Results 161 to 170 of about 4,674 (215)
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Journal of Organometallic Chemistry, 1985
Abstract The conditions of the preparation of boron—thallated 1,2-, 1,7- and 1,12-dicarba- closo -dodecaboranes(12) (trivial names “ o -, m - and p -carboranes”) have been studied. It was shown that maximum yields of the products are attained when o - and m -carboranes are treated consecutively with equimolecular amounts of mercuric oxide and ...
V.I. Bregadze +2 more
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Abstract The conditions of the preparation of boron—thallated 1,2-, 1,7- and 1,12-dicarba- closo -dodecaboranes(12) (trivial names “ o -, m - and p -carboranes”) have been studied. It was shown that maximum yields of the products are attained when o - and m -carboranes are treated consecutively with equimolecular amounts of mercuric oxide and ...
V.I. Bregadze +2 more
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New carboranes and phosphaboranes
Pure and Applied Chemistry, 2003Abstract A review is presented on the new routes to the synthesis of the monocarbaboranes [arachno-6-CB9H14]–, arachno-4-CB8H14, and nido-1-CB8H12, that now have become excellent starting materials for the preparation of a family of seven-, eight-, and nine-vertex closo-monocarbaborane anions [2-CB6H7]–, [1-CB7H8]–, and [4-CB8H9]–. These
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Carboranes in the chemist's toolbox
Dalton Transactions, 2015A carborane-fullerene dyad for organic field-effect transistors illustrates one of the many diverse areas of technology in which the special properties of these polyhedral boron clusters are being exploited.
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Journal of Organometallic Chemistry, 1979
Abstract The methine group of o-carboranes react with acrylonitrile and alkali catalyst to form β-cyanoethylcarboranes.
V.N. Kalinin +2 more
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Abstract The methine group of o-carboranes react with acrylonitrile and alkali catalyst to form β-cyanoethylcarboranes.
V.N. Kalinin +2 more
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Icosahedral carboranes. XVII. Simplified preparation of o-carborane
Inorganic Chemistry, 1972Abstract : A new synthesis of 1,2-dicarbaclosododecaborane is described which involves the reaction of acetylene with B10H12L2 compounds in the solid state. This simplified laboratory procedure provides pure o-carborane in one step as a sublimate from the reaction mixture. (Author)
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Carboranes. III. Reactions of the Carboranes
Inorganic Chemistry, 1963Daniel Grafstein +6 more
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Pd‐Catalyzed Selective Bifunctionalization of 3‐Iodo‐o‐Carborane by Pd Migration
Angewandte Chemie - International Edition, 2020Zaozao Qiu, Zuowei Xie
exaly
Highly Efficient Carborane-Based Activators for Molecular Olefin Polymerization Catalysts
ACS Catalysis, 2021David M Pearson +2 more
exaly
1,1′-Bis(ortho-carborane)-based transition metal complexes
Coordination Chemistry Reviews, 2019Igor B Sivaev, Vladimir I Bregadze
exaly