Gas-Phase Synthesis of Charged Copper and Silver Fischer Carbenes from Diazomalonates: Mechanistic and Conformational Considerations in Metal-Mediated Wolff Rearrangements [PDF]
, 2003 Ryan R. Julian +3 more
openalex +1 more source
ChemistryEurope, EarlyView.A kinetically stable Wheland intermediate of the electrophilic aromatic substitution at ferrocene is isolated from the reaction of the diferrocenylphosphenium ion with the allene 2‐(trimethylsilyl)‐2,3‐pentadiene and fully characterized. The reaction of the diferrocenylphosphenium ion with four terminal allenes follows two different pathways, via allyl
Corina Stoian +7 more
wiley +1 more source
ROMP and Vinyl Polynorbornenes with Vanadium(III) and Nickel(II) diNHC Complexes. [PDF]
Int J Mol SciHalikowska-Tarasek K +4 more
europepmc +1 more source
Pd‐Catalyzed Allylic Substitution Using Nucleophilic N‐Heterocyclic Carbene as a Ligand. [PDF]
, 2003 Yoshihiro Sato +2 more
openalex +1 more source
Visible Light‐Induced N‐Heterocyclic Nitrenium‐Catalyzed Deoxygenative Borylation of Acyl Chlorides
ChemistryEurope, EarlyView.Herein, direct deoxygenative borylation of acyl chlorides is reported, which is an unknown but desirable chemical transformation. The N‐heterocyclic nitrenium ion has been utilized as the photocatalyst under mild reaction conditions to synthesize a series of alkylboronates using bis‐(catecholato)diboron (B2cat2) as the diboron reagent.
Rahul Mondal +2 more
wiley +1 more source
Carbenoid Reactions Promoted by Solids: From Lewis to Brønsted Catalysts. [PDF]
Acc Chem ResLeyva-Pérez A, Mon M, Zheng Y.
europepmc +1 more source
Geometrically Strained Carbenes: Interdependence among Geometry, Spin Multiplicity, and Reactivity.
, 2001 Yasutake Takahashi +2 more
openalex +2 more sources
Synthesis of Pyrroles Through Coupling of Enyne‐Hydrazones with Fischer Carbene Complexes. [PDF]
, 2003 Yanshi Zhang, James W. Herndon
openalex +1 more source
Gallium Nitride in Heterogeneous Photocatalysis: Fundamental Insights and Emerging Trends
ChemistryEurope, EarlyView.Gallium nitride is a binary III–V direct band gap semiconductor. Recently, it has emerged as a promising material for next‐generation heterogeneous photocatalytic systems due to its unique electronic and structural properties. This review outlines the fundamental principles and key design strategies of heterogeneous photocatalysis and provides a ...
Hyotaik Kang, Chao‐Jun Li
wiley +1 more source
Confirmation of Breslow's hypothesis: A carbene stable in liquid water. [PDF]
Sci AdvRaviprolu VT +7 more
europepmc +1 more source