Mono- and Dinuclear Carbonyl Dithiolene Complexes Related to the [FeFe]-Hydrogenases
The di-iron carbonyl dithiolene bridged complex [Fe2(CO)6(µ-S2C2(CO2Me)2)] (1) reacts with 1 equivalent of phosphane PR3 (R = Ph, OMe) to give, as major products, monosubstituted derivatives [Fe2(CO)5L(µ-S2C2(CO2Me)2)] (L = PPh3 (2), P(OMe)3 (3)). In the
Mohamed Kdider +3 more
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Correction:Carbonyl trapping and antiglycative activities of olive oil mill wastewater [PDF]
Correction for ‘Carbonyl trapping and antiglycative activities of olive oil mill wastewater’ by Marta Navarro et al., Food Funct., 2015, 6, 574 ...
Fiore, Alberto +3 more
core +3 more sources
Essential oils sourced from herbs commonly used in the Mediterranean diet have demonstrated advantageous attributes as nutraceuticals and prebiotics within a model of severe cardiometabolic disorder.
María José Sánchez-Quintero +15 more
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Assessing a New Clue to How Much Carbon Plants Take Up [PDF]
Current climate models disagree on how much carbon dioxide land ecosystems take up for photosynthesis.
Baker, Ian +22 more
core +5 more sources
Photo-Induced Reactions between Glyoxal and Hydroxylamine in Cryogenic Matrices
In this paper, the photochemistry of glyoxal–hydroxylamine (Gly–HA) complexes is studied using FTIR matrix isolation spectroscopy and ab initio calculations.
Barbara Golec +2 more
doaj +1 more source
Carbon-13 nuclear magnetic resonance spectra and mechanism of bridge–terminal carbonyl exchange in di-µ-carbonyl-bis[carbonyl(η-cyclopentadienyl)iron](Fe–Fe)[{(η-C5H5)Fe(CO)2}2]; cd-di-µ-carbonyl-f-carbonyl-ae-di(η-cyclopentadienyl)-b-(triethyl -phosphite)di-iron(Fe–Fe)[(η-C5H5)2Fe2(CO)3P(OEt)3], and some related complexes [PDF]
A mechanism involving carbonyl-bridge breaking, rotation about the Fe–Fe bond, and bridge reformation is shown to account qualitatively for changes in the carbonyl region of the 13C n.m.r spectrum of the complex [(cp)(OC)[graphic omitted]e(cp){P(OEt)3 ...
Harris, Daniel C. +2 more
core +1 more source
trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate
The chemical formulation of the title compound was established as trans-[PtCl{P(C2H5)3(CO)}BF4 by single-crystal X-ray analysis, in contrast to the five-coordinate tetrafluoroethylene complex that had been anticipated.
Peter W. R. Corfield
doaj +1 more source
The ruthenium carbonyl compounds, Ru(bpy)(CO)2X2 (X = Cl, Br or I) act as neutral halogen bond (XB) acceptors when co-crystallized with 1,4-diiodotetrafluoro-benzene (DITFB).
Xin Ding +3 more
doaj +1 more source
O- vs. N-protonation of 1-dimethylaminonaphthalene-8-ketones: formation of a peri N–C bond or a hydrogen bond to the pi-electron density of a carbonyl group [PDF]
X-ray crystallography and solid-state NMR measurements show that protonation of a series of 1-dimethylaminonaphthalene-8-ketones leads either to O protonation with formation of a long N–C bond (1.637–1.669 Å) between peri groups, or to N protonation and ...
Allen +39 more
core +2 more sources
Carbonylation of Phenylacetylene by Rhodium Carbonyl Chloride [PDF]
Abstract The reaction of phenylacetylene with carbon monoxide catalyzed by rhodium carbonyl chloride (Rh2(CO)4Cl2) gives 3,6 diphenyl-1-oxa-[3,3,0] bicycloocta-3,6-diene-2,4-dione.
Jitsuo Kiji +2 more
openaire +1 more source

