Results 11 to 20 of about 552,882 (305)

Mono- and Dinuclear Carbonyl Dithiolene Complexes Related to the [FeFe]-Hydrogenases

open access: yesMolbank, 2023
The di-iron carbonyl dithiolene bridged complex [Fe2(CO)6(µ-S2C2(CO2Me)2)] (1) reacts with 1 equivalent of phosphane PR3 (R = Ph, OMe) to give, as major products, monosubstituted derivatives [Fe2(CO)5L(µ-S2C2(CO2Me)2)] (L = PPh3 (2), P(OMe)3 (3)). In the
Mohamed Kdider   +3 more
doaj   +1 more source

Correction:Carbonyl trapping and antiglycative activities of olive oil mill wastewater [PDF]

open access: yes, 2014
Correction for ‘Carbonyl trapping and antiglycative activities of olive oil mill wastewater’ by Marta Navarro et al., Food Funct., 2015, 6, 574 ...
Fiore, Alberto   +3 more
core   +3 more sources

Multi-Omics Approach Reveals Prebiotic and Potential Antioxidant Effects of Essential Oils from the Mediterranean Diet on Cardiometabolic Disorder Using Humanized Gnotobiotic Mice

open access: yesAntioxidants, 2023
Essential oils sourced from herbs commonly used in the Mediterranean diet have demonstrated advantageous attributes as nutraceuticals and prebiotics within a model of severe cardiometabolic disorder.
María José Sánchez-Quintero   +15 more
doaj   +1 more source

Assessing a New Clue to How Much Carbon Plants Take Up [PDF]

open access: yes, 2017
Current climate models disagree on how much carbon dioxide land ecosystems take up for photosynthesis.
Baker, Ian   +22 more
core   +5 more sources

Photo-Induced Reactions between Glyoxal and Hydroxylamine in Cryogenic Matrices

open access: yesMolecules, 2022
In this paper, the photochemistry of glyoxal–hydroxylamine (Gly–HA) complexes is studied using FTIR matrix isolation spectroscopy and ab initio calculations.
Barbara Golec   +2 more
doaj   +1 more source

Carbon-13 nuclear magnetic resonance spectra and mechanism of bridge–terminal carbonyl exchange in di-µ-carbonyl-bis[carbonyl(η-cyclopentadienyl)iron](Fe–Fe)[{(η-C5H5)Fe(CO)2}2]; cd-di-µ-carbonyl-f-carbonyl-ae-di(η-cyclopentadienyl)-b-(triethyl -phosphite)di-iron(Fe–Fe)[(η-C5H5)2Fe2(CO)3P(OEt)3], and some related complexes [PDF]

open access: yes, 1974
A mechanism involving carbonyl-bridge breaking, rotation about the Fe–Fe bond, and bridge reformation is shown to account qualitatively for changes in the carbonyl region of the 13C n.m.r spectrum of the complex [(cp)(OC)[graphic omitted]e(cp){P(OEt)3 ...
Harris, Daniel C.   +2 more
core   +1 more source

trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate

open access: yesIUCrData, 2022
The chemical formulation of the title compound was established as trans-[PtCl{P(C2H5)3(CO)}BF4 by single-crystal X-ray analysis, in contrast to the five-coordinate tetrafluoroethylene complex that had been anticipated.
Peter W. R. Corfield
doaj   +1 more source

Extended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benzene (DITFB) Halogen Bond Donors

open access: yesCrystals, 2019
The ruthenium carbonyl compounds, Ru(bpy)(CO)2X2 (X = Cl, Br or I) act as neutral halogen bond (XB) acceptors when co-crystallized with 1,4-diiodotetrafluoro-benzene (DITFB).
Xin Ding   +3 more
doaj   +1 more source

O- vs. N-protonation of 1-dimethylaminonaphthalene-8-ketones: formation of a peri N–C bond or a hydrogen bond to the pi-electron density of a carbonyl group [PDF]

open access: yes, 2014
X-ray crystallography and solid-state NMR measurements show that protonation of a series of 1-dimethylaminonaphthalene-8-ketones leads either to O protonation with formation of a long N–C bond (1.637–1.669 Å) between peri groups, or to N protonation and ...
Allen   +39 more
core   +2 more sources

Carbonylation of Phenylacetylene by Rhodium Carbonyl Chloride [PDF]

open access: yesBulletin of the Chemical Society of Japan, 1974
Abstract The reaction of phenylacetylene with carbon monoxide catalyzed by rhodium carbonyl chloride (Rh2(CO)4Cl2) gives 3,6 diphenyl-1-oxa-[3,3,0] bicycloocta-3,6-diene-2,4-dione.
Jitsuo Kiji   +2 more
openaire   +1 more source

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