Enantioselective C(sp<sup>3</sup>)-H bond functionalization enabled by Cp <sup><i>x</i></sup> M(iii) catalysis (M = Co, Rh, Ir). [PDF]
Mou SB +5 more
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Enantioselective C-H functionalization: logic and applications in the total synthesis of natural products. [PDF]
Qian PF, Shi BF.
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Caging the Chlorine Radical: Chemoselective Photocatalytic C(sp<sup>3</sup>)-H Functionalization Enabled by Terminal Cu-Cl Sites in a Metal-Organic Framework. [PDF]
Eaton MC +7 more
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Sensing of Nitroaromatics Using Substituted Nitrene-Functionalized Boron Carbide Nanosurfaces. [PDF]
Baachaoui S, Aldulaijan S, Raouafi N.
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Organocatalysis in Inert C–H Bond Functionalization
Chemical Reviews, 2017As two coexisting and fast-growing research fields in modern synthetic chemistry, the merging of organocatalysis and C-H bond functionalization is well foreseeable, and the joint force along this line has been demonstrated to be a powerful approach in making inert C-H bond functionalization more viable, predictable, and selective.
Lihui Zhu, Sanzhong Luo
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C-H Bond Functionalization in Complex Organic Synthesis
Science, 2006Direct and selective replacement of carbon-hydrogen bonds with new bonds (such as C–C, C–O, and C–N) represents an important and long-standing goal in chemistry. These transformations have broad potential in synthesis because C–H bonds are ubiquitous in organic substances. At the same time, achieving selectivity among many different C–H bonds remains a
Kamil, Godula, Dalibor, Sames
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C−H Bond Functionalization by Mechanochemistry
Chemistry – A European Journal, 2017AbstractThe advances made in the mechanosynthesis of inorganic and organometallic complexes and the excellent past developments with metal‐catalyzed cross‐coupling reactions by high‐speed ball milling have sufficienly laid the ground work for the merging of C−H functionalization and mechanochemical techniques.
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1.3 C—H Bond Functionalization
2017AbstractThis chapter deals with C—H bond functionalization catalyzed by N-heterocyclic carbene transition-metal complexes. The C—H bond functionalizations have been classified with respect to the hybridization of the carbon atom and the reaction type.
M. Elie, J.-L. Renaud, S. Gaillard
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CH Bond Functionalization through Intramolecular Hydride Transfer
Angewandte Chemie International Edition, 2014AbstractKnown for over a century, reactions that involve intramolecular hydride‐transfer events have experienced a recent resurgence. Undoubtedly responsible for the increased interest in this research area is the realization that hydride shifts represent an attractive avenue for CH bond functionalization.
Michael C, Haibach, Daniel, Seidel
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Functionalization of C-H Bonds by Photoredox Catalysis
The Chemical Record, 2017Visible-light photoredox catalysis has been successfully used in the functionalization of inert C-H bonds including C(sp2 )-H bonds of arenes and C(sp3 )-H bonds of aliphatic compounds over the past decade. These transformations are typically promoted by the process of single-electron-transfer (SET) between substrates and photo-excited photocatalyst ...
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