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Noncovalent Interactions in C–H Bond Functionalization
2019Over the past few decades, direct functionalization/activation of the C–H bond to C–E (E = C, N, O, S, metal, etc.) bonds has become one of the most valuable and straightforward protocols in modern synthetic chemistry. In parallel, controlling the selectivity remains a central challenge in the catalytic functionalization/activation of C–H bond(s) owing
Kamran T. Mahmudov +3 more
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Ir-Catalyzed Functionalization of C–H Bonds
2010The ability to selectively functionalize C–H bonds holds enormous potential value in virtually every sphere of organic chemistry, from fuels to pharmaceuticals. Transition metal complexes have shown great promise in this context. Iridium provided the first examples of oxidative addition of C–H bonds; this addition is key to iridium’s leading role in ...
Jongwook Choi, Alan S. Goldman
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Site-specific allylic C–H bond functionalization with a copper-bound N-centred radical
Nature, 2019Jia-Yao Li +6 more
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Transition metal-catalyzed site- and regio-divergent C-H bond functionalization.
Chemical Society Reviews, 2017Lu Ping +3 more
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Carbon–Carbon Bond Cleavage for Late-Stage Functionalization
Chemical Reviews, 2023Yu-Feng Liang, Ning Jiao, Muhammad Bilal
exaly
Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis
Chemical Reviews, 2021Jia-Rong Chen, Wen-Jing Xiao, Xiao-Ye Yu
exaly
Photoelectrochemical Approaches for the Functionalization of C-H Bonds
The combination of photocatalysis and electrochemistry has recently emerged as a powerful approach in organic synthesis, enabling the (selective) elaboration of ubiquitous C–H bonds. Photoelectrochemical strategies are driven by open-shell intermediates (radicals and radical-ions), that lead to the desired products with high efficiency thanks to the ...Alexandra Jorea +2 more
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