Results 31 to 40 of about 104,529 (263)
The title cluster compound, [Ru3(C19H17PS)(CO)11], comprises a triangle of Ru0 atoms, two of which are bonded to four carbonyl ligands. The third metal atom is bound to three carbonyl ligands and the phosphane-P atom of a dissymmetric phosphane ligand ...
Omar bin Shawkataly +4 more
doaj +1 more source
Carbonylation of Phenylacetylene by Rhodium Carbonyl Chloride [PDF]
Abstract The reaction of phenylacetylene with carbon monoxide catalyzed by rhodium carbonyl chloride (Rh2(CO)4Cl2) gives 3,6 diphenyl-1-oxa-[3,3,0] bicycloocta-3,6-diene-2,4-dione.
Jitsuo Kiji +2 more
openaire +1 more source
Mono- and Dinuclear Carbonyl Dithiolene Complexes Related to the [FeFe]-Hydrogenases
The di-iron carbonyl dithiolene bridged complex [Fe2(CO)6(µ-S2C2(CO2Me)2)] (1) reacts with 1 equivalent of phosphane PR3 (R = Ph, OMe) to give, as major products, monosubstituted derivatives [Fe2(CO)5L(µ-S2C2(CO2Me)2)] (L = PPh3 (2), P(OMe)3 (3)). In the
Mohamed Kdider +3 more
doaj +1 more source
Essential oils sourced from herbs commonly used in the Mediterranean diet have demonstrated advantageous attributes as nutraceuticals and prebiotics within a model of severe cardiometabolic disorder.
María José Sánchez-Quintero +15 more
doaj +1 more source
High throughput identification of carbonyl compounds in natural organic matter by directional derivatization combined with ultra-high resolution mass spectrometry [PDF]
Carbonyl compounds are an important component of natural organic matter (NOM), widely distributed in atmosphere, water, soil and organisms. However, our understanding on the molecular composition of these carbonyl compounds is still limited due to the ...
Feifei, Li +7 more
core +1 more source
4-[(E)-3-(4-Methylphenyl)-3-oxoprop-1-en-1-yl]benzonitrile
In the title molecule C17H13NO, the phenyl rings are inclined to one another by 48.04 (9)°. In the crystal, weak C—H...π(ring) interactions form a layered structure parallel to the ab plane.
Dandavathi Arunkumar +4 more
doaj +1 more source
Photo-Induced Reactions between Glyoxal and Hydroxylamine in Cryogenic Matrices
In this paper, the photochemistry of glyoxal–hydroxylamine (Gly–HA) complexes is studied using FTIR matrix isolation spectroscopy and ab initio calculations.
Barbara Golec +2 more
doaj +1 more source
Carbonyl-Stabilized Phosphorus Ylide as an Organocatalyst for Cyanosilylation Reactions Using TMSCN
We report carbonyl-stabilized phosphorus ylides as general and efficient catalysts for the cyanosilylation of ketones. The N,N-diethylacetamide derived phosphorane is identified as an extremely efficient catalyst for the cyanosilylation of dialkyl ...
Wen-Biao Wu (8500884) +5 more
core +1 more source
A dicarbonylruthenium(II) complex containing bidentate 2-(2-pyridyl)-1,8-naphthyridine, as well as monodentate aqua and chlorido ligands, were isolated and characterized using spectroscopic techniques and single crystal X-ray diffraction.
Tsugiko Takase, Ryosuke Abe, Dai Oyama
doaj +1 more source
trans-Carbonylchloridobis(triethylphosphane-κP)platinum(II) tetrafluoridoborate
The chemical formulation of the title compound was established as trans-[PtCl{P(C2H5)3(CO)}BF4 by single-crystal X-ray analysis, in contrast to the five-coordinate tetrafluoroethylene complex that had been anticipated.
Peter W. R. Corfield
doaj +1 more source

