Results 61 to 70 of about 293,133 (311)
Diastereoselective synthesis of β- and γ2-muurolene. A carbocationic pathway from mono- to sesquiterpenes [PDF]
The Lewis acid catalysed addition of the piperityl chlorides 6 to isoprene yields adduct 7, which undergoes a cis-stereoselective cyclisation to give the diastereoisomeric muurolene monohydrochlorides 8.
Azizur-Rahman, +24 more
core +1 more source
The present work evaluates the method of electrochemical extraction of chloride ions for the rehabilitation of corroded concrete structures. The influence of the concrete cover and the water-to-cement ratio in the efficiency of the method was studied by ...
E. Monteiro, P. Helene, P. Barbosa
doaj +1 more source
In this study, the electrochemical performance of microcapsules (MCs) containing NaNO2 corrosion inhibitors for steel reinforcements was studied in 0.6 M chloride contaminated simulated concrete pore solutions (SCPS) with varying pH for a period of 28 ...
Jacob Ress+2 more
doaj +1 more source
Social context prevents heat hormetic effects against mutagens during fish development
This study shows that sublethal heat stress protects fish embryos against ultraviolet radiation, a concept known as ‘hormesis’. However, chemical stress transmission between fish embryos negates this protective effect. By providing evidence for the mechanistic molecular basis of heat stress hormesis and interindividual stress communication, this study ...
Lauric Feugere+5 more
wiley +1 more source
[2 + 2]-Cycloaddition of a stabilised vinyl cation with cyclopentadiene; X-ray crystal structure of the 2 : 1 addition product [PDF]
Lewis acid-catalysed reaction of 1,1-dimethyl-3-phenylprop-2-ynyl chloride with cyclopentadiene yields a 2 : 1 addition product via[2 + 2]-cycloaddition of an intermediate allenyl ...
Kaliba, Claus+2 more
core +1 more source
The enzyme 5‐lipoxygenase (5‐LOX) catalyzes the first step in the biosynthesis of leukotrienes (LTs) involved in inflammatory pathophysiology. After cellular stimulation, 5‐LOX translocates to the nucleus, interacting with the 5‐LOX‐activating protein (FLAP) to form LTA4 from arachidonic acid (AA).
Erik Romp+5 more
wiley +1 more source
We quantified and cultured circulating tumor cells (CTCs) of 62 patients with various cancer types and generated CTC‐derived tumoroid models from two salivary gland cancer patients. Cellular liquid biopsy‐derived information enabled molecular genetic assessment of systemic disease heterogeneity and functional testing for therapy selection in both ...
Nataša Stojanović Gužvić+31 more
wiley +1 more source
Kinetic and Thermodynamic Studies of Carbenium Ion Additions Towards Alkenes [PDF]
The ionisation (Ar2CHCl + BC13 v=± Ar2CH+BCi;) and dissociation (Ar2CH+BCi; ^=*Ar2CH+ + BCl^) equilibria of diarylmethyl chlorides i n boron trichloride/ dichloromethane solution have been studied by conductimetry, photometry and *H NMR spectroscopy ...
Arnett+20 more
core +1 more source
Extracting Aluminum from Aluminum Alloys in AlCl3-NaCl Molten Salts
Extracting aluminum from aluminum alloys in AlCl3-NaCl molten salts was investigated in this paper. The influences of experimental parameters such as electrolyte composition, cathodic current density and electrolysis time on the deposits morphology were ...
Xu Junli, Zhang Jing, Shi Zhongning
doaj +1 more source
Dual targeting of AKT and mTOR using MK2206 and RAD001 reduces tumor burden in an intracardiac colon cancer circulating tumor cell xenotransplantation model. Analysis of AKT isoform‐specific knockdowns in CTC‐MCC‐41 reveals differentially regulated proteins and phospho‐proteins by liquid chromatography coupled mass spectrometry. Circulating tumor cells
Daniel J. Smit+19 more
wiley +1 more source