Results 71 to 80 of about 705,088 (330)

Mirror symmetry breaking with limited enantioselective autocatalysis and temperature gradients: a stability survey

open access: yes, 2012
We analyze limited enantioselective (LES) autocatalysis in a temperature gradient and with internal flow/recycling of hot and cold material. Microreversibility forbids broken mirror symmetry for LES in the presence of a temperature gradient alone.
Blanco, Celia   +5 more
core   +1 more source

Aβ42 promotes the aggregation of α‐synuclein splice isoforms via heterogeneous nucleation

open access: yesFEBS Letters, EarlyView.
The aggregation of amyloid‐β (Aβ) and α‐synuclein (αSyn) is associated with Alzheimer's and Parkinson's diseases. This study reveals that Aβ aggregates serve as potent nucleation sites for the aggregation of αSyn and its splice isoforms, shedding light on the intricate interplay between these two pathogenic proteins.
Alexander Röntgen   +2 more
wiley   +1 more source

Unraveling the structure and role of Mn and Ce for NOx reduction in application-relevant catalysts

open access: yesNature Communications, 2022
The role of Ce one Mn-based catalysts for the selective catalytic reduction of NOx at low temperature is an ongoing debate. Here the authors demonstrate that Ce has a structural promoting effect but impacts negatively on the intrinsic catalytic activity ...
Lieven E. Gevers   +10 more
doaj   +1 more source

Frustrated Lewis Pairs in Heterogeneous Catalysis: Theoretical Insights

open access: yesMolecules, 2022
Frustrated Lewis pair (FLP) catalysts have attracted much recent interest because of their exceptional ability to activate small molecules in homogeneous catalysis.
Qiang Wan, Sen Lin, Hua Guo
doaj   +1 more source

Inverse magnetic catalysis induced by sphalerons

open access: yes, 2013
The recently discovered inverse magnetic catalysis around the critical temperature indicates that some important information is missing in our current understanding of conventional chiral dynamics of QCD, which is enhanced by the magnetic field.
Chao, Jingyi, Chu, Pengcheng, Huang, Mei
core   +1 more source

Catalysis of the electrochemical reduction of oxygen by bacteria isolated from electro-active biofilms formed in seawater [PDF]

open access: yes, 2011
Biofilmsformed in aerobic seawater on stainless steel are known to be efficient catalysts of the electrochemicalreduction of oxygen. Based on their genomic analysis, seven bacterial isolates were selected and a cyclic voltammetry (CV) procedure was ...
Bergel, Alain   +7 more
core   +2 more sources

Thermostable neutral metalloprotease from Geobacillus sp. EA1 does not share thermolysin's preference for substrates with leucine at the P1′ position

open access: yesFEBS Letters, EarlyView.
Knowing how proteases recognise preferred substrates facilitates matching proteases to applications. The S1′ pocket of protease EA1 directs cleavage to the N‐terminal side of hydrophobic residues, particularly leucine. The S1′ pocket of thermolysin differs from EA's at only one position (leucine in place of phenylalanine), which decreases cleavage ...
Grant R. Broomfield   +3 more
wiley   +1 more source

Holographic Monopole Catalysis of Baryon Decay

open access: yes, 2008
We study how monopole catalysis of baryon decay is realized in holographic QCD. Physics of monopole catalysis becomes much simpler in holographic description as it occurs due to the violation of the Bianchi identity for the 5D gauge symmetry when ...
Hong, Deog Ki   +3 more
core   +1 more source

Investigation of Structural Dynamics of Enzymes and Protonation States of Substrates Using Computational Tools. [PDF]

open access: yes, 2016
This review discusses the use of molecular modeling tools, together with existing experimental findings, to provide a complete atomic-level description of enzyme dynamics and function.
Chang, Chia-En A   +3 more
core   +2 more sources

Redox‐dependent binding and conformational equilibria govern the fluorescence decay of NAD(P)H in living cells

open access: yesFEBS Letters, EarlyView.
In this work, we reveal how different enzyme binding configurations influence the fluorescence decay of NAD(P)H in live cells using time‐resolved anisotropy imaging and fluorescence lifetime imaging microscopy (FLIM). Mathematical modelling shows that the redox states of the NAD and NADP pools govern these configurations, shaping their fluorescence ...
Thomas S. Blacker   +8 more
wiley   +1 more source

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