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Flow Chemistry Perspective for C H Bond Functionalization
2017In this chapter, we give an overview of the use of continuous-flow reactors for C. H activation chemistry.
Laudadio, G., Noël, T.
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Activation and Functionalization of C—H Bonds
2004Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationally leading research groups contributed to this volume, and their chapters cover such topics as fundamental ...
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Functionalization and Homologation of C-H Bonds
2013Justin Du Bois of Stanford University developed (J. Am. Chem. Soc. 2010, 132, 10202) a Ru catalyst for the stereoretentive hydroxylation of 1 to 2. John T. Groves of Princeton University effected (J. Am. Chem. Soc. 2010, 132, 12847) equatorial chlorination of the test substrate 3. Kenneth M. Nicholas of the University of Oklahoma found (J. Org.
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Asymmetric Functionalization of C–H Bonds
2015Asymmetric C-H direct functionalization reactions are one of the most active and fascinating areas of research in organic chemistry due to their significance in the construction of molecular complexity without pre-activation, and the step economy and atom economy features in potential synthetic application.
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Cobalt-Catalyzed C-H Bond Functionalization
The ultimate goal of organic synthetic chemistry is to design and synthesize more complex structures from simple molecules. Classic organic synthesis often relies on the manipulations of functional groups. In organic chemistry, the term 'C-H bond functionalization' is used to describe a chemical reaction, in which a C-H bond of a substrate is cleaved ...openaire +3 more sources
Ir-Catalyzed Functionalization of C–H Bonds
2010The ability to selectively functionalize C–H bonds holds enormous potential value in virtually every sphere of organic chemistry, from fuels to pharmaceuticals. Transition metal complexes have shown great promise in this context. Iridium provided the first examples of oxidative addition of C–H bonds; this addition is key to iridium’s leading role in ...
Jongwook Choi, Alan S. Goldman
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Noncovalent Interactions in C–H Bond Functionalization
2019Over the past few decades, direct functionalization/activation of the C–H bond to C–E (E = C, N, O, S, metal, etc.) bonds has become one of the most valuable and straightforward protocols in modern synthetic chemistry. In parallel, controlling the selectivity remains a central challenge in the catalytic functionalization/activation of C–H bond(s) owing
Kamran T. Mahmudov +3 more
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C-H and C-X Bond Functionalization
20131. Cu-catalyzed Ullmann-type C-heteroatom bond formation: the key role of dinucleating ancillary ligands 2. Mechanistic understanding of copper-catalyzed aryl-heteroatom bond formation: dependence on ancillary ligands 3. Fundamental Pd(0)/Pd(II) redox steps in cross-coupling reactions 4.
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Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis
Chemical Reviews, 2021Jia-Rong Chen +2 more
exaly
Photoelectrochemical Approaches for the Functionalization of C-H Bonds
The combination of photocatalysis and electrochemistry has recently emerged as a powerful approach in organic synthesis, enabling the (selective) elaboration of ubiquitous C–H bonds. Photoelectrochemical strategies are driven by open-shell intermediates (radicals and radical-ions), that lead to the desired products with high efficiency thanks to the ...Alexandra Jorea +2 more
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