A new visible light‐induced method is reported for the C3‐alkylation of imidazo[1,2‐a]pyrimidines and ‐pyridines with aryldiazoacetates. This protocol can be performed in open air and serves as a convenient entry to several known and new molecules. A formal synthesis of zolpidem is achieved by changing the alkylating agent to an appropriate hypervalent
Ronei M. S. Souza+6 more
wiley +1 more source
Synthesis of Furano[2,3‐c]pyran‐3‐one and Thieno[2,3‐c]pyran‐3‐one Derivatives Through the Coupling of 3‐Alkynyl‐2‐heteroaromatic Carboxaldehydes with Fischer Carbene Complexes: Total Synthesis of a Baccharis‐Derived Cadinene Derivative. [PDF]
Yanshi Zhang, James W. Herndon
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Silyl‐NHC chelate iron complexes with various substituents on NHC were synthesized and demonstrated to be active catalysts for hydroboration and dehydrogenative borylation of olefins. The selectivity of these borylation reactions is significantly controlled by the steric bulk of a substituent on the NHC nitrogen.
Nozomu Ishiwata+5 more
wiley +1 more source
Phosphinoisocyanide/Alkyne Cycloaddition: Generation of Azaphospholylidene (NPHC) Ligands. [PDF]
Kirk RM, Hill AF.
europepmc +1 more source
Triplet carbenes: From fleeting existence to attractive molecular units [PDF]
H. TOMIOKA
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Saccharinate‐Based Ionic Liquids and Lithium Battery Electrolytes
Fluorine‐free ionic liquids (ILs) with saccharinate anion coupled to ether‐functionalized pyrrolidinium/imidazolinium cations exhibit promising thermal, transport, and electrochemical properties. The imidazolinium‐based ILs offer higher electrochemical stability, while the pyrrolidinium‐based ILs display superior ion transport.
Mukhtiar Ahmed+4 more
wiley +1 more source
Copper-catalyzed direct regioselective C5-H alkylation reactions of functionalized indoles with α-diazomalonates. [PDF]
Isono T, Harada S, Yanagawa M, Nemoto T.
europepmc +1 more source
A series of all‐cis ring fluorinated cyclohexylalanines with progressively increasing levels of vicinal fluorines, as well as 4‐fluorophenylalanine and pentafluoroarylphenylalanine were introduced into the WKYMVm peptide in place of its tyrosine residue, for assays against the G‐protein coupled formylpeptide receptor, FPR2.
David O'Hagan+6 more
wiley +1 more source
Insertion of Nitriles Into a Gold(III)/Carbene Bond: A Direct and Powerful Entry to Imino-Substituted Carbenes. [PDF]
Wei R+4 more
europepmc +1 more source
Dirhodium(II) Carbenes : The Chiral Product Cascade
Gregory Roos+2 more
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