Results 11 to 20 of about 357,701 (311)

Carbonyl-Containing Solid Polymer Electrolyte Host Materials: Conduction and Coordination in Polyketone, Polyester, and Polycarbonate Systems

open access: yes, 2022
Research on solid polymer electrolytes (SPEs) is now moving beyond the realm of polyethers that have dominated the field for several decades. A promising alternative group of candidates for SPE host materials is carbonyl-containing polymers. In this work,
Daniel Brandell (1720741)   +8 more
core   +1 more source

Molybdenum and Tungsten Carbonyl Compounds Generate Carbonyl Sulfide (COS), but not Carbonyl Selenide (COSe), when Treated with Elemental Sulfur and Selenium

open access: yes, 2023
Carbonyl sulfide (COS) is implicated in prebiotic chemistry, and recent work on COS/H2S donors has invigorated COS chemistry. We demonstrate that [TpM(CO)3]- (M=Mo,W) react with S8 to form COS, but form [TpW(CO)2]2Se3 not COSe upon reaction with Se ...
Lev, Zakharov   +2 more
core   +1 more source

The flux of carbonyl sulfide and carbon disulfide between the atmosphere and a spruce forest [PDF]

open access: yes, 2002
Turbulent fluxes of carbonyl sulfide (COS) and carbon disulfide (CS2) were measured over a spruce forest in Central Germany using the relaxed eddy accumulation (REA) technique.
Schmidt, U.   +9 more
core   +1 more source

Carbonyl-Assisted Iridium-Catalyzed C–H Amination Using 2,2,2-Trichloroethoxycarbonyl Azide

open access: yes, 2022
The carbonyl-directed, mono C–H amination of arenes has been achieved using [Cp*Ir(III)Cl2]2 as the catalyst and 2,2,2-trichloroethoxycarbonyl (Troc) azide as an aminating reagent. The amination proceeds smoothly with a variety of arylcarbonyl compounds,
Hitesh B. Jalani (5420672)   +5 more
core   +1 more source

Multi-Omics Approach Reveals Prebiotic and Potential Antioxidant Effects of Essential Oils from the Mediterranean Diet on Cardiometabolic Disorder Using Humanized Gnotobiotic Mice

open access: yesAntioxidants, 2023
Essential oils sourced from herbs commonly used in the Mediterranean diet have demonstrated advantageous attributes as nutraceuticals and prebiotics within a model of severe cardiometabolic disorder.
María José Sánchez-Quintero   +15 more
doaj   +1 more source

Photo-Induced Reactions between Glyoxal and Hydroxylamine in Cryogenic Matrices

open access: yesMolecules, 2022
In this paper, the photochemistry of glyoxal–hydroxylamine (Gly–HA) complexes is studied using FTIR matrix isolation spectroscopy and ab initio calculations.
Barbara Golec   +2 more
doaj   +1 more source

trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate

open access: yesIUCrData, 2022
The chemical formulation of the title compound was established as trans-[PtCl{P(C2H5)3(CO)}BF4 by single-crystal X-ray analysis, in contrast to the five-coordinate tetrafluoroethylene complex that had been anticipated.
Peter W. R. Corfield
doaj   +1 more source

Extended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benzene (DITFB) Halogen Bond Donors

open access: yesCrystals, 2019
The ruthenium carbonyl compounds, Ru(bpy)(CO)2X2 (X = Cl, Br or I) act as neutral halogen bond (XB) acceptors when co-crystallized with 1,4-diiodotetrafluoro-benzene (DITFB).
Xin Ding   +3 more
doaj   +1 more source

An Automated Aerosol Collection and Extraction System to Characterize Electronic Cigarette Aerosols

open access: yesFrontiers in Chemistry, 2021
Electronic cigarette (e-cigarette) market increased by 122% during 2014–2020 and is expected to continue growing rapidly. Despite their popularity, e-cigarettes are known to emit dangerous levels of toxic compounds (e.g., carbonyls), but a lack of ...
Yeongkwon Son, Andrey Khlystov
doaj   +1 more source

Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): crystal structure and Hirshfeld surface analysis

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2018
The title cluster compound, [Ru3(C19H17PS)(CO)11], comprises a triangle of Ru0 atoms, two of which are bonded to four carbonyl ligands. The third metal atom is bound to three carbonyl ligands and the phosphane-P atom of a dissymmetric phosphane ligand ...
Omar bin Shawkataly   +4 more
doaj   +1 more source

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