Results 71 to 80 of about 668,340 (247)

Highly selective hydrogenation of arenes using nanostructured ruthenium catalysts modified with a carbon–nitrogen matrix

open access: yesNature Communications, 2016
The selective reduction of arenes is important in organic synthesis and also valorization of biomass. Here, the authors report the use of ruthenium-based nanoparticles, which display high activity in arene reduction and preferentially hydrogenate ...
Xinjiang Cui   +6 more
doaj   +1 more source

A search for inverse magnetic catalysis in thermal quark-meson models [PDF]

open access: yes, 2013
We explore the parameter space of the two-flavor thermal quark-meson model and its Polyakov loop-extended version under the influence of a constant external magnetic field $B$.
Fraga, E. S.   +2 more
core   +2 more sources

Effective reduction of N2O emission via combined plasma catalysis

open access: yesCatalysis Communications, 2023
N2O is a potent greenhouse gas that also causes devastating effects on the ozone layer. In this study, N2O decomposition is evaluated via thermal catalysis, plasma-alone and plasma catalysis, respectively. In thermal catalysis, N2O decomposition achieved
Li Si Ko   +3 more
doaj  

Carbon Monoxide Adsorption and Carbon Monoxide Oxidation Studies on Thiolate Supported Gold Nanoclusters Dispensed on Metallic Oxides [PDF]

open access: yesarXiv, 2018
Thiolate-protected gold nanoclusters represent atomically well-defined active centers for catalysis with resolved crystal structures, enabling the creation of a homogeneous and defined surface. The correlation of characterization via FT-IR spectroscopy with kinetics studies gives insight into the gold clusters activity and tests their utilization to ...
arxiv  

Geometrically induced magnetic catalysis and critical dimensions

open access: yes, 2015
We discuss the combined effect of magnetic fields and geometry in interacting fermionic systems. At leading order in the heat-kernel expansion, the infrared singularity (that in flat space leads to the magnetic catalysis) is regulated by the chiral gap ...
Flachi, Antonino   +2 more
core   +1 more source

Ligand engineering to achieve enhanced ratiometric oxygen sensing in a silver cluster-based metal-organic framework

open access: yesNature Communications, 2020
Incorporating dual fluorescence and phosphorescence into a single matrix is attractive for oxygen sensing, but material design is challenging. Here the authors achieve dual fluorescence-phosphorescence from a single linker chromophore in a silver ...
Xi-Yan Dong   +8 more
doaj   +1 more source

Thermodynamics of PNJL at zero temperature in a strong magnetic field [PDF]

open access: yesarXiv, 2022
In this paper, the deconfinement and chiral restoration transitions in strong magnetic field is realized at zero temperature in the Polyakov Nambu$-$Jona-Lasinio model. We provide the thermodynamic treatment to mimic the deconfinement phase transition at zero temperature together with the entangled scalar and vector interactions coupled with the ...
arxiv  

Holographic Monopole Catalysis of Baryon Decay

open access: yes, 2008
We study how monopole catalysis of baryon decay is realized in holographic QCD. Physics of monopole catalysis becomes much simpler in holographic description as it occurs due to the violation of the Bianchi identity for the 5D gauge symmetry when ...
Hong, Deog Ki   +3 more
core   +1 more source

How flexibility can enhance catalysis [PDF]

open access: yesarXiv, 2022
Conformational changes are observed in many enzymes, but their role in catalysis is highly controversial. Here we present a theoretical model that illustrates how rigid catalysts can be fundamentally limited and how a conformational change induced by substrate binding can overcome this limitation, ultimately enabling barrier-free catalysis.
arxiv  

Predicting template-based catalysis rates in a simple catalytic reaction model [PDF]

open access: yesarXiv, 2011
We show that in a particular model of catalytic reaction systems, known as the binary polymer model, there is a mathematical invariance between two versions of the model: (1) random catalysis and (2) template-based catalysis. In particular, we derive an analytical calculation that allows us to accurately predict the (observed) required level of ...
arxiv  

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