Übergangsmetall-Carben-Komplexe, CXXVI [1]. Darstellung und Struktur symmetrischer Hydroxycarben-Anhydrid-Komplexe des Mangans und Rheniums / Transition Metal Carbene Complexes, CXXVI [1]. Preparation and Structure of Symmetrica! Hydroxycarbene Anhydride Complexes of Manganese and Rhenium [PDF]
, 1982 Ernst Otto Fischer +2 more
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Angewandte Chemie, EarlyView.Eine kooperative N‐heterozyklische Carben und Photoredox‐Katalyse zur C−H Benzoylierung und Veresterung von Allenen wird präsentiert. Diese Reaktion verläuft über die Kreuzkupplung von in situ generierten Ketyl‐ und Allylradikalen. Zusammenfassung Diese Studie demonstriert die Verwendung von kooperativer Photoredox‐ und N‐heterozyklischer Carben (NHC ...
Shyam Kumar Banjare +2 more
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Reaction of Carbenes with Cyclic Ethers in the Presence of Nucleophiles. A Three-Component Coupling Reaction. [PDF]
, 1993 Akira Oku +9 more
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Reaktionen von Komplexliganden, LVI. 3-Pyrrolylcarben-Komplexe des Chroms: Darstellung und neuartige Carbenanellierung zum Isoindol-Gerüst / Reactions of Complex Ligands, LVI. 3-Pyrrolylcarbene Complexes of Chromium: Synthesis and Carbene Annulation to the Isoindole Skeleton [PDF]
, 1993 Karl Heinz Dötz, Jörg Glänzer
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Angewandte Chemie International Edition, EarlyView.We demonstrate the unique reactivity of a mesoionic imine with bis‐aryl carbodiimides, forming an MII‐CDI adduct at room temperature via a spontaneous 1,3‐H shift. These MII‐CDI adducts serve as important synthons for mesoionic carbene‐acyclic diamino carbene‐stabilized nitreones (I) and guanidinate‐type ligands.
Alok Mahata +4 more
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The Chemistry and Biology of the Tetrodotoxin Natural Product Family
Angewandte Chemie International Edition, EarlyView.Tetrodotoxin is best known as the poison of the pufferfish, which is a delicacy in Japanese cuisine. Its toxicity arises from the selective blockage of NaV channels, which is depicted for the NaV1.7 pore, highlighting the DEKA motif, which permeates sodium ions.
Benedikt Nißl +6 more
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Chemistry of Carbene Complexes : Ylids and Inverse Ylids
, 1969 Hitosi Nozaki
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Competing Radical, Carbanion, and Carbene Intermediates in the Reaction of a Primary Alkyl Halide with Lithium Diisopropylamide. [PDF]
, 1990 E. C. Ashby +6 more
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Angewandte Chemie International Edition, EarlyView.The reaction of a dihydro‐dialane supported by a hybrid ligand (DNI) with organic azides yields structurally diverse aluminium species, including the first example of low oxidation state aluminium azide complex, a diazido‐dialane, along with an aluminium‐tetrazole, and azide alumination.
Xiaobai Wang +7 more
wiley +1 more source
Electronic Structure and Reactivity of Carbenes
, 1964 Hitosi Nozaki, R. Noyori
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