ChemInform, 2004
AbstractFor Abstract see ChemInform Abstract in Full Text.
Fumitoshi Kakiuchi, Naoto Chatani
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AbstractFor Abstract see ChemInform Abstract in Full Text.
Fumitoshi Kakiuchi, Naoto Chatani
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Current Opinion in Chemical Biology, 1999
Although the biocatalytic activation of carbon-hydrogen bonds by oxidation to alcohols was one of the first biotransformations to be exploited by the chemical industry, this remarkable process continues to be the subject of intense research activity.
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Although the biocatalytic activation of carbon-hydrogen bonds by oxidation to alcohols was one of the first biotransformations to be exploited by the chemical industry, this remarkable process continues to be the subject of intense research activity.
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Understanding and Exploiting C—H Bond Activation
ChemInform, 2002AbstractFor Abstract see ChemInform Abstract in Full Text.
Labinger, Jay A., Bercaw, John E.
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2014
The C–H activation reaction is a reaction that cleaves a carbon–hydrogen bond. Here the carbon–hydrogen bond is mostly referred to unactivated carbon–hydrogen bonds.
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The C–H activation reaction is a reaction that cleaves a carbon–hydrogen bond. Here the carbon–hydrogen bond is mostly referred to unactivated carbon–hydrogen bonds.
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Electrophilic C−H Activation at {Cp*Ir}: Ancillary-Ligand Control of the Mechanism of C−H Activation
Journal of the American Chemical Society, 2006Density functional calculations on the low-temperature cyclometalation of dimethylbenzylamine with [IrCl2Cp*]2/NaOAc have characterized a novel electrophilic activation pathway for C-H bond activation. C-H activation occurs from [Ir(DMBA-H)(kappa2-OAc)Cp*]+, and OAc plays a central role in determining the barrier for reaction.
Davies, David L. +4 more
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Angewandte Chemie, 2018
AbstractDisclosed herein is the merging of C−H activation and radical chemistry, enabling rapid access to a structurally diverse family of fused carbohelicenes through the fusion of α‐acetylnaphthalenes with alkynes under oxidative conditions. This cascade process exhibits exquisite chemoselectivity and regioselectivity.
Jiangliang Yin, Jingsong You
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AbstractDisclosed herein is the merging of C−H activation and radical chemistry, enabling rapid access to a structurally diverse family of fused carbohelicenes through the fusion of α‐acetylnaphthalenes with alkynes under oxidative conditions. This cascade process exhibits exquisite chemoselectivity and regioselectivity.
Jiangliang Yin, Jingsong You
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Chemical Communications, 2009
An organocatalytic stereoselective alpha-alkylation reaction of aldehydes based on C-H activation is presented.
F. Benfatti +4 more
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An organocatalytic stereoselective alpha-alkylation reaction of aldehydes based on C-H activation is presented.
F. Benfatti +4 more
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Intramolecular C−H Activation Reactions of Molybdenacyclobutanes
Journal of the American Chemical Society, 2006Molybdenacyclobutane complexes can be prepared by reaction of Cp*Mo(NO)(=CHCMe3) (formed spontaneously by loss of neopentane from Cp*Mo(NO)(CH2CMe3)2 (1) under ambient conditions) with cyclic olefins, including cyclopentene, cycloheptene, and cyclooctene. The cyclopentene metallacyclobutane orients the metallacycle bridgehead protons cis to each other.
Peter M, Graham +2 more
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