Results 21 to 30 of about 552,882 (305)

Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): crystal structure and Hirshfeld surface analysis

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2018
The title cluster compound, [Ru3(C19H17PS)(CO)11], comprises a triangle of Ru0 atoms, two of which are bonded to four carbonyl ligands. The third metal atom is bound to three carbonyl ligands and the phosphane-P atom of a dissymmetric phosphane ligand ...
Omar bin Shawkataly   +4 more
doaj   +1 more source

An Automated Aerosol Collection and Extraction System to Characterize Electronic Cigarette Aerosols

open access: yesFrontiers in Chemistry, 2021
Electronic cigarette (e-cigarette) market increased by 122% during 2014–2020 and is expected to continue growing rapidly. Despite their popularity, e-cigarettes are known to emit dangerous levels of toxic compounds (e.g., carbonyls), but a lack of ...
Yeongkwon Son, Andrey Khlystov
doaj   +1 more source

Design, synthesis and antibacterial activity of minor groove binders: the role of non-cationic tail groups [PDF]

open access: yes, 2012
he design and synthesis of a new class of minor groove binder (MGBs) in which, the cationic tail group has been replaced by a neutral, polar variant including cyanoguanidine, nitroalkene, and trifluoroacetamide groups.
Bourdin, Claire   +9 more
core   +1 more source

Dynamic Kinetic Resolution of Hetero biaryl Ketones by Zinc- Catalyzed Asymmetr ic Hydrosil ylation [PDF]

open access: yes, 2019
Adiastereo- and highly enantioselective dynamic kinetic resolution (DKR) of configurationally labile hetero- biaryl ketones is described. The DKR proceeds by zinc- catalyze dhydrosilylation of the carbonyl group ,thus leading to ...
Carmona, José A.   +6 more
core   +1 more source

Nature of Amide Carbonyl−Carbonyl Interactions in Proteins

open access: yesJournal of the American Chemical Society, 2009
Noncovalent interactions define and modulate biomolecular structure, function, and dynamics. In many protein secondary structures, an intimate interaction exists between adjacent carbonyl groups of the main-chain amide bonds. As this short contact contributes to the energetics of protein conformational stability as well as protein-ligand interactions ...
Choudhary, Amit   +3 more
openaire   +2 more sources

Tris(μ2-carbonyl)octacarbonyl(triphenylphosphite)tetracobalt

open access: yesMolbank, 2022
In toluene solution, the reaction of [Co2(CO)8] with an equimolar amount of [P(OPh)3] yields first [Co2(CO)7{P(OPh)3}] 1. Following heating of 1, an alternative synthetic access to the tetranuclear cluster [{Co4(μ2-CO)3(CO)8{P(OPh)3}] 2 is provided in a ...
Isabelle Jourdain   +3 more
doaj   +1 more source

Canopy uptake dominates nighttime carbonyl sulfide fluxes in a boreal forest [PDF]

open access: yes, 2017
Nighttime vegetative uptake of carbonyl sulfide (COS) can exist due to the incomplete closure of stomata and the light independence of the enzyme carbonic anhydrase, which complicates the use of COS as a tracer for gross primary productivity (GPP).
Aalto, J.   +15 more
core   +7 more sources

Relationship between Protein Oxidation Biomarkers and Uterine Health in Dairy Cows during the Postpartum Period [PDF]

open access: yes, 2019
High neutrophil (PMN, Polymorphonuclear neutrophil) counts in the endometrium of cows affected by endometritis, suggests the involvement of oxidative stress (OS) among the causes of impaired fertility. Protein oxidation, in particular, advanced oxidation
Barberio, Antonio   +7 more
core   +2 more sources

(OC-6-35-A)-Aquadicarbonylchlorido[2-(2-pyridyl)-1,8-naphthyridine-κ;2N1,N2]ruthenium(II) hexafluoridophosphate 2,2′-Bipyridine

open access: yesMolbank, 2017
A dicarbonylruthenium(II) complex containing bidentate 2-(2-pyridyl)-1,8-naphthyridine, as well as monodentate aqua and chlorido ligands, were isolated and characterized using spectroscopic techniques and single crystal X-ray diffraction.
Tsugiko Takase, Ryosuke Abe, Dai Oyama
doaj   +1 more source

Surface-enhanced Raman spectroscopy of DNA bases [PDF]

open access: yes, 1986
A Raman microprobe has been used to measure the surface-enhanced Raman spectra of adenine, guanine, cytosine and thymine. Comparison of the SERS spectrum with solution spectra shows that some line positions are not influenced by the adsorption process ...
Greve, J.   +3 more
core   +3 more sources

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