Results 61 to 70 of about 101,444 (317)

Well-defined silica-supported olefin metathesis catalysts [PDF]

, 2009
Two triethoxysilyl-functionalized N-heterocyclic carbene ligands have been synthesized and used to prepare the corresponding second-generation ruthenium olefin metathesis catalysts.
Allen, Daryl P., Grubbs, Robert H., Van Wingerden, Matthew M.   +2 more
core   +1 more source

N‐heterocyclic Carbenes as Adhesion Promoters on Aluminum Alloy 6061

Advanced Materials Interfaces, EarlyView.
N‐heterocyclic carbenes as novel non‐toxic surface primers for aluminum alloys for better adhesive bonding, because strong adhesive bonding shouldn't come at the cost of poisoning the human body. The impact of NHC functionalization on adhesive joint strength and durability is also evaluated using a single‐lap‐shear test, following continuous exposure ...
Jashanpreet Kaur, Vikram Singh, Alban Morel, Amélie Ruest, Mark D. Aloisio, Cathleen M. Crudden, Janine Mauzeroll   +6 more
wiley   +1 more source

Double E─H Bond Activation of Ammonia and Water by Cyclic Gallaphosphene L(OCP)GaPGaL

Angewandte Chemie, EarlyView.
Cyclic gallaphosphene 1 undergoes a twofold E─H bond activation with ammonia and water via a beneficial interplay between the polar “GaPGa” unit and the electrophilic nature of the C center in the bridging PCO unit, yielding six‐membered heterocycles 2 and 3, in which both nucleophilic phosphorus atoms are protonated.
Mahendra K. Sharma, Christoph Wölper, Gebhard Haberhauer, Stephan Schulz   +3 more
wiley   +2 more sources

C-H Functionalization via Iron-Catalyzed Carbene-Transfer Reactions

Molecules, 2020
The direct C-H functionalization reaction is one of the most efficient strategies by which to introduce new functional groups into small organic molecules.
Claire Empel, Sripati Jana, Rene M. Koenigs   +2 more
doaj   +1 more source

Submicron Patterning Techniques for Perovskite Optoelectronics From Materials Challenges to Scalable Device Integration

Advanced Optical Materials, EarlyView.
This review highlights submicron patterning strategies for metal halide perovskites, focusing on solvent compatibility, resolution, and alignment toward scalable integration in advanced optoelectronic systems. Abstract Halide perovskites are promising materials for future optoelectronic and display systems.
Dante Ahn, Minz Lee, Youngsoo Jang, Gun Young Jung, Yusin Pak   +4 more
wiley   +1 more source

PCA‐Based Database Mining Enables the Discovery of Bacterial Carbene Transferases for Stereodivergent Cyclopropanation

Angewandte Chemie, EarlyView.
Database mining using principal component analysis (PCA)‐based clustering enabled discovery of bacterial enzymes capable of catalyzing stereodivergent cyclopropanation of styrene. Statistical analyses of sequence data further revealed characteristic structural properties of these enzymes, highlighting the potential of the bioinformatics tools for ...
Shunsuke Kato, Koki Takeuchi, Kohei Umeda, Hisashi Kudo, Tomohisa Hasunuma, Takashi Hayashi   +5 more
wiley   +2 more sources

Design of a novel Fischer carbene complex which can facilitate thiol mediated site-specific protein immobilization

Results in Chemistry, 2022
A novel Fischer carbene complex has been synthesized which has tuneable reactivity owing to its dual functionality to facilitate binding with peptides and proteins via thiol moiety in presence of the amine groups of abundant lysine residues.
Namrata Ray
doaj   +1 more source

Vanadium (β-(Dimethylamino)ethyl)cyclopentadienyl Complexes with Diphenylacetylene Ligands [PDF]

, 2008
Reduction of the V(III) (β-(dimethylamino)ethyl)cyclopentadienyl dichloride complex [η5:η1-C5H4(CH2)2NMe2]VCl2(PMe3) with 1 equiv of Na/Hg yielded the V(II) dimer {[η5:η1-C5H4(CH2)2NMe2]V(µ-Cl)}2 (2).
Ahmed K. J., Arndt S., Baretta A., Basuli F., Beweries T., Blais M. S., Bradley S., Britovesk G. J. P., Buijink J. K. F., Buijink J.-K. F., de Bruin T. J. M., Deckers P. J. W., Deckers P. J. W., Evans W. J., Fachinetti G., Feghali K., Flores J. C., Flores J. C., Hessen B., Hessen B., Hessen B., Hessen B., Hessen B., Hessen B., Hirpo W., Johnson S. A., Jungst R., Jutzi P., Köhler F. H., Köhler F. H., Liu G. H., Lorber C., Marschner C., Mindiola D. J., Moore M., Nieman J., Nieman J., Nieman J., Rosenthal U., Rosenthal U., Schrock R. R.   +40 more
core   +5 more sources

Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes

Advanced Synthesis &Catalysis, EarlyView.
The combination of azole compounds and oxiranes exhibits carbenoid reactivity at elevated temperatures, as demonstrated by the successful benzoin condensation of aromatic aldehydes. Using this catalytic system to polymerize bifunctional aldehyde/oxirane monomers yields thermosets with glass transition temperatures above 100°C.
Matthias R. Steiner, Johanna M. Uher, Jürgen Lindner, Cordula M. Zeiler, Christian Slugovc   +4 more
wiley   +1 more source

Molecular Electrocatalyst Enables Direct Electrochemical Capture and Conversion of CO2 up to Atmospheric Concentration

Angewandte Chemie, EarlyView.
A molecular manganese electrocatalyst enables the direct electrochemical capture and conversion of dilute CO2 (1% – 0.2%) to CO with nearly unit Faradaic efficiency, achieving high efficiency even at atmospheric concentrations (420 ppm). By bypassing energy‐intensive pre‐concentration steps, this integrated approach highlights a sustainable pathway for
Mattia Vettori, Federico Franco, Sergio Fernández, Guillem Pey, Vlad Martin Diaconescu, Josep M. Luis, Julio Lloret‐Fillol   +6 more
wiley   +2 more sources