Room-Temperature Alternative to the Arbuzov Reaction: The Reductive Deoxygenation of Acyl Phosphonates [PDF]
, 2010 The reductive deoxygenation of acyl phosphonates using a Wolff−Kishner-like sequence is described. This transformation allows direct access to alkyl phosphonates from acyl phosphonates at room temperature. The method can be combined with acyl phosphonate
Dougherty, Dennis A. +1 more
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Carboxylic Acid Production [PDF]
Fermentation, 2017 Carboxylic acids are central compounds in cellular metabolism, and in the carbon cycle in nature.[...]
openaire +3 more sources
Enabling Heterogeneous Catalysis to Achieve Carbon Neutrality: Directional Catalytic Conversion of CO$_2$ into Carboxylic Acids [PDF]
arXiv, 2022 The increase in anthropogenic carbon dioxide (CO$_2$) emissions has exacerbated the deterioration of the global environment, which should be controlled to achieve carbon neutrality. Central to the core goal of achieving carbon neutrality is the utilization of CO$_2$ under economic and sustainable conditions.
arxiv
Crystals, 2021 This study aimed to synthesize quinolinone derivatives and investigate their cytotoxic activity. The compound 1-azacoumarin-3-carboxylic acid (2-oxo-1H-quinoline-3-carboxylic acid) was obtained via the cyclocondensation of 2-hydroxybenzaldehyde with ...
Ahmed Gaber +5 more
doaj +1 more source
An expedient route for the reduction of carboxylic acids to alcohols employing 1-propanephosphonic acid cyclic anhydride as acid activator [PDF]
, 2012 A simple and efficient method for the synthesis of alcohols from the corresponding carboxylic acids is described. Activation of carboxylic acid with 1-propane phosphonic acid cyclic anhydride (T3P) and subsequent reduction of the intermediate phosphonic ...
Madhu, C. +3 more
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Ringed spherulitic and undulated textures in the nematic phase of a mixture of trans-4-hexylcyclohexanecarboxylic and benzoic acids [PDF]
Phase Transitions, Volume 82, Issue 8 August 2009 , pages 620 -
631, 2009 We present a polarising optical microscopy study of a liquid-crystal mixture of trans-4-hexylcyclohexanecarboxylic acid (C6) and benzoic acid. Both materials have carboxylic groups that can form dimers through hydrogen bonding. The mixture is nematic and room temperature and has the clearing point at 88 Celsius.
arxiv +1 more source
Valorization of Lignin by Partial Wet Oxidation Using Sustainable Heteropoly Acid Catalysts
Molecules, 2017 The production of carboxylic acids by partial wet oxidation of alkali lignin at elevated temperatures and pressures was studied experimentally. Two different heteropoly acids, phosphotungstic acid (H3PW12O40) and phosphomolybdic acid (H3PMo12O40), were ...
Abayneh Getachew Demesa +3 more
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Direct deoxygenative borylation of carboxylic acids
Nature Communications, 2021 Converting a carboxylic acid into a boronic acid, which makes a useful chemical handle from a feedstock chemical, currently relies on decarboxylation and requires metal catalysts and prior functionalization.
Jianbin Li +4 more
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Photocatalytic direct borylation of carboxylic acids
Nature Communications, 2022 Boronic acids are useful reagents in organic synthesis and thus methods to prepare these compounds under mild conditions are desirable. Here, the authors synthesize boronic acids via photocatalytic decarboxylation of benzoic acids followed by borylation;
Qiang Wei +8 more
doaj +1 more source
Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates [PDF]
, 2014 This tutorial review highlights the organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium/azolium enolates.
Morrill, Louis C., Smith, Andrew D.
core +1 more source