Results 81 to 90 of about 1,601,441 (195)

Coated and Immobilized Polysaccharides‐Based Stationary Phases for Planar Metallocenes Enantioseparation in Liquid Chromatography

open access: yesELECTROPHORESIS, EarlyView.
This study examined 21 new ferrocene and ruthenocene derivatives, including those with planar and central chirality. Their stereochemical behavior was examined using UV‐detected normal‐phase liquid chromatography. Under fixed conditions, eight polysaccharide‐based chiral stationary phases were tested using n‐heptane combined with either 2‐propanol or ...
Florine Wartelle   +4 more
wiley   +1 more source

The Evolution of Chiral Stationary Phases for Liquid Chromatography

open access: yes, 1998
The development of effective chiral stationary phases and separation strategies for liquid chromatography (LC) resolution of enantiomers has been beneficial to many scientific disciplines.
Armstrong, Daniel W.
core   +1 more source

Green HPLC Enantioseparation of Chemopreventive Chiral Isothiocyanates Homologs on an Immobilized Chiral Stationary Phase Based on Amylose tris-[(S)-α-Methylbenzylcarbamate]

open access: yesMolecules
Sulforaphane is a chiral phytochemical with chemopreventive properties. The presence of a stereogenic sulfur atom is responsible for the chirality of the natural isothiocyanate.
Francesca Romana Mammone   +3 more
doaj   +1 more source

Chiral HPLC Separation of Phosphonothrixin and Phosphonate Derivatives and Electronic Circular Dichroism Characterization of the Isolated Enantiomers. [PDF]

open access: yesElectrophoresis
Natural compound phosphonothrixin's herbicidal activity resides exclusively in its (S)‐enantiomer, yet existing enantioselective syntheses are cumbersome, and direct chiral LC separation is hampered by the compound's high polarity, lack of aromatic groups, and metal chelation–induced peak tailing.
Maalouf M   +8 more
europepmc   +2 more sources

Capillary electrochromatographic separation of enantiomers on chemically bonded type of cellulose derivative chiral stationary phases with a positively charged spacer

open access: yes, 2003
Positively charged chiral stationary phases (CSPs) were prepared for capillary electrochromatography (CEC) separation of enantiomers by chemically immobilizing cellulose derivatives onto diethylenetriaminopropylated silica (DEAPS) with tolylene-2,4 ...
Zou, HF   +5 more
core   +1 more source

Plant‐Derived Extracts Disrupt Biofilm Formation and Quorum Sensing in Yersinia enterocolitica: Insights From GC‐MS and Molecular Docking

open access: yesFood Chemistry International, EarlyView.
The graphical abstract represents how natural plant products that preferentially target the specific receptors of quorum sensing could be developed to combat biofilms linked to Yersinia enterocolitica using the potent abilities of protein–ligand complexes with high docking scores.
Rajendran Thomas   +7 more
wiley   +1 more source

Gas chromatographic enantiomer separation on single and mixed cyclodextrin derivative chiral stationary phases

open access: yes, 2000
Capillary gas chromatographic enantiomer separation of some polar compounds, including alpha-phenylethylamine, styrene oxide, pyrethroid insecticides and other carboxylates, was investigated on modified cyclodextrin (CD) chiral stationary phases.
Zhu, DQ, Zhou, LM, Wang, QH, Nie, MY
core  

Rotational Anisotropy Raman Spectrometer for High‐Sensitivity Crystallographic Symmetry Analysis

open access: yesLaser &Photonics Reviews, EarlyView.
We introduce rotational‐anisotropy Raman spectroscopy, an enhanced scheme that overcomes the limitations of traditional polarization‐resolved Raman techniques. This method reveals previously inaccessible phonon symmetries and resolves directional anisotropy of phonon‐polaritons in benchmark crystals, establishing a powerful new tool for characterizing ...
Di Cheng   +4 more
wiley   +1 more source

Analysis of Carbohydrates and Glycoconjugates by Matrix‐Assisted Laser Desorption/Ionization Mass Spectrometry: An Update for 2023–2024

open access: yesMass Spectrometry Reviews, EarlyView.
ABSTRACT The use of MALDI mass spectrometry for the analysis of carbohydrates and glycoconjugates is a well‐established technique and this comprehensive review is the twelfth update of the original article published in 1999 and brings coverage of the literature to the end of 2024.
David J. Harvey
wiley   +1 more source

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