Results 101 to 110 of about 1,601,441 (195)

Organocatalytic Enantioselective Addition of Malonates to Cyclic Imines: A Short Total Synthesis of Tetraponerine T‐1

open access: yesAngewandte Chemie, Volume 138, Issue 38, 14 September 2026.
A stereoselective functionalization method of cyclic imines under mild organocatalytic conditions was developed. Bifunctional cinchona alkaloid catalysts combined with carefully optimized reaction conditions to suppress background reactivity enabled highly enantio‐ and diastereoselective addition reactions of malonates to cyclic imines.
Frederic Kölblin, Helma Wennemers
wiley   +2 more sources

Chiral Bifacial Indacenodithiophene‐Based Hole‐Transport Materials With Chirality‐Induced Spin Selectivity: Chirality‐Spin Polarity Correspondence and Perovskite Passivation

open access: yesSmall, EarlyView.
Homochiral bifacial indacenodithiophene (IDT)‐based hole‐transport materials form amorphous spin‐coated films showing pronounced chirality‐induced spin selectivity (CISS) with spin polarization ≈ 60%, and reveal a robust chirality–spin‐polarity correspondence.
Shuang Li   +3 more
wiley   +1 more source

DFT‐assisted rational design of salan ligands for highly enantioselective Zr–salan‐catalyzed hydroxylation of cyclic β‐keto esters

open access: yesSmart Molecules, EarlyView.
Guided by DFT calculations, the design of novel C1‐symmetric salan ligands without the involvement of Suzuki coupling was achieved, and the preparation of α‐hydroxy‐β‐ketoesters in 99% yield and 99% ee was realized under low catalyst loading. Abstract In this work, a structurally simple, inexpensive, and readily accessible Zr–salan catalytic system was
Cunfei Ma   +9 more
wiley   +1 more source

Cellulose-based chiral stationary phases for reversed phase HPLC [PDF]

open access: yes, 2014
This diploma thesis is focused on the comparison of enantioselective potential of chiral stationary phases based on derivatized cellulose by high performance liquid chromatography (HPLC).
Plecitá, Denisa
core  

The role of absorption in 3D electron diffraction dynamical structure refinement

open access: yesActa Crystallographica Section A, EarlyView.
This work establishes the role of absorption in 3D electron diffraction dynamical refinement, where its inclusion is shown to significantly affect refinement outcomes only in high‐Z materials at thicknesses approaching ξg.The role of absorption in 3D electron diffraction is established through analytical theory, simulation and dynamical refinement.
Benjamin Colmey   +3 more
wiley   +1 more source

An insight into chiral monolithic stationary phases for enantioselective high-performance liquid chromatography applications

open access: yes, 2019
In this review, three main classes of chiral monolithic stationary phases, namely silica-, organic polymer-, and hybrid-based monolithic stationary phases, are covered.
Frady G. Adly   +7 more
core   +1 more source

Overlooked components of lipid metabolism: Odd‐chain polyunsaturated fatty acids in photosynthetic microorganisms

open access: yesJournal of Phycology, EarlyView.
Abstract This mini‐review examines odd‐carbon polyunsaturated fatty acids (odd‐PUFAs), a rare but biologically significant group of fatty acids in photosynthetic microorganisms. Odd‐PUFAs are straight‐chain fatty acids containing an odd number of carbon atoms and two or more methylene‐interrupted double bonds. They typically account for less than 1% of
Linda Nedbalová   +2 more
wiley   +1 more source

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