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Noncovalent Interactions in C–H Bond Functionalization

2019
Over the past few decades, direct functionalization/activation of the C–H bond to C–E (E = C, N, O, S, metal, etc.) bonds has become one of the most valuable and straightforward protocols in modern synthetic chemistry. In parallel, controlling the selectivity remains a central challenge in the catalytic functionalization/activation of C–H bond(s) owing
Kamran T. Mahmudov   +3 more
openaire   +1 more source

Programmable late-stage C−H bond functionalization enabled by integration of enzymes with chemocatalysis

Nature Catalysis, 2021
Elliott J. Craven   +6 more
semanticscholar   +1 more source

Ir-Catalyzed Functionalization of C–H Bonds

2010
The ability to selectively functionalize C–H bonds holds enormous potential value in virtually every sphere of organic chemistry, from fuels to pharmaceuticals. Transition metal complexes have shown great promise in this context. Iridium provided the first examples of oxidative addition of C–H bonds; this addition is key to iridium’s leading role in ...
Jongwook Choi, Alan S. Goldman
openaire   +1 more source

Site-specific allylic C–H bond functionalization with a copper-bound N-centred radical

Nature, 2019
Jia-Yao Li   +6 more
semanticscholar   +1 more source

Transition metal-catalyzed site- and regio-divergent C-H bond functionalization.

Chemical Society Reviews, 2017
Lu Ping   +3 more
semanticscholar   +1 more source

Carbon–Carbon Bond Cleavage for Late-Stage Functionalization

Chemical Reviews, 2023
Yu-Feng Liang, Ning Jiao, Muhammad Bilal
exaly  

Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis

Chemical Reviews, 2021
Jia-Rong Chen, Wen-Jing Xiao, Xiao-Ye Yu
exaly  

Photoelectrochemical Approaches for the Functionalization of C-H Bonds

The combination of photocatalysis and electrochemistry has recently emerged as a powerful approach in organic synthesis, enabling the (selective) elaboration of ubiquitous C–H bonds. Photoelectrochemical strategies are driven by open-shell intermediates (radicals and radical-ions), that lead to the desired products with high efficiency thanks to the ...
Alexandra Jorea   +2 more
openaire   +2 more sources

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