Konjugierte Anorganisch‐Organische Hybrid‐Polymere mit p‐Block Elementen
Der Einfluss unterschiedlicher p‐Block‐Element‐Motive auf die photophysikalischen Eigenschaften konjugierter anorganisch‐organischer Hybridpolymere im Hinblick auf die Anwendung in organischen Elektronikbauteilen wird dargelegt. Die jüngsten Fortschritte beim Einsatz der schwereren Elemente und schwererer Mehrfachbindungen sowie zu diversen (Post ...
Anna‐Lena Thömmes +1 more
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Difluoro Carbenes: From Genuine Gold Complexes to Unprecedented Metallacyclic Reactivity. [PDF]
Vesseur D +6 more
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Coordination-Accelerated Catalysis in the Heck Reaction Using N-H <i>N</i>-Heterocyclic Carbene Pd Complexes. [PDF]
Harper AP +6 more
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N‑Heterocyclic Carbene Stabilized Aluminum Alkyls and Their Reactivity toward NHC-Alanes. [PDF]
Burnett S, Kennedy AR, Weetman CE.
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Conjugated Inorganic–Organic Hybrid Polymers with p‐Block Elements
The influence of various p‐block element motifs on the photophysical properties of conjugated inorganic‐organic hybrid polymers is surveyed regarding applications in organic electronics. Recent advances in the use of heavier elements as well as heavier multiple bonds and the development of diverse (post‐)functionalization strategies suggest ample scope
Anna‐Lena Thömmes +1 more
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Alkene Diversification through a Molecular Recasting Strategy Enabled by <i>N</i>-Heterocyclic Carbene and Photoredox Dual Catalysis. [PDF]
Li QZ +6 more
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Synthetic study toward vibralactone. [PDF]
Shi L +7 more
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In this article, the synthesis and reactivity of an aluminum triiodide supported by N‐heterocyclic carbene/cyclic(alkyl)(amino)carbene‐based carbodicarbene ligands were reported. Along the research journey towards novel low‐valent aluminum compounds, bulky σ‐donor ligand adducts of aluminum(III) halides are prevalent synthons. These ligands’ steric and
Yueer Zhu +2 more
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Enantioselective intramolecular cyclopropanation via a cationic sulfoxonium-Rh-carbene. [PDF]
Xing Y +6 more
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Formation of Uranium Pinacolate from the Reductive Coupling of Acetone
Uranium(III) cyclopentadienyl complexes are shown to react with acetone in a pinacol coupling, forming uranium pinacolate complexes. Single crystals obtained from the reaction are the first direct structural proof of the previously proposed metallapinacolate intermediate. 1,2‐Diols are elemental building blocks in organic synthesis.
León Hillers, Lisa Vondung
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