Results 41 to 50 of about 75,340 (210)

Asymmetric microbial conversion of (E)-2-benzylideneindan-1-one by the filamentous fungi Botrytis cinerea, Trichoderma viride, and Eutypa lata [PDF]

open access: yes, 2011
The transformation of (E)-2-benzylideneindan-1-one 1 by the filamentous fungi Botrytis cinerea, Trichoderma viride, and Eutypa lata as biocatalysts was studied.
Aleu Casatejada, Josefina   +2 more
core   +2 more sources

Enantioselective Quantification of Amphetamine and Metabolites in Serum Samples: Forensic Evaluation and Estimation of Consumption Time

open access: yesMetabolites, 2021
In forensic toxicology, amphetamine intoxications represent one of the most common case groups and present difficult questions for toxicologists. Estimating the time of consumption and the current influence of the stimulant is particularly difficult when
Moritz Losacker   +7 more
doaj   +1 more source

Distinguishing left- and right-handed molecules by two-step coherent pulses

open access: yes, 2010
Chiral molecules with broken parity symmetries can be modeled as quantum systems with cyclic-transition structures. By using these novel properties, we design two-step laser pulses to distinguish left- and right-handed molecules from the enantiomers ...
Allenmark S   +6 more
core   +1 more source

Chiral separation by ligand-exchange

open access: yesMacedonian Journal of Chemistry and Chemical Engineering, 2011
The principle of chiral ligand-exchange, introduced by Davankov, has become a widely used technique for chiral separation in both chromatography and in electromigration techniques.
Martin G Schmid, Gerald Gübitz
doaj   +1 more source

Substituted Aryl Benzylamines as Potent and Selective Inhibitors of 17β-Hydroxysteroid Dehydrogenase Type 3

open access: yesMolecules, 2021
17β-Hydroxysteroid dehydrogenase type 3 (17β-HSD3) is expressed at high levels in testes and seminal vesicles; it is also present in prostate tissue and involved in gonadal and non-gonadal testosterone biosynthesis.
Nigel Vicker   +7 more
doaj   +1 more source

The diastereoselective Meth-Cohn epoxidation of camphor-derived vinyl sulfones [PDF]

open access: yes, 2012
Some camphor-derived vinyl sulfones bearing oxygen functionality at the allylic position have been synthesized and their nucleophilic epoxidation reactions under Meth-Cohn conditions have been explored.
Adam   +91 more
core   +1 more source

Enantioseparation of organometallic compounds and metal complexes by liquid chromatographic techniques. A review

open access: yesJournal of Chromatography Open
Chiral organometallic compounds and metal complexes, and more recently metal clusters, have attracted great interest for applications in chemical, biological, medical, and material sciences. In these fields, liquid chromatography has been widely used for
Barbara Sechi   +2 more
doaj   +1 more source

Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation

open access: yesNature Communications, 2016
Porous materials can be used in columns for gas separation applications. Here, Yan and co-workers from a bottom-up method have produced chiral covalent organic frameworks and from an in situ strategy formed capillary columns for chiral gas chromatography.
Hai-Long Qian   +2 more
doaj   +1 more source

Preparation of anti-vicinal amino alcohols: asymmetric synthesis of D-erythro-Sphinganine, (+)-spisulosine and D-ribo-phytosphingosine [PDF]

open access: yes, 2013
Two variations of the Overman rearrangement have been developed for the highly selective synthesis of anti-vicinal amino alcohol natural products. A MOM-ether directed palladium(II)-catalyzed rearrangement of an allylic trichloroacetimidate was used as ...
Abraham E.   +67 more
core   +1 more source

The enantioselective potential of amylose tris(3‑chloro-5-methylphenyl carbamate)-based chiral stationary phase in sub/supercritical fluid and normal phase liquid chromatography

open access: yesJournal of Chromatography Open
The enantioselective potential of amylose tris (3‑chloro-5-methylphenylcarbamate) based chiral stationary phase in sub/supercritical fluid chromatography and normal phase liquid chromatography was evaluated.
Denisa Folprechtová   +2 more
doaj   +1 more source

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